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[期刊论文]

Optimizing the Microstructure of SnO2-CeO2 Binary Oxide Supported Palladium Catalysts for Efficient and Stable Methane Combustion

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author:

Huang, Jiangli (Huang, Jiangli.) [1] | Lin, Jia (Lin, Jia.) [2] | Chen, Xiaohua (Chen, Xiaohua.) [3] | Unfold

Indexed by:

EI SCIE

Abstract:

The preparation of palladium-based catalysts with both high catalytic activity and hydrothermal stability currently appears as a critical topic in methane combustion. Herein, we propose a facile strategy to boost the performance of SnO2-CeO2 binary oxide supported palladium catalysts by tuning the composition of supports. The coexistence of SnO2 and CeO2 phases in an appropriate ratio is favorable for the formation of both PdxCe1-xO2-delta and PdxSn1-xO2-delta solid solutions due to the reduced crystallite size. This unique microstructure could enhance the metal-support interaction to stabilize the active PdO phase and promote its reoxidation, meanwhile generating more oxygen vacancies to improve the reducibility of PdO. On account of the facilitated conversion of PdO <-> Pd, coupled with the low-temperature dissociation of methane promoted by abundant active oxygen species, the Pd/5Sn5Ce catalyst exhibits a superior catalytic activity with a T-99 of ca. 360 degrees C, a robust stability under both dry and wet conditions, and an excellent thermal stability during heating-cooling light-off tests.

Keyword:

methane combustion oxygen mobility Pd-based catalyst SnO2-CeO2 binary oxide solid solutions

Community:

  • [ 1 ] [Huang, Jiangli]Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Fujian, Peoples R China
  • [ 2 ] [Lin, Jia]Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Fujian, Peoples R China
  • [ 3 ] [Chen, Xiaohua]Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Fujian, Peoples R China
  • [ 4 ] [Zheng, Ying]Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Fujian, Peoples R China
  • [ 5 ] [Zheng, Yong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Xiao, Yihong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst, Fuzhou 350002, Fujian, Peoples R China

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2022

Issue: 14

Volume: 14

Page: 16233-16244

9 . 5

JCR@2022

8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:91

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 17

SCOPUS Cited Count: 17

30 Days PV: 1

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