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With the development of alternatives to traditional fossil energy and the rise of wearable technology, flexible energy storage devices have attracted great attention. In this paper, a polyaniline/poly(acrylamide-sodium acrylate copolymer) hydrogel (PASH) with high flexibility and excellent electrochemical properties for flexible electrodes is fabricated by freeze-thaw-shrink treatment of a highly water-absorptive hydrogel, together with in-situ polymerization of aniline at a low aniline concentration (0.1 mol L-1). The PASH exhibits a conductivity of 4.05 S m(-1) and an elongation at break of 1245%. The freeze-thaw-shrink treatment greatly improves the electrochemical performance and stability of the conductive PASH. The area specific capacitance of PASH reaches 849 mF cm(-2) and the capacitance maintains 89% after 1000 galvanostatic charge-discharge cycles. All the raw materials are conventional industrialized materials and no additional templating agent is needed during the entire synthesis process. This study provides a cost-efficient approach for the fabrication of conductive polymer hydrogels, which has a broad application prospect in flexible energy storage electronic devices.
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MACROMOLECULAR MATERIALS AND ENGINEERING
ISSN: 1438-7492
Year: 2020
Issue: 3
Volume: 305
4 . 3 6 7
JCR@2020
4 . 2 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:196
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 16
SCOPUS Cited Count: 19
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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