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High-mobility organic field-effect transistors (OFETs), particularly those based on donor-acceptor polymers, often exhibit nonideal transfer characteristics, limiting their practical applications. Doping these semiconductors with specifically designed organic molecular electron acceptors can effectively address these deficiencies. By employing isoindigo-based acceptors with appropriate electron-withdrawing groups as dopants in diketopyrrolopyrrole-thienothiophene-based OFETs, we achieve an outstanding transistor performance with ideal transfer characteristics. Comprehensive analyses using ultraviolet-visible absorption, X-ray diffraction, ultraviolet photoelectron spectroscopy, and electrical measurements demonstrate that p-dopants play crucial roles in enhancing electron transfer, reducing charge carrier traps, and lowering contact resistance, thereby eliminating the typical "double slope" and hysteresis in OFET transfer characteristics.
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ACS APPLIED POLYMER MATERIALS
ISSN: 2637-6105
Year: 2025
Issue: 9
Volume: 7
Page: 5448-5455
4 . 5 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0