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学者姓名：汤育欣
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Abstract ：
Polyethylene oxide (PEO)-based electrolytes are essential to advance all-solid-state lithium batteries (ASSLBs) with high safety/energy density due to their inherent flexibility and scalability. However, the inefficient Li+ transport in PEO often leads to poor rate performance and diminished stability of the ASSLBs. The regulation of intermolecular H-bonds is regarded as one of the most effective approaches to enable efficient Li+ transport, while the practical performances are hindered by the electrochemical instability of free H-bond donors and the constrained mobility of highly ordered H-bonding structures. To overcome these challenges, we develop a surface-confined disordered H-bond system with stable donor-acceptor interactions to construct a loosened chain segments/ions arrangement in the bulk phase of PEO-based electrolytes, realizing the crystallization inhibition of PEO, weak coordination of Li+ and entrapment of anions, which are conducive to efficient Li+ transport and stable Li+ deposition. The rationally designed LiFePO4-based ASSLB demonstrates a long cycle-life of over 400 cycles at 1.0 C and 65 degrees C with a capacity retention rate of 87.5 %, surpassing most of the currently reported polymer-based ASSLBs. This work highlights the importance of confined disordered H-bonds on Li+ transport in an all-solid-state battery system, paving the way for the future design of polymer-based ASSLBs.
Keyword ：
all-solid-state Li batteries all-solid-state Li batteries H-bond H-bond Li+ transport Li+ transport polyethylene oxide polyethylene oxide polymer electrolytes polymer electrolytes
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| GB/T 7714 | Fan, You , Malyi, Oleksandr I. , Wang, Huicai et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
| MLA | Fan, You et al. "Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2025) . |
| APA | Fan, You , Malyi, Oleksandr I. , Wang, Huicai , Cheng, Xiangxin , Fu, Xiaobin , Wang, Jingshu et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
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The development of solid-state electrolytes for Li-metal batteries demands high ionic conductivity, interfacial compatibility, and robust mechanical strength to address lithium dendrite formation and manufacturing challenges. Herein, We report a high-performance SSE, designed via in-situ polymerization of cross-linked poly(vinyl carbonate) (PVC) on a LATSP-coated polypropylene (PP) separator, resulting a LATSP@PP-PVC composite solid electrolyte. The PP separator ensures mechanical strength, while the LATSP coating improves wettability and lithium salt dissociation. Additionally, the cross-linked PVC network restricts TFSI-ion migration, enhancing Li+ conductivity. As a result, the composite exhibits excellent mechanical properties (70 MPa tensile strength, 54 % tensile strain), alongside a room-temperature ionic conductivity (3.19 x 10-4 S cm-1) and a Li+ transference number of 0.468. Li metal batteries employing this SSE paired with LiFePO4 cathodes show 81.56 % capacity retention after 800 cycles at 2 C, demonstrating its potential for commercial solid-state batteries. These findings hold promise for advancing the commercialization of composite electrolytes for solid state batteries.
Keyword ：
Cross-linked network Cross-linked network In-situ polymerization In-situ polymerization Interfaces Interfaces LATSP@PP separator LATSP@PP separator Solid-state lithium metal batteries Solid-state lithium metal batteries
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| GB/T 7714 | Zhao, Wenlong , Wang, Huihui , Dong, Qingyu et al. Mechanical stable composite electrolyte for solid-state lithium metal batteries [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 505 . |
| MLA | Zhao, Wenlong et al. "Mechanical stable composite electrolyte for solid-state lithium metal batteries" . | CHEMICAL ENGINEERING JOURNAL 505 (2025) . |
| APA | Zhao, Wenlong , Wang, Huihui , Dong, Qingyu , Shao, Hui , Zhang, Yanyan , Tang, Yuxin et al. Mechanical stable composite electrolyte for solid-state lithium metal batteries . | CHEMICAL ENGINEERING JOURNAL , 2025 , 505 . |
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Elucidating the microstructure of hard carbon is essential for uncovering the sodium storage mechanism and constructing state-of-the-art hard carbon anodes for sodium-ion batteries. Guided by an understanding of the crystallization process and inverse materials design principles, we design hard carbon anodes with different local fragments to understand the correlation between the microstructure of hard carbon and sodium storage behavior from the commercialization perspective. The sodiation transformation of hard carbon from slope- to plateau-type is realized via a series of local structure rearrangements, including tuning of the interlayer distance, average crystallite width of graphitic domains, and defect density. We found that the increase in plateau capacity is mainly related to the transition from the critical interlayer distance to the average crystallite width of graphitic domain control, and is limited by the closed pore volume of hard carbon. During sodiation, the formation of NaF and Na2O in the slope region, as well as Na2O2 and NaO2 in the plateau region, is always accompanied by the production of Na2CO3. This work provides insights into understanding the sodium storage behavior in hard carbon anodes and defines general structural design principles for transitioning from slope-type to plateau-type hard carbon.
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| GB/T 7714 | Wang, Feng , Chen, Lian , Wei, Jiaqi et al. Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement [J]. | ENERGY & ENVIRONMENTAL SCIENCE , 2025 , 18 (9) : 4312-4323 . |
| MLA | Wang, Feng et al. "Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement" . | ENERGY & ENVIRONMENTAL SCIENCE 18 . 9 (2025) : 4312-4323 . |
| APA | Wang, Feng , Chen, Lian , Wei, Jiaqi , Diao, Caozheng , Li, Fan , Du, Congcong et al. Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement . | ENERGY & ENVIRONMENTAL SCIENCE , 2025 , 18 (9) , 4312-4323 . |
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Layered oxide cathodes show great promise for commercial applications due to their low cost, high specific capacity, and energy density. However, their rapid capacity decay and slow kinetics primarily caused by harmful phase transitions and a high energy barrier for Na+ diffusion result in inferior battery performance. Herein, we modulate the crystal structure of layered oxide cathodes by replacing the Fe3+ site with Al3+, which strengthens the transition metal layers and enlarges the Na translation layer owing to the smaller ion radius of Al3+ and the stronger bonding energy of Al-O. This restrains the Jahn-Teller effect owing to transition metal dissolution and improves the electrochemical kinetics. Consequently, the modified cathodes exhibited an excellent high-rate performance of 111 mA h g-1 at a high rate of 5.0C and an unexpectedly long cycling life with a 73.88% capacity retention rate after 500 cycles at 5.0C, whereas the bare cathode exhibited a rate performance of 97.3 mA h g-1 with a low capacity retention rate of 48.42% after 500 cycles at 5.0C. This study provides valuable insights into tuning the crystal structure for designing fast charging and highly stable O3-type cathodes.
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| GB/T 7714 | Lin, Jingping , Chen, Daoyuan , Lin, Zhimin et al. Crystal structure modulation enabling fast charging and stable layered sodium oxide cathodes [J]. | NANOSCALE , 2025 , 17 (16) : 10095-10104 . |
| MLA | Lin, Jingping et al. "Crystal structure modulation enabling fast charging and stable layered sodium oxide cathodes" . | NANOSCALE 17 . 16 (2025) : 10095-10104 . |
| APA | Lin, Jingping , Chen, Daoyuan , Lin, Zhimin , Hong, Zige , Chen, Qiuyan , Wang, Yating et al. Crystal structure modulation enabling fast charging and stable layered sodium oxide cathodes . | NANOSCALE , 2025 , 17 (16) , 10095-10104 . |
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Sodium-ion batteries (SIBs) with low cost and high safety are considered as an electrochemical energy storage technology suitable for large-scale energy storage. Hard carbon, which is inexpensive and has both high capacity and low sodium storage potential, is regarded as the most promising anode for commercial SIBs. However, the commercialization of hard carbon still faces technical issues of low initial Coulombic efficiency, poor rate performance, and insufficient cycling stability, due to the intrinsically irregular microstructure of hard carbon. To address these challenges, the rational design of the hard carbon microstructure is crucial for achieving high-performance SIBs, via gaining an in-depth understanding of its structure–performance correlations. In this context, our review firstly describes the sodium storage mechanism from the perspective of the hard carbon microstructure's formation. We then summarize the state-of-art development of hard carbon, providing a critical overview of emergence of hard carbon in terms of precursor selection, microstructure design, and electrolyte regulation to optimize strategies for addressing practical problems. Finally, we highlight directions for the future development of hard carbon to achieve the commercialization of high-performance SIBs. We believe this review will serve as basic guidance for the rational design of hard carbon and stimulate more exciting research into other types of energy storage devices. © 2023 The Authors
Keyword ：
Controllable microstructure Controllable microstructure Coulombic efficiency Coulombic efficiency Electrolyte regulation Electrolyte regulation Hard carbon Hard carbon Sodium-ion batteries Sodium-ion batteries Sodium storage mechanism Sodium storage mechanism
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| GB/T 7714 | Wang, F. , Jiang, Z. , Zhang, Y. et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon [J]. | eScience , 2024 , 4 (3) . |
| MLA | Wang, F. et al. "Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon" . | eScience 4 . 3 (2024) . |
| APA | Wang, F. , Jiang, Z. , Zhang, Y. , Li, J. , Wang, H. , Jiang, Y. et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon . | eScience , 2024 , 4 (3) . |
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Solid-state lithium batteries (SSLBs) with high safety have emerged to meet the increasing energy density demands of electric vehicles, hybrid electric vehicles, and portable electronic devices. However, the dendrite formation, high interfacial resistance, and deleterious interfacial reactions caused by solid-solid contact between electrode and electrolyte have hindered the commercialization of SSLBs. Thus, in this review, the state-of-the-art developments in the rational design of solid-state electrolyte and their progression toward practical applications are reviewed. First, the origin of interface instability and the sluggish charge carrier transportation in solid-solid interface are presented. Second, various strategies toward stabilizing interfacial stability (reducing interfacial resistance, suppressing lithium dendrites, and side reactions) are summarized from the physical and chemical perspective, including building protective layer, constructing 3D and gradient structures, etc. Finally, the remaining challenges and future development trends of solid-state electrolyte are prospected. This review provides a deep insight into solving the interfacial instability issues and promising solutions to enable practical high-energy-density lithium metal batteries.
Keyword ：
dendrite formation dendrite formation high energy density high energy density interface instability interface instability interfacial resistance interfacial resistance solid-state electrolyte solid-state electrolyte
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| GB/T 7714 | He, Honggang , Wang, Litong , Al-Abbasi, Malek et al. Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries [J]. | ENERGY & ENVIRONMENTAL MATERIALS , 2024 , 7 (4) . |
| MLA | He, Honggang et al. "Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries" . | ENERGY & ENVIRONMENTAL MATERIALS 7 . 4 (2024) . |
| APA | He, Honggang , Wang, Litong , Al-Abbasi, Malek , Cao, Chunyan , Li, Heng , Xu, Zhu et al. Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries . | ENERGY & ENVIRONMENTAL MATERIALS , 2024 , 7 (4) . |
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Aqueous zinc-ion batteries (AZIBs) are promising large-scale energy storage devices due to their costeffectiveness and high safety. However, the rampant dendrite growth and notorious side reactions resulting from the decomposition of active water molecules hinder its practical application. Herein, the zincophilic polyoltype surfactant of alkyl polyglycoside (APG) is introduced to induce the rearrangement of the H-bonds network to diminish the free water activity, facilitating the zinc-ion solvation structure transition from [Zn2+(H2O)6 & sdot;SO42-] (solvent separated ion pair, SSIP) to [Zn2+(H2O)5 & sdot;OSO32-] (contact ion pair, CIP) with less Zn2+-solvated H2O. Meanwhile, the APG molecular preferentially adsorb on the Zn surface to form a dehydrated layer, which can suppress the hydrogen evolution reaction (HER) and hinder the two-dimensional (2D) diffusion of Zn2+ ions. Consequently, the Zn//Zn symmetric cell using our designed electrolyte demonstrates an ultralong cycle life of 5250 h at 1.0 mA cm-2/1.0 mAh cm-2. Furthermore, the as-prepared Zn//Na2V6O16 & sdot;3H2O full cell also delivers a high-capacity retention rate of 80.8% even after 1000 cycles at 2.0 A g-1, superior to that of the full cell using pure ZnSO4 electrolyte. This study offers an effective strategy to modulate the cation solvation structure by rearranging the H-bonds network for a highly reversible Zn anode.
Keyword ：
Alkyl polyglycoside Alkyl polyglycoside H -bonds network H -bonds network Hydrogen evolution reaction Hydrogen evolution reaction Solvation structure Solvation structure Zn anodes Zn anodes
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| GB/T 7714 | Wang, Huicai , Zhu, Mengyu , Wang, Huibo et al. Rearrangement of H-bonds network of solvation structure via a zincophilic polyol-type surfactant to stabilize zinc anode in aqueous zinc-ion batteries [J]. | ENERGY STORAGE MATERIALS , 2024 , 67 . |
| MLA | Wang, Huicai et al. "Rearrangement of H-bonds network of solvation structure via a zincophilic polyol-type surfactant to stabilize zinc anode in aqueous zinc-ion batteries" . | ENERGY STORAGE MATERIALS 67 (2024) . |
| APA | Wang, Huicai , Zhu, Mengyu , Wang, Huibo , Li, Chunxin , Ren, Zejia , Zhang, Yanlei et al. Rearrangement of H-bonds network of solvation structure via a zincophilic polyol-type surfactant to stabilize zinc anode in aqueous zinc-ion batteries . | ENERGY STORAGE MATERIALS , 2024 , 67 . |
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Hard carbon with abundant resources, low-cost, and high specific capacity, is a promising anode material for large-scale sodium-ion batteries. However, the poor rate performance of hard carbon suffers from serious challenges due to sluggish ion transport dynamic behavior, especially at low potential, in high power density of sodium-ion batteries. To address this issue, we introduce an ionic-conductive sodium-titanate into hard carbon to boost its sodium-ion transport kinetics via constructing a dual ionic-electronic conducting network in hard carbon anode. Benefiting from our design, the optimized hard carbon-sodium titanate electrode achieves high specific capacity of 137 mAh g(-1) at a high current density of 10 A g(-1), compared to that of hard carbon of 25 mAh g(-1) at 10 A g(-1). Remarkably, it also exhibits an excellent capacity retention of 71.4% at the current density of 2.0 A g(-1) after 800 cycles. This work presents a practical strategy for high-rate hard carbon design and provides valuable insights into the construction of high-rate anode for advanced sodium-ion batteries.
Keyword ：
Hard carbon Hard carbon High rate High rate Ionic conductivity Ionic conductivity Sodium ion batteries Sodium ion batteries Sodium titanate Sodium titanate
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| GB/T 7714 | Li, Fan , Gong, Hao , Zhang, Yanlei et al. Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries [J]. | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 981 . |
| MLA | Li, Fan et al. "Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries" . | JOURNAL OF ALLOYS AND COMPOUNDS 981 (2024) . |
| APA | Li, Fan , Gong, Hao , Zhang, Yanlei , Liu, Xinyu , Jiang, Zhenming , Chen, Lian et al. Ionic-conductive sodium titanate to boost sodium-ion transport kinetics of hard carbon anode in sodium-ion batteries . | JOURNAL OF ALLOYS AND COMPOUNDS , 2024 , 981 . |
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Abstract ：
Sodium-ion batteries (SIBs) with low cost and high safety are considered as an electrochemical energy storage technology suitable for large-scale energy storage. Hard carbon, which is inexpensive and has both high capacity and low sodium storage potential, is regarded as the most promising anode for commercial SIBs. However, the commercialization of hard carbon still faces technical issues of low initial Coulombic efficiency, poor rate performance, and insufficient cycling stability, due to the intrinsically irregular microstructure of hard carbon. To address these challenges, the rational design of the hard carbon microstructure is crucial for achieving highperformance SIBs, via gaining an in-depth understanding of its structure-performance correlations. In this context, our review firstly describes the sodium storage mechanism from the perspective of the hard carbon microstructure's formation. We then summarize the state-of-art development of hard carbon, providing a critical overview of emergence of hard carbon in terms of precursor selection, microstructure design, and electrolyte regulation to optimize strategies for addressing practical problems. Finally, we highlight directions for the future development of hard carbon to achieve the commercialization of high-performance SIBs. We believe this review will serve as basic guidance for the rational design of hard carbon and stimulate more exciting research into other types of energy storage devices.
Keyword ：
Controllable microstructure Controllable microstructure Coulombicefficiency Coulombicefficiency Electrolyte regulation Electrolyte regulation Hard carbon Hard carbon Sodium-ion batteries Sodium-ion batteries Sodium storage mechanism Sodium storage mechanism
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| GB/T 7714 | Wang, Feng , Jiang, Zhenming , Zhang, Yanyan et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon [J]. | ESCIENCE , 2024 , 4 (3) . |
| MLA | Wang, Feng et al. "Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon" . | ESCIENCE 4 . 3 (2024) . |
| APA | Wang, Feng , Jiang, Zhenming , Zhang, Yanyan , Zhang, Yanlei , Li, Jidao , Wang, Huibo et al. Revitalizing sodium-ion batteries via controllable microstructures and advanced electrolytes for hard carbon . | ESCIENCE , 2024 , 4 (3) . |
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Layered structure Na2Ti3O7 with a suitable sodiation plateau potential (similar to 0.3 V vs Na+/Na) is a promising anode for highly safe sodium-ion batteries (SIBs). However, the practical use of Na2Ti3O7 is hindered by the unstable interface that forms between the anode and electrolyte leading to issues such as low initial coulombic efficiency (ICE) and cycling instability. Herein, we introduce tetraethyl orthosilicate (TEOS) as an electrolyte additive that can spontaneously and effectively react with the main component of the detrimental surface corrosion layer (sodium hydroxide, etc.) to form a protective film on the Na2Ti3O7 anode. The Na2Ti3O7 anode exhibits an enhanced capacity from 134.8 to 167.1 mAh g(-1) at 0.1 A g(-1), along with an increase in capacity retention from 56.1 to 83.9% after 250 cycles at 0.2 A g(-1). This work provides a straightforward protection strategy to address the unstable interface issues, rendering sodium titanate as a promising anode material to achieve practical application in the future.
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| GB/T 7714 | Jiang, Zhenming , Ke, Haifeng , Zhang, Yanlei et al. Building a Stable Plateau-Type Na2Ti3O7 Anode Interface toward Advanced Sodium-Ion Batteries [J]. | ENERGY & FUELS , 2024 , 38 (3) : 2472-2479 . |
| MLA | Jiang, Zhenming et al. "Building a Stable Plateau-Type Na2Ti3O7 Anode Interface toward Advanced Sodium-Ion Batteries" . | ENERGY & FUELS 38 . 3 (2024) : 2472-2479 . |
| APA | Jiang, Zhenming , Ke, Haifeng , Zhang, Yanlei , Li, Linwei , Wang, Feng , Li, Jidao et al. Building a Stable Plateau-Type Na2Ti3O7 Anode Interface toward Advanced Sodium-Ion Batteries . | ENERGY & FUELS , 2024 , 38 (3) , 2472-2479 . |
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