The　rapid　advances　in　photochromic　devices　have　spurred　great　enthusiasm　in　the　design　and　preparation　of　luminescent　materials.　It　is　an　efficient　and　facile　strategy　to　incorporate　ZnS-based　phosphors　into　crosslinking　polymer　substrates,　obtaining　photochromic　materials　with　excellent　comprehensive　properties.　However,　crosslinking　polymeric　ZnS-based　phosphor　luminous　materials　are　unable　to　be　recycled　and　reprocess　at　the　end　of　service,　limiting　their　long-term　utilization　and　burdening　the　environment.　Besides,　few　reported　works　have　explored　photoluminescent　properties　of　samples　during　multiple　reprocessing　and　recycling.　Herein,　enlightened　by　the　intriguing　dynamic　covalent　crosslinking　technology,　recyclable　and　photoluminescent　elastomers,　employed　polymeric　flexible　matrixes　with　dynamic　covalent　joints　integrated　with　ZnS:Cu　and　ZnS:Cu,Mn　phosphors,　were　prepared　in　this　work.　Due　to　the　breakage　and　reformation　of　exchangeable　crosslinking　connections　and　intensive　interfacial　interactions　between　polar　elastomeric　matrixes　and　luminophores,　the　original　and　recycled　composites　exhibit　excellent　recyclable,　photoluminescent,　and　mechanical　properties.　We　anticipate　that　the　strategy　of　this　work,　inserted　phosphors　into　dynamic　crosslinking　polymer　matrixes　with　a　facile　fabrication　process,　paves　the　way　for　the　recycling　and　long-term　utilization　of　photoluminescent　materials.　©　2022　Society　of　Plastics　Engineers.