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author:

Yang, Huihui (Yang, Huihui.) [1] | Sun, Yuxuan (Sun, Yuxuan.) [2] | Wang, Cong (Wang, Cong.) [3] | Li, Yafeng (Li, Yafeng.) [4] (Scholars:李亚峰) | Wei, Mingdeng (Wei, Mingdeng.) [5] (Scholars:魏明灯)

Indexed by:

EI Scopus SCIE

Abstract:

The ternary MnCoNi layered double hydroxides (MnCoNi-LDH) used in supercapacitors frequently encounters issues in low electronic conductivity and big volume expansion throughout charge-discharge, which compro-mise cycling stability. Herein, MnCoNi-LDH is effectively produced via the straightforward one-pot hydrother-mal method with ZIF-67 as the template, which delivers an ultrahigh specific capacitance performance of 2254 F g-1 at a current density of 1 A/g. More importantly, the capacitance lost is only 8.47 % after 5000 cycles at 10 A/g. The fabricated MnCoNi-LDH consists of the hollow polyhedral nanostructure with interior nanoporous channels and nanosheet on the surface, which supply high specific areas and a huge quantity of redox active sites. It is found the exceptional performance of ternary MnCoNi-LDH is related to its distinctive nanostructure, the synergy effect among metal ions and the enhanced ion transmission speed and the conductivity. Additionally, when the ternary MnCoNi-LDH is employed in a flexible solid-state hybrid supercapacitor, the device has an excellent specific capacitance of 303.08 mF cm-2 at a current density of 1 mA cm-2, a high energy density of 47.42 Wh kg-1 at a power density of 404.1 W kg-1 and retains 96.3 % of capacitance after 5000 cycles.

Keyword:

Flexible Hollow Manganese-cobalt-nickel ternary hydroxides Polyhedral nanostructure Supercapacitor

Community:

  • [ 1 ] [Yang, Huihui]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China
  • [ 2 ] [Sun, Yuxuan]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China
  • [ 3 ] [Wang, Cong]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China
  • [ 4 ] [Li, Yafeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wei, Mingdeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China
  • [ 6 ] [Li, Yafeng]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Wei, Mingdeng]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Li, Yafeng]Fuzhou Univ, Fujian Key Lab Electrochem Energy Storage Mat, Fuzhou 350002, Peoples R China;;[Li, Yafeng]Fuzhou Univ, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China;;

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Source :

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

ISSN: 1572-6657

Year: 2022

Volume: 928

4 . 5

JCR@2022

4 . 1 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 4

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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