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author:

Wang, Jinshan (Wang, Jinshan.) [1] | Lian, Ruqian (Lian, Ruqian.) [2] | Zhao, Si (Zhao, Si.) [3] | Zheng, Lituo (Zheng, Lituo.) [4] | Huang, Yiyin (Huang, Yiyin.) [5] | Wei, Mingdeng (Wei, Mingdeng.) [6] (Scholars:魏明灯) | Mathur, Sanjay (Mathur, Sanjay.) [7] | Hong, Zhensheng (Hong, Zhensheng.) [8]

Indexed by:

EI SCIE

Abstract:

Sodium metal is considered as an excellent anode material for sodium-based energy storage devices with both high energy density and low cost, but the uncontrollable growth of sodium metal seriously limits its application. Herein, we firstly propose 3D spaced TiO2 nanotube arrays (STNTs) uniformly coated with ultra-fine metal (Ag, Cu) nanocrystals as a substrate with absorption-diffusion regulation strategy to control the sodium metal deposition behavior. TiO2 has a higher sodiophilic activity with larger Na absorption energy than the traditional copper substrate. Moreover, it is found by ab initio molecular dynamics (AIMD) simulations that it is much easier for Na to spread upon the surface of silver compared to copper, and thus forming a mixed Na-Ag layer at the interface. As a result, sodium metal is inclined to deposit inside or along the nanotube in STNTs-Ag in nanoscale. Finally, STNTs-Ag||Na half-cell displays a high Coulombic efficiency ~99.5% even after 500 cycles with 1 mAh cm(-2). Symmetric cell of STNTs-Ag-Na exhibits an ultralow overpotential of 4 mV and a long-term cycling life over 1400 h. Moreover, STNTs-Ag-Na anode coupling with Na3V2(PO4)(3) cathode exhibits a significantly reduced polarization voltage with 22 mV and improved rate performance with 110 mAhg(-1) at 10 C.

Keyword:

Electrochemical deposition Heterogeneous nucleation Sodium metal anode TiO2 & nbsp;nanotube arrays

Community:

  • [ 1 ] [Wang, Jinshan]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 2 ] [Zhao, Si]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 3 ] [Zheng, Lituo]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 4 ] [Huang, Yiyin]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 5 ] [Hong, Zhensheng]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Key Lab Quantum Manipulat & New Energ, Fuzhou 350117, Fujian, Peoples R China
  • [ 6 ] [Lian, Ruqian]Hebei Univ, Sch Phys Sci & Technol, Baoding 071002, Peoples R China
  • [ 7 ] [Zhao, Si]Fujian Prov Collaborat Innovat Ctr Adv High Field, Fuzhou 350117, Fujian, Peoples R China
  • [ 8 ] [Wei, Mingdeng]Fuzhou Univ, Fujian Prov Key Lab Elect Energy Storage Mat, Fuzhou 350116, Fujian, Peoples R China
  • [ 9 ] [Mathur, Sanjay]Univ Cologne, Inst Inorgan Chem, Greinstr 6, D-50939 Cologne, Germany
  • [ 10 ] [Hong, Zhensheng]Univ Cologne, Inst Inorgan Chem, Greinstr 6, D-50939 Cologne, Germany

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Source :

CHEMICAL ENGINEERING JOURNAL

ISSN: 1385-8947

Year: 2022

Volume: 431

1 5 . 1

JCR@2022

1 3 . 4 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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