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学者姓名：鲍晓军
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Abstract ：
以苯胺和N-羟基邻苯二甲酰亚胺(NHPI)为原料,经缩合偶联反应得到N-苯基邻苯二甲酰亚胺,产物经核磁共振氢谱确证.缩合偶联反应的优化条件为:以2,2'-联吡啶为助催化剂,氯化亚铜(CuCl)为催化剂,物料比n(2,2'-联吡啶)∶n(氯化亚铜)∶n(苯胺)∶n(N-羟基邻苯二甲酰亚胺)=0.1∶0.2∶1.0∶1.0,乙腈为溶剂、温度为70 ℃、反应时间为4 h,反应气体环境为氧气,产物收率达82.0％.
Keyword ：
2 2 2’-联吡啶 2’-联吡啶 N-羟基邻苯二甲酰亚胺 N-羟基邻苯二甲酰亚胺 N-苯基邻苯二甲酰亚胺 N-苯基邻苯二甲酰亚胺 氯化亚铜 氯化亚铜 苯胺 苯胺
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| GB/T 7714 | 南沛然 , 王博闻 , 李世云 et al. N-苯基邻苯二甲酰亚胺的合成 [J]. | 精细石油化工 , 2025 , 42 (2) : 48-51 . |
| MLA | 南沛然 et al. "N-苯基邻苯二甲酰亚胺的合成" . | 精细石油化工 42 . 2 (2025) : 48-51 . |
| APA | 南沛然 , 王博闻 , 李世云 , 文彬 , 陈兴权 , 鲍晓军 . N-苯基邻苯二甲酰亚胺的合成 . | 精细石油化工 , 2025 , 42 (2) , 48-51 . |
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Electrochemical biomass upgrading is a promising substitute for oxygen evolution reaction (OER) to generate valuable chemicals in conjunction with hydrogen generation. Pursuing highly efficient and durable electrocatalysts for significant concentration levels (≥ 50 mM) of biomass electrooxidation remains an enduring challenge. Herein, we introduce a robust Cu-supported CoFe Prussian blue analogue (CoFe PBA/CF) electrocatalyst, adept at facilitating high-concentration (50 mM) 5-hydroxymethylfurfural (HMF) oxidation into 2,5-furandicarboxylic acid (FDCA), achieving an exceptional HMF conversion (100%) with a notable FDCA yield of 98.4%. The influence of copper substrate and adsorption energy are therefore discussed. Impressively, the CoFe PBA/CF electrode sustains considerable durability in a continuous-flow electrochemical reactor designed for consecutive FDCA production, showcasing FDCA yields of 100/94% at flow rates of 0.4/0.8 mL·min-1 over 60 h’ uninterrupted electrolysis. This work provides a promising strategy to develop highly efficient and robust electrocatalysts for the consecutive production of high-value products coupled with green H2 production. © The Author(s) 2025.
Keyword ：
5-hydroxymethylfurfural oxidation 5-hydroxymethylfurfural oxidation CoFe Prussian blue analogues CoFe Prussian blue analogues electrochemical conversion electrochemical conversion high concentration high concentration structural reconstruction structural reconstruction
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| GB/T 7714 | Zhang, B. , Xiao, T. , Hu, C. et al. Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues [J]. | Chemical Synthesis , 2025 , 5 (1) . |
| MLA | Zhang, B. et al. "Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues" . | Chemical Synthesis 5 . 1 (2025) . |
| APA | Zhang, B. , Xiao, T. , Hu, C. , Liu, Z. , Chen, P. , Zhao, Z. et al. Continuous-flow electrooxidation for scalable biomass upgrading over copper-supported CoFe Prussian blue analogues . | Chemical Synthesis , 2025 , 5 (1) . |
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Deep hydrogenation of dicyclopentadiene resin (DCPD resin) plays an important role in enhancing its performance and broadening its applications. However, designing suitable catalysts for promoting DCPD resin deep hydrogenation remains a challenge due to the high steric hindrance and abundant unsaturated bonds in DCPD resin, requiring strong binding to C=C double bonds. We herein propose a strategy for simultaneously constructing highly-dispersed Ni particles for hydrogen dissociation and interfacial Ni0/Ni(OH)+ sites for C=C adsorption by controlled reduction of Ni phyllosilicate (Ni PS). The catalyst, after reduction at 400 degrees C, demonstrated balanced ratio between Ni0 and interfacial Ni0/Ni(OH)+ sites, and achieved a hydrogenation degree of 99.8% (TOF: 68.8 h-1) while maintaining 99.3% efficiency after seven consecutive cycles. Through in-situ DRIFTS analysis and density functional theory (DFT) calculations, it is confirmed that the introduction of Ni0/Ni(OH)+ interfacial sites results in superior activity compared to pure Ni0 or unreduced PS due to optimized charge transfer and electronic configuration. This work not only establishes a simple and environmentally-friendly approach to design efficient catalysts for polymer hydrogenation, but also provides insights into the mechanism of unsaturated bond hydrogenation through the synergistic effects of Ni0 and Ni0/Ni(OH)+ interfacial sites.
Keyword ：
DCPD resin DCPD resin Hydrogenation Hydrogenation Ni(OH) plus Ni(OH) plus Ni phyllosilicate Ni phyllosilicate
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| GB/T 7714 | Liu, Qunhong , Liu, Zhen , Yang, Zongxuan et al. Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin [J]. | CHEMICAL ENGINEERING JOURNAL , 2025 , 512 . |
| MLA | Liu, Qunhong et al. "Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin" . | CHEMICAL ENGINEERING JOURNAL 512 (2025) . |
| APA | Liu, Qunhong , Liu, Zhen , Yang, Zongxuan , Wu, Qingchen , Li, Zimeng , Liu, Zhichen et al. Deciphering Ni0/Ni(OH)+ interfacial sites for deep hydrogenation of dicyclopentadiene resin . | CHEMICAL ENGINEERING JOURNAL , 2025 , 512 . |
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Elucidating the microstructure of hard carbon is essential for uncovering the sodium storage mechanism and constructing state-of-the-art hard carbon anodes for sodium-ion batteries. Guided by an understanding of the crystallization process and inverse materials design principles, we design hard carbon anodes with different local fragments to understand the correlation between the microstructure of hard carbon and sodium storage behavior from the commercialization perspective. The sodiation transformation of hard carbon from slope- to plateau-type is realized via a series of local structure rearrangements, including tuning of the interlayer distance, average crystallite width of graphitic domains, and defect density. We found that the increase in plateau capacity is mainly related to the transition from the critical interlayer distance to the average crystallite width of graphitic domain control, and is limited by the closed pore volume of hard carbon. During sodiation, the formation of NaF and Na2O in the slope region, as well as Na2O2 and NaO2 in the plateau region, is always accompanied by the production of Na2CO3. This work provides insights into understanding the sodium storage behavior in hard carbon anodes and defines general structural design principles for transitioning from slope-type to plateau-type hard carbon.
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| GB/T 7714 | Wang, Feng , Chen, Lian , Wei, Jiaqi et al. Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement [J]. | ENERGY & ENVIRONMENTAL SCIENCE , 2025 , 18 (9) : 4312-4323 . |
| MLA | Wang, Feng et al. "Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement" . | ENERGY & ENVIRONMENTAL SCIENCE 18 . 9 (2025) : 4312-4323 . |
| APA | Wang, Feng , Chen, Lian , Wei, Jiaqi , Diao, Caozheng , Li, Fan , Du, Congcong et al. Pushing slope- to plateau-type behavior in hard carbon for sodium-ion batteries via local structure rearrangement . | ENERGY & ENVIRONMENTAL SCIENCE , 2025 , 18 (9) , 4312-4323 . |
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In order to gain insight into the influence of SiO2 support particle size on the vacuum residue (VR) slurry-phase hydrocracking performance of Fe-based catalysts, a series of FeZn/SiO2 catalysts with varying SiO2 particle sizes were prepared. Characterization results show that the surface area and pore volume of the FeZn/SiO2 catalysts increase with the reduction of SiO2 particle sizes. The metals Fe and Zn species on FeZn/SiO2-S catalyst are more readily reducible via H2-TPR analysis. Notably, FeZn/SiO2-S catalyst presents higher metal dispersion and a greater degree of sulfurization compared to the other catalysts by XRD and XPS. Hydrocracking results demonstrate that the FeZn/SiO2-S catalyst achieves the lowest coke and gas yields (11.9 wt% and 0.4 wt%), respectively, and the highest VR conversion among these catalysts. The superior performance of the FeZn/SiO2-S catalyst in VR slurry-phase hydrocracking is ascribed to its enhanced hydrogenation activity, deriving from the higher dispersion and sulfurization of metals species. This suppresses the aggregation of polycyclic aromatic hydrocarbons in VR and the over-cracking of intermediate products. Additionally, the increased mesopore associated with smaller SiO2 particles facilitates to the diffusion of large VR molecules, further promoting the hydrocracking reaction.
Keyword ：
FeZn catalyst FeZn catalyst Hydrogenation activity Hydrogenation activity SiO2 particle size SiO2 particle size Slurry-phase hydrocracking Slurry-phase hydrocracking Vacuum residue Vacuum residue
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| GB/T 7714 | Wang, Jianbo , Yan, Jianteng , Cui, Qingyan et al. Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking [J]. | CATALYSIS TODAY , 2025 , 449 . |
| MLA | Wang, Jianbo et al. "Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking" . | CATALYSIS TODAY 449 (2025) . |
| APA | Wang, Jianbo , Yan, Jianteng , Cui, Qingyan , Li, Tiesen , Shi, Jie , Wang, Tinghai et al. Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking . | CATALYSIS TODAY , 2025 , 449 . |
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采用Sandmeyer法以3-氯-2-甲基苯胺为原料,亚硝酸钠为重氮化试剂,在低温、酸性环境下得到重氮盐,再利用铜基催化剂、不同温度的条件下分解,得到2-氯-6-溴甲苯.适宜合成条件为:以30％硫酸溶解胺,以亚硝酸钠的硫酸溶液成盐,以氢溴酸为溴源、铜粉为催化剂、在0 ℃分解.其中,酸用量为原料的5倍,n(3-氯-2-甲基苯胺)∶n(亚硝酸钠)∶n(铜粉)∶n(工业氢溴酸)=1∶1.2∶0.1∶1.2,2-溴-6-氯甲苯的收率可达95％.
Keyword ：
2-溴-6-氯甲苯 2-溴-6-氯甲苯 3-氯-2-甲基苯胺 3-氯-2-甲基苯胺 Sandmeyer反应 Sandmeyer反应 亚硝酸钠 亚硝酸钠 重氮盐 重氮盐
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| GB/T 7714 | 王博闻 , 南沛然 , 李世云 et al. Sandmeyer法合成2-溴-6-氯甲苯 [J]. | 精细石油化工 , 2025 , 42 (1) : 23-26 . |
| MLA | 王博闻 et al. "Sandmeyer法合成2-溴-6-氯甲苯" . | 精细石油化工 42 . 1 (2025) : 23-26 . |
| APA | 王博闻 , 南沛然 , 李世云 , 文彬 , 陈兴权 , 鲍晓军 . Sandmeyer法合成2-溴-6-氯甲苯 . | 精细石油化工 , 2025 , 42 (1) , 23-26 . |
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Polyethylene oxide (PEO)-based electrolytes are essential to advance all-solid-state lithium batteries (ASSLBs) with high safety/energy density due to their inherent flexibility and scalability. However, the inefficient Li+ transport in PEO often leads to poor rate performance and diminished stability of the ASSLBs. The regulation of intermolecular H-bonds is regarded as one of the most effective approaches to enable efficient Li+ transport, while the practical performances are hindered by the electrochemical instability of free H-bond donors and the constrained mobility of highly ordered H-bonding structures. To overcome these challenges, we develop a surface-confined disordered H-bond system with stable donor-acceptor interactions to construct a loosened chain segments/ions arrangement in the bulk phase of PEO-based electrolytes, realizing the crystallization inhibition of PEO, weak coordination of Li+ and entrapment of anions, which are conducive to efficient Li+ transport and stable Li+ deposition. The rationally designed LiFePO4-based ASSLB demonstrates a long cycle-life of over 400 cycles at 1.0 C and 65 degrees C with a capacity retention rate of 87.5 %, surpassing most of the currently reported polymer-based ASSLBs. This work highlights the importance of confined disordered H-bonds on Li+ transport in an all-solid-state battery system, paving the way for the future design of polymer-based ASSLBs.
Keyword ：
all-solid-state Li batteries all-solid-state Li batteries H-bond H-bond Li+ transport Li+ transport polyethylene oxide polyethylene oxide polymer electrolytes polymer electrolytes
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| GB/T 7714 | Fan, You , Malyi, Oleksandr I. , Wang, Huicai et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery [J]. | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
| MLA | Fan, You et al. "Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery" . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2025) . |
| APA | Fan, You , Malyi, Oleksandr I. , Wang, Huicai , Cheng, Xiangxin , Fu, Xiaobin , Wang, Jingshu et al. Surface-Confined Disordered Hydrogen Bonds Enable Efficient Lithium Transport in All-Solid-State PEO-Based Lithium Battery . | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION , 2025 . |
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The heterogeneous selective hydrogenation of nitrile butadiene rubber (NBR) is an efficient method to generate high value-added hydrogenated NBR. Nevertheless, the inherent large molecular size and high spatial hindrance of polymers lead to poor activity and metal loss. Herein, we report a simple support ammonia pretreatment strategy for the synthesis of efficient N-doped Pd catalyst and applied for the NBR hydrogenation. The results reveal that N doping enhances electron transfer from the support to Pd more effectively than oxygen-rich vacancy support, thereby substantially enhancing the electron cloud density and stability of the Pd sites. The formation of more electron-rich Pd sites not only significantly enhances the adsorption-activation ability of C=C and H2, but also lowers the apparent activation energy of the reaction. As a result, the Pd/N-TiO2-R demonstrates best activity with a hydrogenation degree (HD) of 98 % and a TOF value of 335 h-1, significantly higher than that of Pd/TiO2-R (HD=83 %, 282 h-1) and Pd/TiO2 (HD=74 %, 204 h-1). This strategy will provide new inspiration to improve the activity and stability of Pd/TiO2 catalysts for the hydrogenation of unsaturated polymers.
Keyword ：
Electron density Electron density Hydrogenation Hydrogenation N doping N doping Oxygen vacancies Oxygen vacancies Pd catalyst Pd catalyst
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| GB/T 7714 | Wang, Shidong , Fan, Benwei , Ge, Bingqing et al. Regulating the Electronic Structure of Pd Nanoparticles on NH3-Pretreated Nano-Flake TiO2 for Efficient Hydrogenation of Nitrile Butadiene Rubber [J]. | CHEMCATCHEM , 2024 , 16 (23) . |
| MLA | Wang, Shidong et al. "Regulating the Electronic Structure of Pd Nanoparticles on NH3-Pretreated Nano-Flake TiO2 for Efficient Hydrogenation of Nitrile Butadiene Rubber" . | CHEMCATCHEM 16 . 23 (2024) . |
| APA | Wang, Shidong , Fan, Benwei , Ge, Bingqing , Zhang, Hongwei , Hu, Cejun , Cui, Qinyang et al. Regulating the Electronic Structure of Pd Nanoparticles on NH3-Pretreated Nano-Flake TiO2 for Efficient Hydrogenation of Nitrile Butadiene Rubber . | CHEMCATCHEM , 2024 , 16 (23) . |
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Electrocatalytic oxidation as a promising route to produce value-added products from biomass-derived organics has received increasing attention in recent years. However, the efficient conversion of concentrated feedstock solutions with high selectivity and Faradaic efficiency (FE) remains challenging. Herein, we report a cation-defective Ni-based electrocatalyst derived from the surface reconstruction of the NiCo Prussian blue analogue (NiCo PBA) in alkaline media for the efficient oxidation of biomass-derived organics in a high concentration solution. Taking 5-hydroxymethylfurfural (HMF) as an example, the NiCo PBA can deliver a satisfactory catalytic performance in terms of high HMF conversion (97%), selectivity to 2,5-furandicarboxylic acid (98%), and FE (100%), even at a concentration as high as 100 mM. Theoretical calculations suggest that the cation defects not only promote the fast conversion of Ni(OH)(2) to electrochemically active NiOOH under anodic potential but also enhance the adsorption of HMF onto the active sites and accelerate the spontaneous chemical oxidation. This study provides deep insights into the structural evolution of PBA-based catalysts and reveals the pivotal factor that affects the performance of electrocatalytic oxidation, paving the way to further develop advanced electrocatalysts for efficient oxidation reactions with a high concentration.
Keyword ：
biomass upgrade biomass upgrade cation defects cation defects electrooxidation electrooxidation operandoRaman spectroscopies operandoRaman spectroscopies Prussian blue analogues catalysts Prussian blue analogues catalysts
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| GB/T 7714 | Zhang, Hongwei , Yang, Qin , Luo, Shuting et al. On the Activity and Selectivity of 5-Hydroxymethylfurfural Electrocatalytic Oxidation over Cation-Defective Nickel Hydroxides [J]. | ACS CATALYSIS , 2024 , 14 (12) : 9565-9574 . |
| MLA | Zhang, Hongwei et al. "On the Activity and Selectivity of 5-Hydroxymethylfurfural Electrocatalytic Oxidation over Cation-Defective Nickel Hydroxides" . | ACS CATALYSIS 14 . 12 (2024) : 9565-9574 . |
| APA | Zhang, Hongwei , Yang, Qin , Luo, Shuting , Liu, Zhichen , Huang, Jinming , Zheng, Yun et al. On the Activity and Selectivity of 5-Hydroxymethylfurfural Electrocatalytic Oxidation over Cation-Defective Nickel Hydroxides . | ACS CATALYSIS , 2024 , 14 (12) , 9565-9574 . |
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Synthesizing zeolites, which are important materials used in the petroleum and chemical industries, from natural aluminosilicate minerals has been qualitatively recognized as a greener approach compared to that from traditional Si- and Al-containing chemicals; however, studies on the quantitative environmental impacts are still lacking. Herein, life cycle assessment (LCA) and green metrics (atom economy and environmental factor) were employed to comparatively assess the life cycle environmental impacts of zeolites synthesized from chemicals and natural minerals at the industrial scale. The values of seven LCA impact categories and sensitivity analysis between them were thoroughly compared. The results showed that, for each category, the synthesis from natural minerals has lower environmental impacts to varying degrees than that from chemicals. Further efficiency analysis of zeolite manufacturing technologies by green metrics indicated that the synthesis from natural minerals outperforms that from chemicals in terms of the resource utilization rate. The quantitative results indicate that significant benefits stem from the replacement of raw materials from chemicals to natural minerals. This work may provide a basis for the future selection and upgrade of zeolite production processes. Life cycle assessment and green metrics were used to comparatively assess the synthesis of zeolites from natural minerals and chemicals in which the former exhibits a better balance between efficiency and environmental impacts than the latter.
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| GB/T 7714 | Chen, Xiaoling , Xiao, Guoxi , Li, Tiesen et al. Comparative environmental assessment of zeolites synthesized from chemicals and natural minerals [J]. | GREEN CHEMISTRY , 2024 , 26 (9) : 5273-5283 . |
| MLA | Chen, Xiaoling et al. "Comparative environmental assessment of zeolites synthesized from chemicals and natural minerals" . | GREEN CHEMISTRY 26 . 9 (2024) : 5273-5283 . |
| APA | Chen, Xiaoling , Xiao, Guoxi , Li, Tiesen , Wang, Chan , Cui, Qingyan , Bao, Xiaojun et al. Comparative environmental assessment of zeolites synthesized from chemicals and natural minerals . | GREEN CHEMISTRY , 2024 , 26 (9) , 5273-5283 . |
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