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author:

Zhao, Hailan (Zhao, Hailan.) [1] | Zhang, Weiying (Zhang, Weiying.) [2] (Scholars:张卫英) | Sun, Pengju (Sun, Pengju.) [3] | Ying, Xiaoguang (Ying, Xiaoguang.) [4] (Scholars:英晓光) | Huang, Jianying (Huang, Jianying.) [5] (Scholars:黄剑莹) | Li, Xiao (Li, Xiao.) [6] (Scholars:李晓)

Indexed by:

EI Scopus SCIE

Abstract:

As the core component of wearable electronic devices, flexible energy storage materials play an irreplaceable role. At present, it is still a challenge to prepare flexible electrode materials with high energy density. In this paper, a polyaniline-based composite flexible conductive hydrogel (PPG-P) with a two-level conductive network is successfully prepared by a secondary induced assembly in situ polymerization method. The special conductive structure greatly promotes the efficiency of charge transfer and the utilization of electroactive substances, so that PPG-P exhibits excellent electrochemical performance. In a three-electrode system, PPG-P has a mass-specific capacitance as high as 989 F g(-1) (0.5 A g(-1)). After 1000 charge and discharge cycles, the capacitance retention is 87%. Symmetrical flexible supercapacitors based on PPG-P have high specific capacitance (176 F g(-1)/0.5 A g(-1)) and high energy density (15.6 Wh kg(-1)). After 1000 cycles of constant current charge and discharge, the capacitance maintains 78.1%. The preparation of PPG-P with a hierarchical structure demonstrates the possibility of achieving high energy density in flexible electrode materials, which has great application potential in the development of energy storage elements in wearable devices.

Keyword:

conductive polymer hydrogels flexible supercapacitors polyaniline secondary induced assembly in situ polymerization methods two-level conductive networks

Community:

  • [ 1 ] [Zhao, Hailan]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhang, Weiying]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Sun, Pengju]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Ying, Xiaoguang]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Huang, Jianying]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Li, Xiao]Fuzhou Univ, Coll Chem Engn, Fuzhou 350108, Peoples R China
  • [ 7 ] [Li, Xiao]Fujian Key Lab Adv Mfg Technol Special Chem, Fuzhou 350108, Peoples R China

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Source :

MACROMOLECULAR MATERIALS AND ENGINEERING

ISSN: 1438-7492

Year: 2022

Issue: 11

Volume: 307

3 . 9

JCR@2022

4 . 2 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 8

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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