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author:

Xue, Jiahao (Xue, Jiahao.) [1] | Zhang, Jing (Zhang, Jing.) [2] | Zhao, Yulai (Zhao, Yulai.) [3] (Scholars:赵玉来) | Cai, Jingyu (Cai, Jingyu.) [4] (Scholars:蔡静宇) | Xiao, Longqiang (Xiao, Longqiang.) [5] (Scholars:肖龙强) | Hou, Linxi (Hou, Linxi.) [6] (Scholars:侯琳熙)

Indexed by:

EI Scopus SCIE

Abstract:

In this work, a series of N-doped porous carbons (NPCs) are prepared via high internal phase emulsion (HIPE) template, followed by growing polyaniline (PANI) arrays and subsequent carbonization/activation. As evidenced by SEM and N2 absorption/desorption results, the NPCs have interconnected hierarchical porous structures with abundant micropores and mesopores inside. The morphology and porous structures of NPCs can be tuned by changing aniline concentration and polymerization time, respectively. With the increase of aniline concentration or polymerization time, the porous structure of NPC becomes more and more serried, however too high aniline concentration (>0.75 M) makes the porous structure become sparse, which is because excess PANI will nucleate itself and make it detach from the surface of NPC. As a result, the specific surface area (SSA) of NPCs first in-creases to 1769 m2/g and then decreases. Electrochemical performances of the obtained NPCs are evaluated in detail. The test results indicate that both aniline concentration and polymerization time have notable influence on the specific capacitance of NPCs. The specific capacitance of NPC obtained under optimized conditions reaches up to 241 F/g at 1 A/g with a retention ratio of 97.8% after 10, 000 cycles at a high current density, proving its excellent energy storage capability and cycling stability. In two-electrode system, the NPC provides an energy density of 27 Wh/kg at a power density of 400 W/kg and remains a high energy density of 19 Wh/kg at a high power density of 10002 W/kg.

Keyword:

High internal phase emulsion N -doped porous carbons Polyaniline nanoarray Supercapacitor

Community:

  • [ 1 ] [Xue, Jiahao]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Zhang, Jing]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Zhao, Yulai]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 4 ] [Cai, Jingyu]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Xiao, Longqiang]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 7 ] [Zhao, Yulai]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 8 ] [Cai, Jingyu]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 9 ] [Xiao, Longqiang]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 10 ] [Hou, Linxi]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China

Reprint 's Address:

  • [Zhao, Yulai]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China;;[Xiao, Longqiang]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China;;

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Source :

MATERIALS CHEMISTRY AND PHYSICS

ISSN: 0254-0584

Year: 2023

Volume: 301

4 . 3

JCR@2023

4 . 3 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:49

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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