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[期刊论文]

Tree-inspired semiconductor-on-ceramic 2D/1D heterostructure for efficient CO2 photoreduction

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author:

Hu, Yingzi (Hu, Yingzi.) [1] | Zhu, Yan (Zhu, Yan.) [2] | He, Xi (He, Xi.) [3] | Unfold

Indexed by:

EI Scopus SCIE

Abstract:

Two-dimension nanosheets are ideal photocatalysts for CO2 reduction due to their high exposure of active sites and short charge transfer pathway. However, 2D photocatalysts have a tendency to agglomeration, thus compromising the performance of photocatalytic CO2 reduction. Trees, one of the most important plants for photosynthesis, have a unique "leaf-on-branch" structure. This unique two-dimension/one-dimension (2D/1D) configuration maximizes the adsorption of CO2 molecules and light harvesting. Herein, a tree-inspired semiconductor-on-ceramic 2D/1D heterostructure for efficient photocatalytic CO2 reduction is reported. The cobalt silicate (CoSi) nanosheets (similar to 0.68 nm) are in situ grown on the surfaces of hydroxyapatite (HAP) nanowires, creating a well-defined 2D/1D hierarchical structure. The vertical alignment of ultrathin CoSi nanosheets on the HAP nanowires effectively suppresses their agglomeration, leading to a large BET surface area (106.45 m(2)/g) and excellent CO2 adsorption (8.00 cm(3) g(-1)). The results of photoelectrochemical characterization demonstrate that the 2D/1D hierarchical structure is powerful to expedite charge transfer. As a result, the gas generation rate of CO is as high as 28780 mu mol g(-1) h(-1) over the CoSi-on-HAP 2D/1D heterostructure. In addition, the electron transfer mechanism and reaction pathways of CO2 reduction are revealed by in situ irradiated XPS and in situ DRIFT spectra.

Keyword:

CO2 reduction Heterostructure Hydroxyapatite nanowires Photocatalysis Silicate nanosheets

Community:

  • [ 1 ] [Hu, Yingzi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 3 ] [He, Xi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 4 ] [Feng, Ya-Nan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 5 ] [Chen, Fei-Fei]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 6 ] [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 7 ] [Hu, Yingzi]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 8 ] [Zhu, Yan]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 9 ] [He, Xi]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 10 ] [Feng, Ya-Nan]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 11 ] [Chen, Fei-Fei]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 12 ] [Yu, Yan]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China

Reprint 's Address:

  • [Feng, Ya-Nan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China;;[Chen, Fei-Fei]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China;;[Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China;;

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Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2024

Volume: 672

6 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

30 Days PV: 1

Online/Total:50/10154023
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