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author:

Chen, Huaiyin (Chen, Huaiyin.) [1] (Scholars:陈怀银) | Wang, Zhonghe (Wang, Zhonghe.) [2] | Li, Jun (Li, Jun.) [3] | Liu, Xiaolin (Liu, Xiaolin.) [4] | Li, Congxiang (Li, Congxiang.) [5] | Li, Yongzhao (Li, Yongzhao.) [6] | Yu, Weihe (Yu, Weihe.) [7] | Liu, Longmin (Liu, Longmin.) [8] | Zhang, Yi (Zhang, Yi.) [9] | Lai, Yuekun (Lai, Yuekun.) [10] (Scholars:赖跃坤) | Cai, Weilong (Cai, Weilong.) [11] (Scholars:蔡伟龙)

Indexed by:

EI Scopus SCIE

Abstract:

ZIF-8 is considered as a promising functional material in anti-corrosion coating applications. However, ZIF-8 hydrolyzes easily, especially in acidic and salty media, due to its unstable Zn-N coordination bonding and hydrophilic crystal surface, which reduces anti-corrosion durability of the coatings. In this study, highly hydrophobic modification of ZIF-8 particles was performed through simple surface ligand exchange with 5,6dimethylbenzimidazole (DMBIM). The as-prepared ZIF-8/DMBIM particles showed high water-repellency and enhanced chemical stability in acidic, neutral, and alkaline media, and excellent compatibility and barrier function in epoxy coatings. As a consequence, ZIF-8/DMBIM modified epoxy coatings showed significantly enhanced corrosion resistances in acid, alkali and salt aqueous solutions with pH 3.0-11.0. Electrochemical impedance spectroscopy tests demonstrated that, after 20 days of immersion in 3.5 wt% NaCl solution at all the studied pH, the |Z|0.01 Hz values of ZIF-8/DMBIM modified epoxy coatings were approximately two orders of magnitude higher than of the original epoxy coatings. This work provides an idea for the development and application of ZIF materials in more fields, and innovative anti-corrosion coatings based on functional modification of materials.

Keyword:

Corrosion resistance Epoxy coatings Hydrophobic modification Surface ligand exchange ZIF-8

Community:

  • [ 1 ] [Chen, Huaiyin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Wang, Zhonghe]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Li, Jun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Liu, Xiaolin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Li, Congxiang]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Cai, Weilong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Chen, Huaiyin]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 9 ] [Li, Yongzhao]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 10 ] [Yu, Weihe]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 11 ] [Liu, Longmin]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 12 ] [Lai, Yuekun]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 13 ] [Cai, Weilong]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 14 ] [Zhang, Yi]Fudan Univ, Dept Environm Sci & Engn, Shanghai 200438, Peoples R China

Reprint 's Address:

  • 赖跃坤 蔡伟龙

    [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China;;[Cai, Weilong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China;;[Zhang, Yi]Fudan Univ, Dept Environm Sci & Engn, Shanghai 200438, Peoples R China

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Source :

MATERIALS TODAY CHEMISTRY

ISSN: 2468-5194

Year: 2025

Volume: 43

6 . 7 0 0

JCR@2023

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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