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author:

Li, Shengyang (Li, Shengyang.) [1] | He, Wei (He, Wei.) [2] | Liu, Ben (Liu, Ben.) [3] | Cui, Jingqin (Cui, Jingqin.) [4] | Wang, Xinghui (Wang, Xinghui.) [5] (Scholars:王星辉) | Peng, Dong-Liang (Peng, Dong-Liang.) [6] | Liu, Bin (Liu, Bin.) [7] | Qu, Baihua (Qu, Baihua.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

A three-dimensional design composing of porous carbon matrix (PCM) decorated with nickel sulfide nanoparticles (denoted as NiSx@PCM) was fabricated through a one-step hydrothermal process, and successfully utilized as an electrode material in high performance sodium-ion batteries (SIBs) and sodium-ion hybrid capacitors (SIHCs). The as-prepared NiSx@PCM delivered a high reversible capacity of 650 mAh g(-1) over 200 cycles at 0.5 A g(-1), outstanding rate capability (167 mAh g(-1) at as high as 20 A g(-1)), and excellent cycle performance (300 mAh g(-1) at 1 A g(-1) after 800 cycles) in the SIBs. In addition, SIHCs based on NiSx@PCM composite anodes and commercial activated-carbon cathodes behaved carried remarkably high energy densities of 99.3 and 52.2 Wh kg(-1) at power densities of 140 and 4480 W kg(-1), respectively. The significantly high-performance enhancement should be attributed to the excellent electron/ion transports within the three-dimensional active material-carbon network during charging/discharging with the in-situ growth of the more conducive nickel sulfide nanoparticles throughout the porous carbon matrix. This work presents a facile method to synthesize three-dimensional carbon matrix incorporating metal sulfide nanoparticles, as well as suggests new insights into further advancing nextgeneration high energy-density/power-density energy storage units by combining the merits of both batteries and supercapacitors.

Keyword:

Nickel sulfide Sodium-ion batteries Sodium-ion hybrid capacitors Three-dimensional carbon

Community:

  • [ 1 ] [Li, Shengyang]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 2 ] [Liu, Ben]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 3 ] [Cui, Jingqin]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 4 ] [Qu, Baihua]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 5 ] [He, Wei]Xiamen Univ, Coll Mat, Dept Mat Sci & Engn, Xiamen 361005, Peoples R China
  • [ 6 ] [Peng, Dong-Liang]Xiamen Univ, Coll Mat, Dept Mat Sci & Engn, Xiamen 361005, Peoples R China
  • [ 7 ] [Wang, Xinghui]Fuzhou Univ, Sch Phys & Informat Engn, Inst Micro Nano Devices & Solar Cells, Fuzhou 350108, Peoples R China
  • [ 8 ] [Liu, Bin]Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA

Reprint 's Address:

  • [Qu, Baihua]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China;;[Liu, Ben]Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA

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Source :

ENERGY STORAGE MATERIALS

ISSN: 2405-8297

Year: 2020

Volume: 25

Page: 636-643

1 7 . 7 8 9

JCR@2020

1 8 . 9 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 107

SCOPUS Cited Count: 107

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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