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author:

Chen, F. (Chen, F..) [1] | Li, J. (Li, J..) [2] | Shao, Y. (Shao, Y..) [3] | Zhu, Z. (Zhu, Z..) [4] | Shen, T. (Shen, T..) [5] | Chen, K. (Chen, K..) [6] | Chen, Y. (Chen, Y..) [7]

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Scopus

Abstract:

Layered double hydroxides (LDHs) have long been a hot research topic in supercapacitors because of their abundant reaction sites. However, LDH nanosheets tend to easily stack together during the synthesis process. Therefore, in this paper, a simple and effective stirring aging method was used to grow ZIF-67 uniformly on the surface of Ni-Mn LDH. The strategy can fully utilize the high specific surface area of ZIF-67 to provide a large number of active sites for Ni-Mn LDHs, which results in a significant increase of the capacitance contribution. The core–shell structure NM LDHs@Z has significant redox peaks and the surface redox reaction. The capacitance contribution of NM LDHs@Z increase from 21.7 % to 91.4 %. But it does not belong battery-type supercapacitors from the CV curves. It is necessary to find out a better characterization parameter to estimate the type of battery or capacitor, instead of the CV and GCD curve shapes. The Ni-Mn LDHs@ZIF-67 composites can achieve a specific capacitance of 1340 F g−1at a current density of 1 A g−1. As the specific current density is increased to 10 A g−1, the capacity retention can reach about 75 %, which is superior to that of the Ni-Mn LDHs (60 %). The hybrid supercapacitor is composed of Ni-Mn LDHs@ZIF-67 composite as the cathode and activated carbon (AC) as the anode with a 128 F g−1 specific capacitance at a 1 A g−1 current density and a 45.8 Wh kg−1 energy density at a 850 W kg−1 power density. The Ni-Mn LDH@ZIF-67 composites has a potential application in hybrid supercapacitors. © 2025 Elsevier B.V.

Keyword:

Aggregated LDHs Ni-Mn LDHs Supercapacitors ZIF-67

Community:

  • [ 1 ] [Chen F.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 2 ] [Li J.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 3 ] [Shao Y.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 4 ] [Shao Y.]College of Zhicheng, Fuzhou University, Fujian, Fuzhou, 350002, China
  • [ 5 ] [Zhu Z.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 6 ] [Shen T.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 7 ] [Chen K.]College of Materials Science and Engineering, Fuzhou University, Fujian, Fuzhou, 350108, China
  • [ 8 ] [Chen Y.]Electric Power Research Institute of State Grid Fujian Electric Power Co. Ltd., Fujian, Fuzhou, 350007, China
  • [ 9 ] [Chen Y.]Fujian Yongzheng Engineering Quality Inspection Co, Ltd, Fujian, Fuzhou, 350010, China

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2025

Volume: 507

1 3 . 4 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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