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author:

Zhang, Xu (Zhang, Xu.) [1] | Su, Wanlan (Su, Wanlan.) [2] | Guo, Huosheng (Guo, Huosheng.) [3] | Fang, Pengyuan (Fang, Pengyuan.) [4] | Yang, Kai (Yang, Kai.) [5] (Scholars:杨凯) | Song, Qiuling (Song, Qiuling.) [6] (Scholars:宋秋玲)

Indexed by:

EI Scopus SCIE

Abstract:

Skeletal editing of N-heterocycles has recently received considerable attention, and the introduction of boron atom into heterocycles often results in positive property changes. However, direct enlargement of N-heterocycles through boron atom insertion is rarely reported in the literature. Here, we report a N-heterocyclic editing reaction through the combination boron atom insertion and C-H borylation, accessing the fused-BN-heterocycles. The synthetic potential of this chemistry was demonstrated by substrate scope and late-stage diversification of products.

Keyword:

Azaborine C-H Borylation N-Heterocycles Nickel Reductive Coupling

Community:

  • [ 1 ] [Zhang, Xu]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Su, Wanlan]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Guo, Huosheng]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Fang, Pengyuan]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Yang, Kai]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Song, Qiuling]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Song, Qiuling]Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

Reprint 's Address:

  • 杨凯 宋秋玲

    [Yang, Kai]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China;;[Song, Qiuling]Fujian Prov Univ, Coll Chem Fuzhou Univ, Key Lab Mol Synth & Funct Discovery, Fuzhou 350108, Fujian, Peoples R China;;[Song, Qiuling]Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China

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Source :

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN: 1433-7851

Year: 2024

Issue: 10

Volume: 63

1 6 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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