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author:

Zhou, Min (Zhou, Min.) [1] | Wang, Sibo (Wang, Sibo.) [2] (Scholars:汪思波) | Yang, Pengju (Yang, Pengju.) [3] | Huang, Caijin (Huang, Caijin.) [4] (Scholars:黄彩进) | Wang, Xinchen (Wang, Xinchen.) [5] (Scholars:王心晨)

Indexed by:

EI Scopus SCIE

Abstract:

Ternary boron carbon nitride (BCN) semiconductors have been developed as emerging metal-free photocatalysts for visible light reduction of COD but the achieved efficiency is still not satisfying. Herein, we report that the CO2 photoreduction performance of a bulk BCN semiconductor can be substantially improved by surface engineering with CdS nanoparticles. The CdS/BCN photocatalysts are characterized completely by diverse tests (e.g., XRD, FTIR, XPS, DRS, SEM, TEM, N-2 sorption, PL, and transient photocurrent spectroscopy). Performance of the CdS/BCN heterostructures is evaluated by reductive CO2 conversion reactions with visible light under benign reaction conditions. Compared with bare BCN material, the optimized CdS/BCN photocatalyst exhibits a 10-fold-enhanced CO, reduction activity and high stability, delivering a considerable CO production rate of 12.5 itmol h(-1) (250 mu mol h(-1) g(-1)) with triethanolamine (TEOA) as the reducing agent. The reinforced photocatalytic CO2 reduction activity is mainly assigned to the obviously improved visible-light harvesting and the greatly accelerated separation/transport kinetics of light-triggered electron hole pairs. Furthermore, a possible visible-light-induced CO2 reduction mechanism is proposed on the basis of photocatalytic and photo(electro)chemical results.

Keyword:

boron carbon nitride CdS CO2 reduction heterostructure photocatalysis

Community:

  • [ 1 ] [Zhou, Min]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Wang, Sibo]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Yang, Pengju]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Huang, Caijin]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Wang, Xinchen]King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah 21589, Saudi Arabia

Reprint 's Address:

  • 王心晨

    [Wang, Xinchen]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China;;[Wang, Xinchen]King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah 21589, Saudi Arabia

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Source :

ACS CATALYSIS

ISSN: 2155-5435

Year: 2018

Issue: 6

Volume: 8

Page: 4928-4936

1 2 . 2 2 1

JCR@2018

1 1 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 425

SCOPUS Cited Count: 434

ESI Highly Cited Papers on the List: 32 Unfold All

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30 Days PV: 4

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