N-Heterocycle-Editing to Access Fused-BN-Heterocycles via Ring-Opening/C−H Borylation/Reductive C−B Bond Formation - Details

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Abstract：

Skeletal　editing　of　N-heterocycles　has　recently　received　considerable　attention,　and　the　introduction　of　boron　atom　into　heterocycles　often　results　in　positive　property　changes.　However,　direct　enlargement　of　N-heterocycles　through　boron　atom　insertion　is　rarely　reported　in　the　literature.　Here,　we　report　a　N-heterocyclic　editing　reaction　through　the　combination　boron　atom　insertion　and　C−H　borylation,　accessing　the　fused-BN-heterocycles.　The　synthetic　potential　of　this　chemistry　was　demonstrated　by　substrate　scope　and　late-stage　diversification　of　products.　©　2024　Wiley-VCH　GmbH.

Keyword：

Atoms Boron Chemical bonds Nickel

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[ 1 ] [Zhang, Xu]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fujian, Fuzhou; 350108, China
[ 2 ] [Su, Wanlan]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fujian, Fuzhou; 350108, China
[ 3 ] [Guo, Huosheng]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fujian, Fuzhou; 350108, China
[ 4 ] [Fang, Pengyuan]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fujian, Fuzhou; 350108, China
[ 5 ] [Yang, Kai]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fujian, Fuzhou; 350108, China
[ 6 ] [Song, Qiuling]Key Laboratory of Molecule Synthesis and Function Discovery, Fujian Province University, College of Chemistry at Fuzhou University, Fujian, Fuzhou; 350108, China
[ 7 ] [Song, Qiuling]School of Chemistry and Chemical Engineering, Henan Normal University, Henan, Xinxiang; 453007, China

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Source ：

Angewandte Chemie - International Edition

ISSN： 1433-7851

Year： 2024

Issue： 10

Volume： 63

1 6 . 1 0 0

JCR@2023

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