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学者姓名：王鹏照
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Abstract ：
Reducing the sulfur content in high-sulfur petroleum coke (HSPC) to below 3.0 % is a big challenge for refineries to meet environmental policy and legal requirements in China. The HSPC examined in this study has a high sulfur content of 7.13 %, with almost all of the sulfur existing in the form of thiophene compounds. The introduction of H2 and the addition of Na2CO3 both promote the sulfur release of HSPC at 800 degrees C. With a 50 % addition of Na2CO3 and the introduction of H2, 87.2 % of the sulfur is released from the HSPC. The details of sulfur distribution during the desulfurization reaction were determined to clarify the roles of H2 and Na2CO3. Thiophene is mainly transformed into gaseous and water-soluble sulfur compounds. The gaseous sulfur includes H2S, elemental sulfur, and sulfur-containing tar (Tar-S). The water-soluble sulfur compounds are primarily sulfides and sulfates adsorbed on the petroleum coke, which can be removed by water washing. The results show that H2 and the addition of Na2CO3 exhibit a synergistic effect on HSPC desulfurization. H2 promotes the hydrogenolysis of C-C and C-S bonds in benzothiophene to form H2S and Tar-S, while Na2CO3 acts as a captor of sulfurcontaining compounds. The findings of this work provide a foundation for the development of a cost-effective and highly efficient industrial desulfurization process.
Keyword ：
High-sulfur petroleum coke High-sulfur petroleum coke Hydrodesulfurization Hydrodesulfurization Sulfur captor Sulfur captor Sulfur removal Sulfur removal
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| GB/T 7714 | Xiong, Wei , Chen, Yanju , Rao, Ying et al. Sulfur distribution and reaction mechanism of sodium carbonate-catalyzed desulfurization of high-sulfur petroleum coke [J]. | JOURNAL OF CLEANER PRODUCTION , 2025 , 508 . |
| MLA | Xiong, Wei et al. "Sulfur distribution and reaction mechanism of sodium carbonate-catalyzed desulfurization of high-sulfur petroleum coke" . | JOURNAL OF CLEANER PRODUCTION 508 (2025) . |
| APA | Xiong, Wei , Chen, Yanju , Rao, Ying , Wang, Jifu , Liu, Huiyong , Wang, Junming et al. Sulfur distribution and reaction mechanism of sodium carbonate-catalyzed desulfurization of high-sulfur petroleum coke . | JOURNAL OF CLEANER PRODUCTION , 2025 , 508 . |
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Aiming to improve the decay in thermochemical energy storage (TCES) performance of CaO-based looping materials with the number of carbonation/calcination cycles, a series of Y/Mg-codoped CaO-based materials were prepared by using the classical sol-gel method and citric acid as a carbon template to enhance the porosity and specific surface area. The structural characterizations showed that Y and Mg were presented in two forms. Part of Y/Mg was presented in the form of Y2O3 and MgO nanoparticles with an average size of 15 and 40 nm, respectively. These Y2O3 and MgO nanoparticles with high Tammann temperature and thermal conductivity were highly dispersed to retard the sintering and growth of CaO grains. The rest of Y and Mg were doped into the framework of the CaO lattice in atomic form by substituting Ca atoms. These Y and Mg created a large amount of the oxygen vacancies surrounding Ca atoms to facilitate the electron transfer from Ca2+ ions to dopants, which enhanced the CO2 capture capacity of CaO-based materials by improving the kinetics of the carbonation reaction. As a result, the optimal CaO-based composite denoted as Ca/Y5/Mg10 exhibited a high initial energy storage density of up to >2300 kJ/kg and held an excellent looping reaction stability after 25 carbonation/calcination cycles owing to the cooperation of Y with Mg additives. This work provided effective and economical CaO-based looping materials for application in thermochemical energy storage.
Keyword ：
CaO-based materials CaO-based materials carbonation/calcination cycles carbonation/calcination cycles sintering resistance sintering resistance thermochemical energy storage thermochemical energy storage Y/Mg codoping Y/Mg codoping
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| GB/T 7714 | Wang, Jifu , Xiong, Wei , Ding, Zhengxin et al. Enhancing the Stability of CaO-Based Looping Materials in Thermochemical Energy Storage by Codoping Y and Mg [J]. | ACS APPLIED ENERGY MATERIALS , 2024 , 7 (24) : 12165-12173 . |
| MLA | Wang, Jifu et al. "Enhancing the Stability of CaO-Based Looping Materials in Thermochemical Energy Storage by Codoping Y and Mg" . | ACS APPLIED ENERGY MATERIALS 7 . 24 (2024) : 12165-12173 . |
| APA | Wang, Jifu , Xiong, Wei , Ding, Zhengxin , Wang, Pengzhao , Long, Jinlin . Enhancing the Stability of CaO-Based Looping Materials in Thermochemical Energy Storage by Codoping Y and Mg . | ACS APPLIED ENERGY MATERIALS , 2024 , 7 (24) , 12165-12173 . |
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We report a facile yet effective strategy to prepare hierarchical Beta zeolite with high molecular transport effectivity in catalysis. Alkaline etching involves preferential desilication from Beta framework and collapse of microporosity. The preferential desilication from outer rim of Beta stacking faults enlarged intercrystallite mesopores, while the collapse of microporosity created cylindroid-like intracrystalline mesopore. Part of Altet with lower stability was removed during alkaline etching, leading to a decrease in acid sites density. Alkaline etching of Beta zeolite with 0.2 mol/L NaOH solution greatly improved n -hexane isomerization activity over Ptbased catalysts. The maximum yield of isohexane and dibranched isomers increased by 6.2 % and 38.6 %, respectively. The enlargement of intercrystallite mesopores and the generation of intracrystalline mesopores of Beta zeolite lowered apparent activation energy of reaction. The apparent diffusivities measurements further revealed that Pt/Beta-0.2 M showed much lower transport limitation than Pt/Beta-parent. Our findings provide a promising catalyst for industrial alkane isomerization.
Keyword ：
Alkaline etching Alkaline etching Alkane isomerization Alkane isomerization Dibranched isomers Dibranched isomers Diffusion barrier Diffusion barrier Mesoporous Beta zeolite Mesoporous Beta zeolite
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| GB/T 7714 | Wang, Pengzhao , Chen, Tingting , Qiu, Zihui et al. Pt-promoted mesoporous Beta zeolite catalysts for n-Hexane isomerization with enhanced selectivity to dibranched isomers [J]. | FUEL , 2024 , 368 . |
| MLA | Wang, Pengzhao et al. "Pt-promoted mesoporous Beta zeolite catalysts for n-Hexane isomerization with enhanced selectivity to dibranched isomers" . | FUEL 368 (2024) . |
| APA | Wang, Pengzhao , Chen, Tingting , Qiu, Zihui , Yao, Wenjun , Liu, Pengpeng , Zhang, Yongze et al. Pt-promoted mesoporous Beta zeolite catalysts for n-Hexane isomerization with enhanced selectivity to dibranched isomers . | FUEL , 2024 , 368 . |
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Developing high-performance Ca-based materials that can work for long-term heat transfer and storage in concentrated solar power plants is crucial to achieve the large-scale conversion of solar photon fluxes to dispatchable electricity. This work demonstrates that a series of Mn, Zr co-doped CaCO3 nanomaterials with the 3D ordered macroporous (3DOM) skeletons are successfully prepared by a novel strategy of templated metal salt co-precipitation. The characterization results indicate that a majority of Zr and Mn are atomically dispersed into the highly-crystallized CaCO3 framework, whereas a minor amount of Mn is present in the form of CaMnO3 nanoparticles (NPs). The optimal 3DOM material made by templating with PS microspheres with a diameter of approximate to 350 nm, 3DOM-Ca80Mn10Zr10, shows a solar light absorptance of approximate to 74.1% and an initial energy storage density of 1706.4 kJ kg(-1). Importantly, it gives an impressive energy storage density loss of < 6.0% and maintains above 1600 kJ kg(-1) after 125 cycles. The density functional theory calculations reveal that the co-doping of Mn and Zr into the CaO crystal lattice offers a strong affinity to [Ca4O4] clusters, as a result, the anti-sintering of CaO NPs is significantly enhanced under high temperature.
Keyword ：
CaCO3 CaCO3 Ca-looping Ca-looping ordered macropores ordered macropores photonic crystals photonic crystals thermochemical energy storage thermochemical energy storage
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| GB/T 7714 | Li, Han , Lin, Jinfeng , Wu, Jianze et al. 3D Ordered Macroporous Mn, Zr-Doped CaCO3 Nanomaterials for Stable Thermochemical Energy Storage [J]. | ADVANCED SCIENCE , 2024 , 12 (6) . |
| MLA | Li, Han et al. "3D Ordered Macroporous Mn, Zr-Doped CaCO3 Nanomaterials for Stable Thermochemical Energy Storage" . | ADVANCED SCIENCE 12 . 6 (2024) . |
| APA | Li, Han , Lin, Jinfeng , Wu, Jianze , Wang, Jiashun , Wang, Pengzhao , Kang, Guojian et al. 3D Ordered Macroporous Mn, Zr-Doped CaCO3 Nanomaterials for Stable Thermochemical Energy Storage . | ADVANCED SCIENCE , 2024 , 12 (6) . |
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The chemical enhancement of semiconductor-based surface-enhanced Raman scattering (SERS) substrates is an exciting hot topic. Herein, a simple hydrothermal method is developed to prepare molybdenum disulfide (MoS2), which can be easily exfoliated into monolayer nanosheets (MoS(2)NSs) by sonication, even in the absence of any surfactant. The obtained MoS(2)NSs contain two types of defects, namely, one caused by the incorporation of Mo atoms of high valence states and one caused by the incorporation of S-2(2-). The density of the two types of defects can be easily tuned by controlling the ratio of Na2S and Na2MoO4 in the raw materials. The unique properties and the clear surface make the obtained MoS(2)NSs ideal models to investigate the effect of defects on the SERS activity of MoS2. It is found that the SERS activity of the obtained MoS(2)NSs increases dramatically with the defects caused by Mo atoms of high valence states, while it first increases and then decreases with the increase of defects caused by S-2(2-). On the basis, MoS(2)NSs with high SERS activity and a low detection limit of 5.0 x 10(-9) mol/L toward crystal violet (CV) are obtained. Moreover, the mechanism of defects affecting the SERS activity of MoS(2)NSs is revealed. The defects on one hand provide a large amount of dangling bonds that can combine CV molecules to form MoS2NS-CV complex and on the other hand provide extensive induced local dipoles and enhance the overall SERS spectrum of CV.
Keyword ：
chemical enhancement chemical enhancement crystal violet crystal violet defects defects molybdenum disulfidenanosheets molybdenum disulfidenanosheets surface-enhanced Raman scattering surface-enhanced Raman scattering
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| GB/T 7714 | Fu, Xiaolong , Wu, Huiying , Liu, Zhihong et al. MoS2 Nanosheets as Substrates for SERS-Based Sensing [J]. | ACS APPLIED NANO MATERIALS , 2024 , 7 (4) : 3988-3996 . |
| MLA | Fu, Xiaolong et al. "MoS2 Nanosheets as Substrates for SERS-Based Sensing" . | ACS APPLIED NANO MATERIALS 7 . 4 (2024) : 3988-3996 . |
| APA | Fu, Xiaolong , Wu, Huiying , Liu, Zhihong , Wang, Pengzhao , Rong, Jiefeng , Fu, Fengfu et al. MoS2 Nanosheets as Substrates for SERS-Based Sensing . | ACS APPLIED NANO MATERIALS , 2024 , 7 (4) , 3988-3996 . |
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本发明公开了一种利用FCC废催化剂制备SSZ‑13分子筛的方法及其应用，属于分子筛合成领域。该方法包括以下步骤：将FCC废催化剂分散到碱溶液中，然后加入模板剂、补充硅源和铝源，混合物在一定温度下持续搅拌直至水分蒸干形成干凝胶，研磨成粉后，转移到聚四氟乙烯烧杯中，然后将其移入装有一定量水的聚四氟乙烯内衬的高压釜中，使干凝胶不与反应釜中的水直接接触进行蒸汽辅助结晶，最后经洗涤、过滤、高温焙烧得到SSZ‑13分子筛。本发明以FCC废催化剂为原料合成具有高结晶度的SSZ‑13分子筛，充分利用了废催化剂中所含的稀土金属，使所获得的SSZ‑13分子筛中富含稀土金属元素，提高了其在以NH3为还原剂的选择性催化还原(NH3‑SCR)反应中的水热稳定性。
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| GB/T 7714 | 岳源源 , 汪雪琴 , 鲍晓军 et al. 一种利用FCC废催化剂制备SSZ-13分子筛的方法及其应用 : CN202210640182.3[P]. | 2022-06-07 00:00:00 . |
| MLA | 岳源源 et al. "一种利用FCC废催化剂制备SSZ-13分子筛的方法及其应用" : CN202210640182.3. | 2022-06-07 00:00:00 . |
| APA | 岳源源 , 汪雪琴 , 鲍晓军 , 李铁森 , 王婵 , 王廷海 et al. 一种利用FCC废催化剂制备SSZ-13分子筛的方法及其应用 : CN202210640182.3. | 2022-06-07 00:00:00 . |
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本发明公开了一种小晶粒SAPO‑11分子筛的快速制备方法，包括以下步骤：将水、磷源、铝源、模板剂搅拌均匀在一定温度下预晶化，结束后取出产物加入硅源和有机酸，再次搅拌均匀后进行水热晶化，晶化结束后离心得到固体产物，最后高温焙烧脱除模板剂即得到所述分子筛。水热晶化是目前合成SAPO‑11分子筛最常用的方法，但其存在反应周期长(≥24h)，生成的晶核表面吉布斯自由能过高，晶粒自聚倾向高，颗粒尺寸大、比表面积低的缺点，从而导致反应物及产物在催化剂上的扩散速率慢、裂化严重或选择性低。本发明通过在合成体系中加入有机酸的方式调控分子筛成核和生长策略，不仅可大幅度降低反应周期，且有效抑制分子筛晶粒尺寸。
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| GB/T 7714 | 鲍晓军 , 池招全 , 岳源源 et al. 一种小晶粒SAPO-11分子筛的快速制备方法 : CN202210063904.3[P]. | 2022-01-20 00:00:00 . |
| MLA | 鲍晓军 et al. "一种小晶粒SAPO-11分子筛的快速制备方法" : CN202210063904.3. | 2022-01-20 00:00:00 . |
| APA | 鲍晓军 , 池招全 , 岳源源 , 王婵 , 王廷海 , 王鹏照 et al. 一种小晶粒SAPO-11分子筛的快速制备方法 : CN202210063904.3. | 2022-01-20 00:00:00 . |
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本发明的目的是为提高催化裂化汽油(FCC汽油)加氢脱硫催化剂的活性和选择性，提供一种改善金属分散性能的加氢脱硫催化剂制备方法，属于石油化工中的加氢脱硫领域。本发明的催化剂制备过程包括三个步骤：首先采用凝胶制备技术将活性金属制备成凝胶前驱体；其次将上述得到的凝胶前驱体与拟薄水铝石机械混合、挤条成型；最后经干燥、高温焙烧制得CoMo/Al2O3催化剂。本发明制备的催化剂用于FCC汽油加氢脱硫反应中表现出更高的脱硫活性和选择性。
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| GB/T 7714 | 鲍晓军 , 李俊锋 , 王廷海 et al. 一种催化裂化汽油加氢脱硫催化剂及其制备方法 : CN202210232599.6[P]. | 2022-03-10 00:00:00 . |
| MLA | 鲍晓军 et al. "一种催化裂化汽油加氢脱硫催化剂及其制备方法" : CN202210232599.6. | 2022-03-10 00:00:00 . |
| APA | 鲍晓军 , 李俊锋 , 王廷海 , 王鹏照 . 一种催化裂化汽油加氢脱硫催化剂及其制备方法 : CN202210232599.6. | 2022-03-10 00:00:00 . |
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本发明公开了一种用于丙烷脱氢制丙烯的Pt@多级孔沸石催化剂及其制备方法，该催化剂的特征为：以纯硅多级孔沸石为载体；活性组分为Pt，其中Pt以团簇的形式存在沸石的微孔中；助剂金属为Sn、Zn或者Ge，这些助剂金属与Pt相互作用形成合金。本发明利用介孔模板的作用一锅法合成出多级孔沸石封装的Pt@多级孔沸石催化剂，由于介孔优异的传质性能显著提高反应物和产物在孔道内的传输速率，从而最大限度的提高Pt的利用率并降低催化剂的积碳失活速率。催化剂应用于丙烷脱氢催化反应，表现出远超其他沸石催化剂的性能。
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| GB/T 7714 | 朱海波 , 路晋阳 , 鲍晓军 et al. 一种用于丙烷脱氢制丙烯的Pt@多级孔沸石催化剂及其制备方法 : CN202210309262.0[P]. | 2022-03-28 00:00:00 . |
| MLA | 朱海波 et al. "一种用于丙烷脱氢制丙烯的Pt@多级孔沸石催化剂及其制备方法" : CN202210309262.0. | 2022-03-28 00:00:00 . |
| APA | 朱海波 , 路晋阳 , 鲍晓军 , 白正帅 , 岳源源 , 王鹏照 . 一种用于丙烷脱氢制丙烯的Pt@多级孔沸石催化剂及其制备方法 : CN202210309262.0. | 2022-03-28 00:00:00 . |
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采用"共沉淀-浸渍"法制备了一系列不同铝质量分数的Pt/SO42--(ZrO2-Al2O3)催化剂,并考察了其催化异丁烷正构化反应性能.结果表明,适量铝的加入抑制了热力学上处于亚稳态的四方相ZrO2向单斜相的转变,提高了催化剂表面的固硫能力,促进了催化剂表面超强酸性位的形成.铝掺杂质量分数为3％的催化剂具有最佳的催化异丁烷正构化反应性能,在250℃时异丁烷转化率和正丁烷选择性分别达45.47％和79.67％.
Keyword ：
异丁烷正构化 异丁烷正构化 超强酸性位 超强酸性位 铝掺杂 铝掺杂 锆基催化剂 锆基催化剂
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| GB/T 7714 | 张海洪 , 辛靖 , 宋宇 et al. Al掺杂对Pt/SO42--(ZrO2-Al2O3)催化异丁烷正构化反应性能的影响研究 [J]. | 现代化工 , 2023 , 43 (10) : 148-153 . |
| MLA | 张海洪 et al. "Al掺杂对Pt/SO42--(ZrO2-Al2O3)催化异丁烷正构化反应性能的影响研究" . | 现代化工 43 . 10 (2023) : 148-153 . |
| APA | 张海洪 , 辛靖 , 宋宇 , 曾土城 , 范文轩 , 王廷海 et al. Al掺杂对Pt/SO42--(ZrO2-Al2O3)催化异丁烷正构化反应性能的影响研究 . | 现代化工 , 2023 , 43 (10) , 148-153 . |
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