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author:

Jiang, Mingcen (Jiang, Mingcen.) [1] | Chen, Yuxuan (Chen, Yuxuan.) [2] | Lin, Zhiyang (Lin, Zhiyang.) [3] | Zhao, Yulai (Zhao, Yulai.) [4] (Scholars:赵玉来) | Hou, Linxi (Hou, Linxi.) [5]

Indexed by:

EI Scopus SCIE

Abstract:

Reduced graphene oxide (rGO) is a type of significant electrode material for flexible supercapacitor due to its outstanding mechanical and electrochemical properties. However, low oxidative activity of rGO remains a constraint in developing such devices. In this study, partially reduced graphene oxide (prGO) with enhanced oxidative activity was prepared, into which carbon nanotubes (CNTs) were incorporated to prepare CNT/prGO film with a loosened structure by filtration. Then, polyaniline (PANi) was deposited onto the surface of CNT/prGO composite through in-situ polymerization, resulting in CNT/prGO/PANi composite film. The morphology and structure were investigated via SEM, TEM, XPS, etc. The influences of CNT/prGO ratio and aniline polymerization time on the morphology and electrochemical performance were studied. The electrochemical test results indicated that the CNT/prGO/PANi composite exhibited the best electrochemical performance under the conditions of aniline polymerization for 4 h and CNT/prGO ratio of 3:10. Further increasing the polymerization time or CNT/prGO ratio resulted in short rods-like PANi coated CNTs which merge to form a large flake morphology. The optimized CNT/prGO/PANi demonstrated a specific capacitance of 706 mF cm(-2) (similar to 353 F g(-1)) at 0.1 mA cm(-2), with the specific capacity retaining 78 % of its original value after 3000 charging/discharging cycles at 1 mA cm(-2). Flexible supercapacitors fabricated with CNT/prGO/PANi as electrode exhibited an energy density of 245 mW h cm(-2) at 124 mW cm(-2). These results suggest that flexible solid-state supercapacitors based on CNT/prGO/PANi hold promising potential for energy storage applications.

Keyword:

Carbon nanotubes (CNTs) Flexible solid-state supercapacitor Partially reduced graphene oxide (prGO) Polyaniline

Community:

  • [ 1 ] [Jiang, Mingcen]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 2 ] [Chen, Yuxuan]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 3 ] [Lin, Zhiyang]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 4 ] [Zhao, Yulai]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China
  • [ 6 ] [Zhao, Yulai]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 7 ] [Hou, Linxi]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 8 ] [Zhao, Yulai]Fujian Key Lab Adv Mfg Technol Specialty, Fuzhou, Peoples R China
  • [ 9 ] [Hou, Linxi]Fujian Key Lab Adv Mfg Technol Specialty, Fuzhou, Peoples R China

Reprint 's Address:

  • 赵玉来

    [Zhao, Yulai]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China;;[Hou, Linxi]Fuzhou Univ, Coll Chem Engn, Dept Mat Oriented Chem Engn, Fuzhou 350116, Peoples R China

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Source :

DIAMOND AND RELATED MATERIALS

ISSN: 0925-9635

Year: 2025

Volume: 154

4 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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