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Abstract:
Potassium-ion batteries (PIBs) are attractive for energy storage due to their obvious cost advantage compared with lithium-ion batteries. However, their commercialization is plagued by the lack of high-performance electrode materials. In this work, a novel polyanionic anode material K2.13V1.52Ti0.48(PO4)3 (KVTP) is prepared for the first time, which exhibits excellent electrochemical properties when used as the electrode material of a PIB. After coating with carbon, the obtained KVTP@C composite delivers a high specific capacity of 136 mA center dot h/g at a current density of 10 mA/g (0.073C) and achieves a long life span of 225 cycles (ca. 7.5 months) with a specific capacity of 106.7 mA center dot h/g, corresponding to 78.55 % of the maximum value. Moreover, the framework host can provide a capacity of 92.6 mA center dot h/g at a rate of 100 mA/g (0.73 C) and retains 69.3 % of the initial capacity at the 1000th cycle. The outstanding cycling stability is attributed to the robust lattice structure revealed by ex situ Xray diffraction.
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ELECTROCHEMISTRY COMMUNICATIONS
ISSN: 1388-2481
Year: 2022
Volume: 136
5 . 4
JCR@2022
4 . 7 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:74
JCR Journal Grade:2
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 7
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: