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author:

Cai, Junhu (Cai, Junhu.) [1] | Zhang, Xiang (Zhang, Xiang.) [2] | Chen, Yu (Chen, Yu.) [3] | Lai, Wenzong (Lai, Wenzong.) [4] | Zhang, Wenyan (Zhang, Wenyan.) [5] | Lin, Zexi (Lin, Zexi.) [6] | Ye, Yun (Ye, Yun.) [7] (Scholars:叶芸) | Xu, Sheng (Xu, Sheng.) [8] (Scholars:徐胜) | Guo, Tailiang (Guo, Tailiang.) [9] (Scholars:郭太良) | Luo, Jiajun (Luo, Jiajun.) [10] | Chen, Enguo (Chen, Enguo.) [11] (Scholars:陈恩果)

Indexed by:

EI Scopus SCIE

Abstract:

Inorganic metal halide perovskite quantum dots (PQDs) have recently emerged as promising candidates for color conversion materials in Micro-LED displays, due to their outstanding color purity, high absorption coefficient, tunable emission wavelength. However the inferior stability and undesirable photoluminescence quantum yield (PLQY) restrict their particle applications. Herein, CsPbX3/PMMA (X = Br, I) composites with improved stability and optical performance were successfully prepared by a general and mild in-situ polymerization strategy. The ester carbonyl (C--O) group in MMA formed complexes with Pb2+, leading to the in-situ thermal polymerization of polymethyl methacrylate (PMMA) under the action of the initiator. The multifunctional PMMA can efficiently passivate halogen vacancies while acting as a barrier against the degradation caused by heat, water, and oxygen. As a result, the PLQYs and stability of PMMA-coated CsPbX3 PQDs have been significantly improved. When implementing CsPbX3/PMMA/PDMS composites as color conversion layers in Micro-LEDs, they achieve an impressive color gamut of 127.23% with excellent stability. We believe our work will stimulate the exploration of perovskite/polymer composites for industrial Micro-LED applications.

Keyword:

dots Inorganic metal halide perovskite quantum In-situ polymerization Micro-LED Photoluminescence PMMA

Community:

  • [ 1 ] [Cai, Junhu]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Yu]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 3 ] [Lai, Wenzong]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zhang, Wenyan]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 5 ] [Lin, Zexi]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 6 ] [Ye, Yun]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 7 ] [Xu, Sheng]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 8 ] [Guo, Tailiang]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 9 ] [Chen, Enguo]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China
  • [ 10 ] [Ye, Yun]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 11 ] [Xu, Sheng]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 12 ] [Guo, Tailiang]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 13 ] [Chen, Enguo]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
  • [ 14 ] [Zhang, Xiang]Huazhong Univ Sci & Technol HUST, Wuhan Natl Lab Optoelect WNLO, 1037 Luoyu Rd, Wuhan 430074, Peoples R China
  • [ 15 ] [Luo, Jiajun]Huazhong Univ Sci & Technol HUST, Wuhan Natl Lab Optoelect WNLO, 1037 Luoyu Rd, Wuhan 430074, Peoples R China
  • [ 16 ] [Zhang, Xiang]Huazhong Univ Sci & Technol HUST, Sch Opt & Elect Informat, 1037 Luoyu Rd, Wuhan 430074, Peoples R China
  • [ 17 ] [Luo, Jiajun]Huazhong Univ Sci & Technol HUST, Sch Opt & Elect Informat, 1037 Luoyu Rd, Wuhan 430074, Peoples R China

Reprint 's Address:

  • 陈恩果

    [Chen, Enguo]Fuzhou Univ, Coll Phys & Informat Engn, Natl & Local United Engn Lab Flat Panel Display Te, Fuzhou 350108, Peoples R China;;[Luo, Jiajun]Huazhong Univ Sci & Technol HUST, Wuhan Natl Lab Optoelect WNLO, 1037 Luoyu Rd, Wuhan 430074, Peoples R China;;[Luo, Jiajun]Huazhong Univ Sci & Technol HUST, Sch Opt & Elect Informat, 1037 Luoyu Rd, Wuhan 430074, Peoples R China

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Source :

JOURNAL OF LUMINESCENCE

ISSN: 0022-2313

Year: 2024

Volume: 269

3 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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