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author:

Wu, Xiaolin (Wu, Xiaolin.) [1] | Xie, Guiqing (Xie, Guiqing.) [2] | Xu, Jing (Xu, Jing.) [3] (Scholars:徐净) | Voudouris, Panagiotis (Voudouris, Panagiotis.) [4] | Liu, Wenyuan (Liu, Wenyuan.) [5] (Scholars:刘文元)

Indexed by:

EI Scopus SCIE

Abstract:

Porphyry copper systems contain porphyry Cu, skarn, carbonate-replacement and epithermal deposits, and presently supply nearly all the Te and Se, and have the potential to produce Co as by-product in the future. However, few studies have investigated the distribution of Co, Te, and Se in the specific porphyry-skarn deposit. Detailed mineralogical and geochemical analyses were conducted to investigate the distribution of Co, Te, and Se across porphyry, skarn, and carbonate-replacement ore types in the Tonglvshan porphyry-skarn Cu-Fe-Au deposit, Eastern China. The early sulfide stage in three ore types is characterized by Co-bearing pyrite (Py1a, Co up to 1.3 wt%) + droplet-like tetradymite +/- hessite +/- cattierite. The texture transition from coarse-grained, porefree to porous Py1a in porphyry and skarn type ores suggests a shift from stable physico-chemical conditions to gentle fluid boiling, resulting in the precipitation of Co- and Te-bearing minerals. In contrast, fine-grained euhedral Py1a in carbonate-replacement type ores implies rapid cooling from high-temperature fluid interaction with marble. The late sulfide stage, which only occurs in skarn and carbonate-replacement type ores, is characterized by Corich pyrite (Py2) + carrollite + hessite + Bi-sulfosalts. In skarn type ores, tetradymite-kawazulite solid solution (TKSS) + hessite + native Te + naumannite reflects intense boiling, leading to an increase in fO2 and pH that precipitates Py2b (Co up to 19.2 wt%) and carrollite, while Te and Se may precipitate through vapor phase condensation. Conversely, the presence of fine-grained carrollite, zoned Py2a, sphalerite, and galena in carbonate-replacement type ore suggests that rapid cooling and increasing pH, resulting from fluid mixing, played a significant role in the precipitation Co and Te. Furthermore, the porous texture resulting from coupled dissolution-reprecipitation (CDR) during the late sulfide stage also provided favorable conditions for the formation of micro-nano sized critical metal particles.

Keyword:

Cobalt Critical metal Porphyry-skarn deposit Selenium Tellurium Tonglvshan

Community:

  • [ 1 ] [Wu, Xiaolin]China Univ Geosci, Sch Earth Sci & Resources, Beijing 100083, Peoples R China
  • [ 2 ] [Xie, Guiqing]China Univ Geosci, Sch Earth Sci & Resources, Beijing 100083, Peoples R China
  • [ 3 ] [Wu, Xiaolin]China Univ Geosci, MNR Key Lab Explorat Theory & Technol Crit Mineral, Beijing 100083, Peoples R China
  • [ 4 ] [Xie, Guiqing]China Univ Geosci, MNR Key Lab Explorat Theory & Technol Crit Mineral, Beijing 100083, Peoples R China
  • [ 5 ] [Xu, Jing]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 6 ] [Liu, Wenyuan]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 7 ] [Voudouris, Panagiotis]Natl & Kapodistrian Univ Athens, Fac Geol & Geoenvironm, Athens 15784, Greece

Reprint 's Address:

  • [Xie, Guiqing]China Univ Geosci, Sch Earth Sci & Resources, Beijing 100083, Peoples R China;;

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Source :

ORE GEOLOGY REVIEWS

ISSN: 0169-1368

Year: 2024

Volume: 174

3 . 2 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

Online/Total:158/9695000
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