Rhodium-Catalyzed Intramolecular Cyclization to Synthesize 2-Aminobenzofurans via Carbene Metathesis Reactions - Details

author：

Li, X. (Li, X..) ^[1] | Sheng, H. (Sheng, H..) ^[2] | Song, Q. (Song, Q..) ^[3]

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Abstract：

Herein,　we　report　a　new　method　of　synthesizing　of　2-aminobenzofuran　3-enes　via　the　formal　C-S　insertion　reaction　of　alkyne-tethered　diazo　compounds.　Metal　carbene,　as　a　kind　of　active　synthetic　intermediate,　plays　a　very　important　role　in　organic　synthesis.　Through　the　carbene/alkyne　metathesis　strategy,　a　new　donor　carbene　is　produced　in　situ　as　a　key　intermediate,　which　has　different　reactions　from　the　donor　receptor　carbene.　©　2023　American　Chemical　Society.

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[ 1 ] [Li, X.]Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Material Sciences Engineering, Huaqiao University, 668 Jimei Blvd, Fujian, Xiamen, 361021, China
[ 2 ] [Sheng, H.]Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Material Sciences Engineering, Huaqiao University, 668 Jimei Blvd, Fujian, Xiamen, 361021, China
[ 3 ] [Song, Q.]Institute of Next Generation Matter Transformation, College of Chemical Engineering, College of Material Sciences Engineering, Huaqiao University, 668 Jimei Blvd, Fujian, Xiamen, 361021, China
[ 4 ] [Song, Q.]Key Laboratory of Molecule Synthesis and Function Discovery (Fijian Province University), College of Chemistry, Fuzhou University, Fujian, Fuzhou, 350108, China
[ 5 ] [Song, Q.]School of Chemistry and Chemical Engineering, Henan Normal University, Henan, Xinxiang, 453007, China

Reprint 's Address：

[Song, Q.]Institute of Next Generation Matter Transformation, 668 Jimei Blvd, Fujian, China

Email：

qsong@hqu.edu.cn

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Source ：

Organic Letters

ISSN： 1523-7060

Year： 2023

Issue： 12

Volume： 25

Page： 2113-2117

4 . 9

JCR@2023

4 . 9 0 0

JCR@2023

ESI HC Threshold：39

JCR Journal Grade：1

CAS Journal Grade：1

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WoS CC Cited Count： 0

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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