Indexed by:
Abstract:
A three-dimensional design composing of porous carbon matrix (PCM) decorated with nickel sulfide nanoparticles (denoted as NiSx@PCM) was fabricated through a one-step hydrothermal process, and successfully utilized as an electrode material in high performance sodium-ion batteries (SIBs) and sodium-ion hybrid capacitors (SIHCs). The as-prepared NiSx@PCM delivered a high reversible capacity of 650 mAh g(-1) over 200 cycles at 0.5 A g(-1), outstanding rate capability (167 mAh g(-1) at as high as 20 A g(-1)), and excellent cycle performance (300 mAh g(-1) at 1 A g(-1) after 800 cycles) in the SIBs. In addition, SIHCs based on NiSx@PCM composite anodes and commercial activated-carbon cathodes behaved carried remarkably high energy densities of 99.3 and 52.2 Wh kg(-1) at power densities of 140 and 4480 W kg(-1), respectively. The significantly high-performance enhancement should be attributed to the excellent electron/ion transports within the three-dimensional active material-carbon network during charging/discharging with the in-situ growth of the more conducive nickel sulfide nanoparticles throughout the porous carbon matrix. This work presents a facile method to synthesize three-dimensional carbon matrix incorporating metal sulfide nanoparticles, as well as suggests new insights into further advancing nextgeneration high energy-density/power-density energy storage units by combining the merits of both batteries and supercapacitors.
Keyword:
Reprint 's Address:
Email:
Version:
Source :
ENERGY STORAGE MATERIALS
ISSN: 2405-8297
Year: 2020
Volume: 25
Page: 636-643
1 7 . 7 8 9
JCR@2020
1 8 . 9 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:196
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 107
SCOPUS Cited Count: 107
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
Affiliated Colleges: