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author:

Wang, Chan (Wang, Chan.) [1] (Scholars:王婵) | Xiao, Guoxi (Xiao, Guoxi.) [2] | Guo, Xiaoxue (Guo, Xiaoxue.) [3] | Xu, Renwei (Xu, Renwei.) [4] | Yue, Yuanyuan (Yue, Yuanyuan.) [5] (Scholars:岳源源) | Bao, Xiaojun (Bao, Xiaojun.) [6] (Scholars:鲍晓军)

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EI PKU CSCD

Abstract:

As an important catalytic material, Beta zeolite is widely used in petrochemical, coal chemical and environmental protection fields, but its conventional hydrothermal synthesis process has problems such as high cost, low yield per kettle and large waste water discharge. This article presents a green and economic strategy to synthesize Beta zeolite from natural mineral via a mesoscale depolymerization-reorganization approach. The proposed methodology results in a Beta zeolite (denoted as Beta-Anhyd) owning abundant meso- and macro-pores, larger specific surface area and lower acid amount than a commercial sample (Beta-Ref). The Beta-Anhyd derived catalyst (Beta-Anhyd-Deal) that was prepared by a two-step post-synthesis method consisting of the dealumination of Beta-Anhyd and the incorporation of tin shows much better catalytic performance in the propane dehydrogenation reaction than the reference one (Beta-Ref-Deal). © 2022 Chemical Industry Press. All rights reserved.

Keyword:

Catalysts Dehydrogenation Hydrothermal synthesis Molecular sieves Propane Zeolites

Community:

  • [ 1 ] [Wang, Chan]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou; 350002, China
  • [ 2 ] [Wang, Chan]Qingyuan Innovation Laboratory, Fujian, Quanzhou; 362801, China
  • [ 3 ] [Xiao, Guoxi]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou; 350002, China
  • [ 4 ] [Guo, Xiaoxue]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou; 350002, China
  • [ 5 ] [Xu, Renwei]Sinochem Quanzhou Energy Technology Co., Ltd., Fujian, Quanzhou; 362000, China
  • [ 6 ] [Yue, Yuanyuan]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou; 350002, China
  • [ 7 ] [Yue, Yuanyuan]Qingyuan Innovation Laboratory, Fujian, Quanzhou; 362801, China
  • [ 8 ] [Bao, Xiaojun]National Engineering Research Center of Chemical Fertilizer Catalyst, College of Chemical Engineering, Fuzhou University, Fujian, Fuzhou; 350002, China
  • [ 9 ] [Bao, Xiaojun]Qingyuan Innovation Laboratory, Fujian, Quanzhou; 362801, China

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Source :

CIESC Journal

ISSN: 0438-1157

CN: 11-1946/TQ

Year: 2022

Issue: 6

Volume: 73

Page: 2690-2697

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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