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author:

Liu, Pengpeng (Liu, Pengpeng.) [1] | Qiu, Zihui (Qiu, Zihui.) [2] | Shi, Huibing (Shi, Huibing.) [3] | Song, Yu (Song, Yu.) [4] | Zhao, Deming (Zhao, Deming.) [5] | Wang, Pengzhao (Wang, Pengzhao.) [6] (Scholars:王鹏照) | Wang, Tinghai (Wang, Tinghai.) [7] (Scholars:王廷海) | Bao, Xiaojun (Bao, Xiaojun.) [8] (Scholars:鲍晓军)

Indexed by:

EI Scopus SCIE

Abstract:

Aiming at improving reaction selectivity of zeolite Beta-catalyzed isomerization of normal alkane, we reported a facile but efficient route to prepare the Beta@SBA-15 composite supports with low surface diffusion barriers in isomers formation from normal alkane. Microporous Beta zeolite and mesoporous SBA-15 zeolite were physically mixed and milled by high-energy planetary ball-mill. The addition of SBA-15 and milling, which have little effect on the acid properties of Beta zeolites, disaggregate the Beta particles and anchor the Beta nanocrystals on the surface of SBA-15 mesostructure. The apparent diffusivities of 2-methyl pentane measured by zero-length column method increased by 50%. n-Hexane isomerization tests show that the Pt/Beta@SBA-15 catalysts exhibit much higher selectivity to isomers, especially the dibranched isomers and lower selectivity to cracking reaction, owning to the reduced transport limitation of composite supports.

Keyword:

Alkane isomerization Ball milling Beta zeolite Diffusion barriers SBA-15 addition

Community:

  • [ 1 ] [Liu, Pengpeng]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Qiu, Zihui]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Wang, Pengzhao]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Wang, Tinghai]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Bao, Xiaojun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Shi, Huibing]Shandong Chambroad Petrochem Co Ltd, Binzhou 256500, Peoples R China
  • [ 7 ] [Zhao, Deming]Shandong Chambroad Petrochem Co Ltd, Binzhou 256500, Peoples R China
  • [ 8 ] [Song, Yu]Res Inst Refining & Petrochem Beijing Co Ltd, CNOOC, Beijing 102200, Peoples R China
  • [ 9 ] [Wang, Pengzhao]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 10 ] [Wang, Tinghai]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 11 ] [Bao, Xiaojun]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China

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Source :

MICROPOROUS AND MESOPOROUS MATERIALS

ISSN: 1387-1811

Year: 2023

Volume: 356

5 . 2 0 0

JCR@2022

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:26

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 5

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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