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author:

Wang, Huibo (Wang, Huibo.) [1] | Liu, Yi (Liu, Yi.) [2] | Zhu, Mengyu (Zhu, Mengyu.) [3] | Chen, Yuejin (Chen, Yuejin.) [4] | Chen, Danling (Chen, Danling.) [5] | Lin, Zhimin (Lin, Zhimin.) [6] | Wang, Kexuan (Wang, Kexuan.) [7] | Xu, Zhu (Xu, Zhu.) [8] | Chen, Shi (Chen, Shi.) [9] | Xing, Guichuan (Xing, Guichuan.) [10] | Malyi, Oleksandr I. (Malyi, Oleksandr I..) [11] | Tang, Yuxin (Tang, Yuxin.) [12] (Scholars:汤育欣) | Zhang, Yanyan (Zhang, Yanyan.) [13] (Scholars:张焱焱)

Indexed by:

EI Scopus SCIE

Abstract:

Uneven Zn deposition and unfavorable side reactions have prevented the reversibility of the Zn anode. Herein, we design a rearranged (002) textured Zn anode inspired by a traditional curvature-enhanced adsorbate coverage (CEAC) process to realize the highly reversible Zn anode. The rearranged (002) textured structure directs superconformal Zn deposition by controlling the spatial deposition rate of the rearranged crystal planes, thereby promoting bottom-up "superfilling" of the 3D Zn skeletons. Meanwhile, our designed anode also induces the epitaxial Zn deposition, alleviating the parasitic reactions owing to the lowest surface energy of the (002) plane. Attributed to these superiorities, uniform and oriented Zn deposition can be obtained, exhibiting an ultra-long lifespan over 479 hrs at an ultrahigh depth of discharge (DOD) of 82.12 %. The Zn|Na2V6O16 & sdot; 3H2O battery delivers an improved cycling performance, even at a high area capacity of 5.15 mAh/cm2 with a low negative/positive (N/P) capacity ratio of 1.63. The superconformal deposition approach for Zn anodes paves the way for the practical application of high-performance zinc-ion batteries.

Keyword:

3D Zn anode epitaxial deposition parasitic reactions plastic deformation superconformal electrodeposition

Community:

  • [ 1 ] [Wang, Huibo]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 2 ] [Malyi, Oleksandr I.]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 3 ] [Tang, Yuxin]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 4 ] [Wang, Huibo]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zhu, Mengyu]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Chen, Yuejin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 7 ] [Chen, Danling]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 8 ] [Lin, Zhimin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 9 ] [Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 10 ] [Zhang, Yanyan]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 11 ] [Wang, Kexuan]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 12 ] [Xu, Zhu]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 13 ] [Chen, Shi]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 14 ] [Xing, Guichuan]Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
  • [ 15 ] [Liu, Yi]Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, State Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
  • [ 16 ] [Malyi, Oleksandr I.]Ctr Excellence ENSEMBLE3 Sp Zoo, Wolczynska Str 133, PL-01919 Warsaw, Poland

Reprint 's Address:

  • 汤育欣 张焱焱

    [Tang, Yuxin]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China;;[Tang, Yuxin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China;;[Zhang, Yanyan]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

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Source :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

Year: 2024

Issue: 2

Volume: 64

1 6 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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