Indexed by:
Abstract:
Sodium-ion hybrid capacitors (SIHCs) have shown great promise in achieving both high energy density and high power density by virtue of synergizing the merits of batteries and capacitors. However, the lack of favorable anode material with superior sodium-ion storage capability is still a major challenge in the development of high-performance SIHCs. Herein, we report the design and synthesis of a promising sodium-ion storage nanohybrid with FeS quantum dots embedded in three-dimensional (3D) inverse opal (IO)-structured N-doped carbon (3D-IO FeS-QDs@NC). By virtue of the robust 3D conductive architecture, the 3D-IO FeS-QDs@NC nanohybrid exhibits favorable features of excellent electron/ion transport kinetics, superior structural stability, as well as impressive sodium-ion storage capability with high specific capacity, outstanding rate capability, and ultra-long cyclic stability. Such highly desirable sodium storage performance inspired us to study their potential application in SHICs by coupling with commercial activated carbon (AC) as a cathode. The as-developed SHICs can deliver a maximum energy density and power output of 151.8 W h kg(-1) and 9280 W kg(-1), respectively, and an excellent cycling lifespan with 91% capacity retention after 5000 cycles at 1 A g(-1), which holds promise for bridging the performance gap between conventional batteries and capacitors.
Keyword:
Reprint 's Address:
Email:
Version:
Source :
JOURNAL OF MATERIALS CHEMISTRY A
ISSN: 2050-7488
Year: 2019
Issue: 3
Volume: 7
Page: 1138-1148
1 1 . 3 0 1
JCR@2019
1 0 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:236
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 101
SCOPUS Cited Count: 105
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
Affiliated Colleges: