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Abstract:
Sodium-ion hybrid capacitors (SIHCs) have been regarded as one of the promising energy devices thanks to its low cost and compromise between energy density and power density, yet remain a challenge towards practical levels of mass loading (>10 mg cm(-2)). Herein, the fabrication of a 1D core-shell structure is reported with N-doped porous carbon encapsulating ZnV2O4 nanofibers (ZnV(2)O(4)NFs@N-PC), which features an open framework and favorable properties for facilitating ion diffusion, mass transportation, and electron transfer, enabling it to perform impressively for sodium ions storage. A 3D printed SIHC is conceptually proposed by coupling the 3D printed ZnV(2)O(4)NFs@N-PC anode with a 3D printed active carbon cathode, which can deliver a high energy/power density of 145.07 Wh kg(-1)/3677.1 W kg(-1) with a durable cycling lifespan. It is demonstrated that the 3D printed SIHC, even at a high mass loading of up to 16.25 mg cm(-2), can release a high areal energy/power density of 1.67 mWh cm(-2)/38.96 mW cm(-2), outperforming most of the SIHCs developed so far. The present work sheds light on the role of the design of electrode materials and verifies the promise of 3D-printed technology for next-generation electrochemical energy devices.
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ADVANCED FUNCTIONAL MATERIALS
ISSN: 1616-301X
Year: 2022
Issue: 30
Volume: 32
1 9 . 0
JCR@2022
1 8 . 5 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:91
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 28
SCOPUS Cited Count: 27
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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