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author:

Wang, Wenbo (Wang, Wenbo.) [1] | Kang, Zhihan (Kang, Zhihan.) [2] | Sun, Chuan-Fu (Sun, Chuan-Fu.) [3] | Li, Yafeng (Li, Yafeng.) [4] (Scholars:李亚峰)

Indexed by:

EI SCIE

Abstract:

Potassium-ion batteries (PIBs) are attractive for energy storage due to their obvious cost advantage compared with lithium-ion batteries. However, their commercialization is plagued by the lack of high-performance electrode materials. In this work, a novel polyanionic anode material K2.13V1.52Ti0.48(PO4)3 (KVTP) is prepared for the first time, which exhibits excellent electrochemical properties when used as the electrode material of a PIB. After coating with carbon, the obtained KVTP@C composite delivers a high specific capacity of 136 mA center dot h/g at a current density of 10 mA/g (0.073C) and achieves a long life span of 225 cycles (ca. 7.5 months) with a specific capacity of 106.7 mA center dot h/g, corresponding to 78.55 % of the maximum value. Moreover, the framework host can provide a capacity of 92.6 mA center dot h/g at a rate of 100 mA/g (0.73 C) and retains 69.3 % of the initial capacity at the 1000th cycle. The outstanding cycling stability is attributed to the robust lattice structure revealed by ex situ Xray diffraction.

Keyword:

Long cycle life Low strain Polyanion-type anode materials Potassium-ion batteries

Community:

  • [ 1 ] [Wang, Wenbo]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Kang, Zhihan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Li, Yafeng]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Wang, Wenbo]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Kang, Zhihan]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Sun, Chuan-Fu]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Wang, Wenbo]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Kang, Zhihan]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Sun, Chuan-Fu]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Li, Yafeng]Fuzhou Univ, Fujian Prov Key Lab Electrochem Energy Storage Ma, Fuzhou 350002, Fujian, Peoples R China

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Source :

ELECTROCHEMISTRY COMMUNICATIONS

ISSN: 1388-2481

Year: 2022

Volume: 136

5 . 4

JCR@2022

4 . 7 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 7

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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