Construction of Two High-Nuclear 3d-4d Heterometallic Cluster Organic Frameworks by Introducing a Bifunctional Tripodal Alcohol as a Structure-Directing Agent - Details

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Abstract：

Two　unique　heterometallic　cluster　organic　frameworks,　[Cd4MnIII4MnII6(Tri)4(CH3COO)14(μ4-O)2(μ3-O)2(H2O)2]　Cd(H2O)2⋅9　H2O　(1)　and　Cu[Cd5Cu6(Tri)4(CH3COO)9(H2O)4]2(CH3COO)3⋅24　H2O　(2)　(H3Tri=2-(hydroxymethyl)-2-(pyridine-4-yl)-1,3-propanediol),　have　been　successfully　prepared　by　employing　a　bifunctional　tripodal　alcohol　ligand　as　a　structure-directing　agent.　Crystal　structure　analyses　reveal　that　1　represents　a　rare　example　of　frameworks　constructed　from　Cd−Mn　heterometallic　chains,　and　2　is　the　first　heterometallic　MOF　based　on　highest-nuclear　Cd−Cu　heterometallic　cluster　building　blocks.　Furthermore,　the　magnetic　properties　and　gas　adsorption　abilities　of　1　and　2　were　systematically　studied.　©　2019　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

3d-4d heterometallic metal clusters; cluster organic frameworks; gas absorption; high-nuclear metal cluster; magnetic properties; metal-organic frameworks

Community：

[ 1 ] [Lin, L.-D.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Ge, R.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Zhang, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 4 ] [Li, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 5 ] [Yu, H.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 6 ] [Liu, J.-H.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 7 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 8 ] [Sun, Y.-Q.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 9 ] [Zhao, D.]Fuqing Branch of Fujian Normal University, Fuqing, Fujian 350300, China
[ 10 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China

Reprint 's Address：

[Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

lxx@fzu.edu.cn

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Source ：

Chemistry - An Asian Journal

ISSN： 1861-4728

Year： 2019

Issue： 11

Volume： 14

Page： 1985-1991

4 . 0 5 6

JCR@2019

3 . 5 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 9

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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