The　two　novel　cluster　organic　frameworks　based　on　heterometallic　supertetrahedral　cluster　secondary　building　units　(SBUs)　[Cd4Cu6(L)(4)(Ac)(7)(H2O)(4)](Ac)center　dot　7H(2)O　(1)　and　[Mn4Cu6(L)(4)(Ac)(4.5)(H2O)(9)]CuCN(Ac)(3.5)center　dot　H2O　(2),　where　H3L　=　2-(hydroxymethyl)-2-(pyridin-4-y1)-1,3-propanediol　and　Ac　=　CH3COO-,　have　been　prepared　under　solvothermal　conditions.　1　and　2　are　the　first　cases　of　cluster　organic　frameworks　containing　Cd-Cu/Mn-Cu　heterometallic　super-tetrahedral　cluster　SBUs.　Furthermore,　1　and　2　show　an　integration　of　magnetic　properties　and　adsorption　properties　from　both　the　heterometallic　cluster　secondary　building　units　and　the　framework　in　a　porous　material.