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学者姓名:岳源源
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A low-cost and process-intensified synthesis approach of SSZ-35 zeolite via a seed-assisted method is presented. This approach involves the development of a relatively inexpensive template and the application of seeds to minimize crystallization time and template consumption. Herein, N-Ethyl, N-methyl 2,6-cis-dimethylpiperidinium hydroxide (EMDMPOH) is selected as a template to synthesize SSZ-35 zeolite, and a simplified and optimized scheme for the preparation of such a template is proposed. Specially, the high-purity EMDMPOH is prepared by a sequential alkylation of 2,6-dimethylpiperidine with iodoethane and iodomethane, followed by ion exchange. By employing a seed-assisted strategy, the synthesis process of SSZ-35 zeolite is intensified, resulting in a significant reduction in crystallization time from 7 d to 75 h. Systematic characterizations reveal that the synthesized SSZ-35 zeolite has smaller crystals and larger specific surface area in comparison with the reference sample, leading to enhanced selectivity in n-octane hydroisomerization. Moreover, the cost accounting analysis shows a notable decrease in the synthesis cost of SSZ-35 zeolite by using the synthesis route that combines the simplified process for preparing the template and the reduced amount of template.
Keyword :
Crystallization intensification Crystallization intensification Low-cost synthesis Low-cost synthesis Seed-assisted method Seed-assisted method SSZ-35 zeolite SSZ-35 zeolite
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GB/T 7714 | Dong, Peng , Wu, Huanliu , Luo, Longhua et al. Low-cost and efficient synthesis of SSZ-35 zeolite through a seed-assisted approach [J]. | CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION , 2025 , 208 . |
MLA | Dong, Peng et al. "Low-cost and efficient synthesis of SSZ-35 zeolite through a seed-assisted approach" . | CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION 208 (2025) . |
APA | Dong, Peng , Wu, Huanliu , Luo, Longhua , Cui, Qingyan , Li, Tiesen , Shi, Jie et al. Low-cost and efficient synthesis of SSZ-35 zeolite through a seed-assisted approach . | CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION , 2025 , 208 . |
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In order to gain insight into the influence of SiO2 support particle size on the vacuum residue (VR) slurry-phase hydrocracking performance of Fe-based catalysts, a series of FeZn/SiO2 catalysts with varying SiO2 particle sizes were prepared. Characterization results show that the surface area and pore volume of the FeZn/SiO2 catalysts increase with the reduction of SiO2 particle sizes. The metals Fe and Zn species on FeZn/SiO2-S catalyst are more readily reducible via H2-TPR analysis. Notably, FeZn/SiO2-S catalyst presents higher metal dispersion and a greater degree of sulfurization compared to the other catalysts by XRD and XPS. Hydrocracking results demonstrate that the FeZn/SiO2-S catalyst achieves the lowest coke and gas yields (11.9 wt% and 0.4 wt%), respectively, and the highest VR conversion among these catalysts. The superior performance of the FeZn/SiO2-S catalyst in VR slurry-phase hydrocracking is ascribed to its enhanced hydrogenation activity, deriving from the higher dispersion and sulfurization of metals species. This suppresses the aggregation of polycyclic aromatic hydrocarbons in VR and the over-cracking of intermediate products. Additionally, the increased mesopore associated with smaller SiO2 particles facilitates to the diffusion of large VR molecules, further promoting the hydrocracking reaction.
Keyword :
FeZn catalyst FeZn catalyst Hydrogenation activity Hydrogenation activity SiO2 particle size SiO2 particle size Slurry-phase hydrocracking Slurry-phase hydrocracking Vacuum residue Vacuum residue
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GB/T 7714 | Wang, Jianbo , Yan, Jianteng , Cui, Qingyan et al. Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking [J]. | CATALYSIS TODAY , 2025 , 449 . |
MLA | Wang, Jianbo et al. "Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking" . | CATALYSIS TODAY 449 (2025) . |
APA | Wang, Jianbo , Yan, Jianteng , Cui, Qingyan , Li, Tiesen , Shi, Jie , Wang, Tinghai et al. Effect of SiO2 support particle sizes on the performance of FeZn catalysts in VR slurry-phase hydrocracking . | CATALYSIS TODAY , 2025 , 449 . |
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A scrics of TS-1 zeolites were prepared by varying the addilions of seeds. The physicochemical properties of the synthesized TS-1 zeolites were systematically characterized by several analytical techniques, including X-ray diffraction, scanning electron microscopy, UV visiblc diffuser reflectance spectroscopy, Fourier transformed infrared spectroscopy, X-ray fluorescence spectroscopy and solid-statc nuclcar magnetie resonance spectroscopy. Morcovcr, the catalytic Performance and regeneration properties of the synthesized TS-1 zeolites in the one-step synthesis of ethylene glycol (EG) from ethylene was thoroughly evaluated. The results demonstrate that the addition of seeds can help improve the crystallinity of the synthesized samplcs. Spccifically, when the seeds mass fraction is 5%, the synthesized TS-1 zcolitc owns the highest Proportion of open framework titanium Ti—OH(HO—Si)3 species and strong Lewis aeid strength. When used in the one-step synthesis of EG from ethylene, this TS-1 zcolite exhibits excellcnt catalytic Performance, i. e., under the dosagc of catalyst of 0. 3 g, ethylene pressure of 2. 5 MPa, and temperaturc of 60 °C, H2()2 conversion rate is 91.1%, H202 utilization rate is 87.2%, and EG selectivity is 89. 8%. Furthermore, through investigating the regeneration properties of zeolites, it is found that thc synthesized optimal TS-1 zcolitc can be regenerated by calcination, and its catalytic Performance remains basically stablc aftcr bcing rcuscd for 5 times in thc one-step synthesis of EG from ethylene. © 2025 Editorial Office of Acta Petrolei Sinica. All rights reserved.
Keyword :
Fluorescence spectroscopy Fluorescence spectroscopy Fourier transform infrared spectroscopy Fourier transform infrared spectroscopy Nuclear magnetic resonance spectroscopy Nuclear magnetic resonance spectroscopy
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GB/T 7714 | Zhang, Ting , Dong, Peng , Wang, Chan et al. Synthesis of TS-1 Zeolites Rieh in Open Framework Titanium and Their Catalytic Performance for One-Step Synthesis of Ethylene Glycol From Ethylene [J]. | Acta Petrolei Sinica (Petroleum Processing Section) , 2025 , 41 (3) : 627-639 . |
MLA | Zhang, Ting et al. "Synthesis of TS-1 Zeolites Rieh in Open Framework Titanium and Their Catalytic Performance for One-Step Synthesis of Ethylene Glycol From Ethylene" . | Acta Petrolei Sinica (Petroleum Processing Section) 41 . 3 (2025) : 627-639 . |
APA | Zhang, Ting , Dong, Peng , Wang, Chan , Yue, Yuanyuan . Synthesis of TS-1 Zeolites Rieh in Open Framework Titanium and Their Catalytic Performance for One-Step Synthesis of Ethylene Glycol From Ethylene . | Acta Petrolei Sinica (Petroleum Processing Section) , 2025 , 41 (3) , 627-639 . |
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Natural rectorite modified by the hydrothermal method was employed to prepare a catalyst for the slurry-phase hydrocracking of vacuum residue (VR). The influence of hydrothermal treatment on the properties of rectorite and the performance of the corresponding catalyst was examined. Hydrothermal treatment of the rectorite led to the formation of Fe3O4, as evidenced by H-2-TPR analysis. XPS results indicate that the hydrothermal treatment of rectorite can intensify the sulfidation process of Mo species supported on it, possibly due to modifications in the surface properties of the rectorite. Comparative slurry-phase hydrocracking tests showed that the catalyst supported on hydrothermally treated rectorite exhibited significantly higher VR conversion, higher liquid product yield, and higher yields of gasoline and diesel fractions, but lower gas yield compared to the catalyst supported on untreated rectorite. This is ascribed to the high hydrogenation activity of the catalyst supported on hydrothermally treated rectorite, which effectively suppresses the over-cracking reactions of intermediate products that would otherwise produce gas, illustrating the process intensification achieved through hydrothermal treatment.
Keyword :
Hydrocracking Hydrocracking Hydrothermal treatment Hydrothermal treatment Mo catalyst Mo catalyst Sulfidation Sulfidation Vacuum residue Vacuum residue
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GB/T 7714 | Cui, Qingyan , Yan, Jianteng , Zhang, Haobin et al. Hydrothermal treatment of natural rectorite enhanced Mo sulfidation for slurry-phase hydrocracking of vacuum residue [J]. | CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION , 2024 , 205 . |
MLA | Cui, Qingyan et al. "Hydrothermal treatment of natural rectorite enhanced Mo sulfidation for slurry-phase hydrocracking of vacuum residue" . | CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION 205 (2024) . |
APA | Cui, Qingyan , Yan, Jianteng , Zhang, Haobin , Feng, Weiwei , Yue, Yuanyuan , Li, Tiesen et al. Hydrothermal treatment of natural rectorite enhanced Mo sulfidation for slurry-phase hydrocracking of vacuum residue . | CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION , 2024 , 205 . |
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NaY zeolites are synthesized using submolten salt depolymerized natural perlite mineral as the main silica and alumina sources in a 0.94 L stirred crystallizer. Effects of alkalinity ranging from 0.38 to 0.55 ( n (Na 2 O)/ n (SiO 2 )) on the relative crystallinity, textural properties and crystallization kinetics were investigated. The results show that alkalinity exerts a nonmonotonic in fluence on the relative crystallinity and textural properties, which exhibit a maximum at the alkalinity of 0.43. The nucleation kinetics are studied by fitting the experimental data of relative crystallinity with the Gualtieri model. It is shown that the nucleation rate constant increases with increasing alkalinity, while the duration period of nucleation decreases with increasing alkalinity. For n (Na 2 O)/ n (SiO 2 ) ratios ranging from 0.38 to 0.55, the as -synthesized NaY zeolites exhibit narrower crystal size distributions with the increase in alkalinity. The growth rates determined from the variations of average crystal size with time are 51.09, 157.50, 46.17 and 24.75 nm $h -1 , respectively. It is found that the larger average crystal sizes at the alkalinity of 0.38 and 0.43 are attributed to the dominant role of crystal growth over nucleation. Furthermore, the combined action of prominent crystal growth and the longer duration periods of nucleation at the alkalinity of 0.38 and 0.43 results in broader crystal size distributions. The findings demonstrate that control of the properties of NaY zeolite and the crystallization kinetics can be achieved by conducting the crystallization process in an appropriate range of alkalinity of the reaction mixture. (c) 2024 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.
Keyword :
Alkalinity Alkalinity Crystallization kinetics Crystallization kinetics NaY zeolite NaY zeolite Submolten salt depolymerized perlite Submolten salt depolymerized perlite
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GB/T 7714 | Qu, Yanli , Dong, Peng , Yang, Li et al. Synthesis of NaY zeolite from a submolten depolymerized perlite: Alkalinity effect and crystallization kinetics [J]. | CHINESE JOURNAL OF CHEMICAL ENGINEERING , 2024 , 70 : 130-138 . |
MLA | Qu, Yanli et al. "Synthesis of NaY zeolite from a submolten depolymerized perlite: Alkalinity effect and crystallization kinetics" . | CHINESE JOURNAL OF CHEMICAL ENGINEERING 70 (2024) : 130-138 . |
APA | Qu, Yanli , Dong, Peng , Yang, Li , Yue, Yuanyuan , Wang, Haoliang , Cheng, Jingcai et al. Synthesis of NaY zeolite from a submolten depolymerized perlite: Alkalinity effect and crystallization kinetics . | CHINESE JOURNAL OF CHEMICAL ENGINEERING , 2024 , 70 , 130-138 . |
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A seed-directed approach to synthesizing FeZSM-22 zeolite without organic structure directing agent(OSDA)was developed by using Fe-rich diatomite as all aluminum and iron sources.The FeZSM-22 zeolite with optimal crystallinity and purity can be obtained by systematically adjusting feed composi-tion and synthesis conditions.Characterizations show that FeZSM-22 zeolite synthesized with OSDA-free owns high crystallinity,obvious thin needle-shaped morphology and high Bronsted/Lewis acid ratio.Significantly,when used for n-octane hydroisomerization reaction,its derived catalyst exhibits the best catalytic performance reflected by the highest selectivity to C8 isomers compared to the two reference catalysts prepared based on a Fe-containing and a Fe-free ZSM-22 synthesized through an OSDA-directed route from natural diatomite and conventional chemicals,respectively.This work provides an alternative route to sustainably synthesizing heteroatomic zeolites with high performance.
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GB/T 7714 | Tiesen Li , Ting Chen , Yinghui Ye et al. OSDA-free synthesis of FeZSM-22 zeolite from natural minerals for n-octane hydroisomerization [J]. | 中国化学工程学报(英文版) , 2024 , 66 (2) : 51-59 . |
MLA | Tiesen Li et al. "OSDA-free synthesis of FeZSM-22 zeolite from natural minerals for n-octane hydroisomerization" . | 中国化学工程学报(英文版) 66 . 2 (2024) : 51-59 . |
APA | Tiesen Li , Ting Chen , Yinghui Ye , Peng Dong , Tinghai Wang , Qingyan Cui et al. OSDA-free synthesis of FeZSM-22 zeolite from natural minerals for n-octane hydroisomerization . | 中国化学工程学报(英文版) , 2024 , 66 (2) , 51-59 . |
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Synthesizing zeolites, which are important materials used in the petroleum and chemical industries, from natural aluminosilicate minerals has been qualitatively recognized as a greener approach compared to that from traditional Si- and Al-containing chemicals; however, studies on the quantitative environmental impacts are still lacking. Herein, life cycle assessment (LCA) and green metrics (atom economy and environmental factor) were employed to comparatively assess the life cycle environmental impacts of zeolites synthesized from chemicals and natural minerals at the industrial scale. The values of seven LCA impact categories and sensitivity analysis between them were thoroughly compared. The results showed that, for each category, the synthesis from natural minerals has lower environmental impacts to varying degrees than that from chemicals. Further efficiency analysis of zeolite manufacturing technologies by green metrics indicated that the synthesis from natural minerals outperforms that from chemicals in terms of the resource utilization rate. The quantitative results indicate that significant benefits stem from the replacement of raw materials from chemicals to natural minerals. This work may provide a basis for the future selection and upgrade of zeolite production processes. Life cycle assessment and green metrics were used to comparatively assess the synthesis of zeolites from natural minerals and chemicals in which the former exhibits a better balance between efficiency and environmental impacts than the latter.
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GB/T 7714 | Chen, Xiaoling , Xiao, Guoxi , Li, Tiesen et al. Comparative environmental assessment of zeolites synthesized from chemicals and natural minerals [J]. | GREEN CHEMISTRY , 2024 , 26 (9) : 5273-5283 . |
MLA | Chen, Xiaoling et al. "Comparative environmental assessment of zeolites synthesized from chemicals and natural minerals" . | GREEN CHEMISTRY 26 . 9 (2024) : 5273-5283 . |
APA | Chen, Xiaoling , Xiao, Guoxi , Li, Tiesen , Wang, Chan , Cui, Qingyan , Bao, Xiaojun et al. Comparative environmental assessment of zeolites synthesized from chemicals and natural minerals . | GREEN CHEMISTRY , 2024 , 26 (9) , 5273-5283 . |
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分子筛合成母液回用技术是分子筛制备的一种新方法,能够有效提高原料利用率和减少废液排放.介绍了分子筛合成母液的产生及组成,简述了分子筛合成母液回用技术及其在分子筛合成中的应用情况,重点总结该技术在工业上最具代表性的Y,ZSM-5,SAPO-34分子筛合成中的研究进展,并阐述当前分子筛母液回用技术面临的挑战,展望其在工业生产中的发展前景,为实现分子筛产业高效与可持续发展提供借鉴.
Keyword :
分子筛 分子筛 可持续制备 可持续制备 合成母液 合成母液 回用技术 回用技术
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GB/T 7714 | 吴岩 , 董鹏 , 王颖 et al. 分子筛合成母液回用技术研究进展 [J]. | 石油炼制与化工 , 2024 , 55 (2) : 110-114 . |
MLA | 吴岩 et al. "分子筛合成母液回用技术研究进展" . | 石油炼制与化工 55 . 2 (2024) : 110-114 . |
APA | 吴岩 , 董鹏 , 王颖 , 岳源源 . 分子筛合成母液回用技术研究进展 . | 石油炼制与化工 , 2024 , 55 (2) , 110-114 . |
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The recycling technology of mother liquid in the synthesis of zeolites is a new method for the preparation of zeolites,which can effectively improve the utilization rate of raw materials and reduce the discharge of waste liquidIn this article, the generation and composition of mother liquid of zeolite synthesis was introduced, the recycling technology of mother liquid of zeolite synthesis and its application in zeolite synthesis were briefly described, and the research progresses of this technology focused on the synthesis of the most representative zeolites including Y, ZSM-5, SAPO-34 as well as other zeolites were summarizedIn addition,the challenges faced by the recycling technology of mother liquid of zeolite synthesis were also proposedBased on this, the development direction of this technology in industrial production was envisionedThis research would provide reference for achieving the efficient and sustainable development of zeolite industry. © 2024 Research Institute of Petroleum Processing, SINOPEC. All rights reserved.
Keyword :
mother liquid mother liquid recycling technology recycling technology sustainable synthesis sustainable synthesis zeolite zeolite
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GB/T 7714 | Wu, Y. , Dong, P. , Wang, Y. et al. RESEARCH PROGRESS ON RECYCLING TECHNOLOGY OF MOTHER LIQUID IN ZEOLITE SYNTHESIS; [分子筛合成母液回用技术硏究进展] [J]. | Petroleum Processing and Petrochemicals , 2024 , 55 (2) : 110-114 . |
MLA | Wu, Y. et al. "RESEARCH PROGRESS ON RECYCLING TECHNOLOGY OF MOTHER LIQUID IN ZEOLITE SYNTHESIS; [分子筛合成母液回用技术硏究进展]" . | Petroleum Processing and Petrochemicals 55 . 2 (2024) : 110-114 . |
APA | Wu, Y. , Dong, P. , Wang, Y. , Yue, Y. . RESEARCH PROGRESS ON RECYCLING TECHNOLOGY OF MOTHER LIQUID IN ZEOLITE SYNTHESIS; [分子筛合成母液回用技术硏究进展] . | Petroleum Processing and Petrochemicals , 2024 , 55 (2) , 110-114 . |
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FAU型分子筛因其独特的孔道结构已成为化学工业中应用最广泛、用量最大的催化剂、催化剂载体及吸附剂之一.然而, FAU型分子筛单一的微孔孔道限制了客体分子的扩散,导致其性能严重下降.相比之下,等级孔FAU型分子筛具有微-介/大孔复合的多级孔道结构,能够促进大分子的扩散、提高活性位点的可接近性,进而改善其吸附和催化性能.目前,等级孔分子筛的制备方法主要包括“自下而上”的直接合成法和“自上而下”的后处理法.本文主要介绍了近年来等级孔X型和Y型分子筛制备方法的研究现状,重点总结了等级孔X型和Y型分子筛在吸附、催化等过程中的应用性能,并对等级孔FAU型分子筛的绿色化制备进行展望.
Keyword :
催化 催化 后处理 后处理 吸附 吸附 直接合成 直接合成 等级孔FAU型分子筛 等级孔FAU型分子筛
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GB/T 7714 | 董鹏 , 朱琳 , 骆龙华 et al. 等级孔FAU型分子筛的制备及应用的研究进展 [J]. | 科学通报 , 2024 , 69 (19) : 2718-2728 . |
MLA | 董鹏 et al. "等级孔FAU型分子筛的制备及应用的研究进展" . | 科学通报 69 . 19 (2024) : 2718-2728 . |
APA | 董鹏 , 朱琳 , 骆龙华 , 李铁森 , 王廷海 , 王婵 et al. 等级孔FAU型分子筛的制备及应用的研究进展 . | 科学通报 , 2024 , 69 (19) , 2718-2728 . |
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