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学者姓名：郑勇
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Abstract ：
Selective adsorption of sulfur dioxide (SO2) is an important clean technology for purification of exhaust gas from fossil fuel combustion. The widely applied zeolite-based adsorbents interact with SO2 through weakly physical adsorption, resulting in low adsorption capacity and selectivity for SO2. Herein, a facile strategy that combines improving the textural property of zeolite and optimizing adsorption sites is developed for efficient and stable SO2 adsorption. The micro-mesoporous silica sphere (MS) with high specific surface area and well-defined pore structure is obtained through a micelle expander assisted soft-template method, which can facilitate the dispersion and exposure of designed adsorption sites- methylated polyethyleneimine (mPEI). Since the Lewis basic sites of N in mPEI can strongly interact with the pi-receptor SO2, and the tertiary amine groups exhibit a weak attraction for CO2, the optimized MS supported mPEI adsorbent exhibits remarkable SO2 adsorption performance (7.5 mmol/g), exceptionally high SO2/N2 selectivity (16673) and SO2/CO2 selectivity (551). Moreover, it presents an outstanding stability in the adsorption-regeneration test. This work sheds light on the design of high-performance organic-solid composite adsorbent for selective capture of SO2.
Keyword ：
Adsorption Adsorption Micro-mesoporous silica sphere Micro-mesoporous silica sphere Polytertiary amine Polytertiary amine Selective desulfurization Selective desulfurization SO 2 capture SO 2 capture
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| GB/T 7714 | Zhang, Qiongdan , Wei, Jixiang , Gao, Changbo et al. Highly selective capture of SO2 with supported micro-mesoporous silica sphere from CO2-rich environment [J]. | JOURNAL OF CLEANER PRODUCTION , 2024 , 436 . |
| MLA | Zhang, Qiongdan et al. "Highly selective capture of SO2 with supported micro-mesoporous silica sphere from CO2-rich environment" . | JOURNAL OF CLEANER PRODUCTION 436 (2024) . |
| APA | Zhang, Qiongdan , Wei, Jixiang , Gao, Changbo , Zheng, Yong , Xiao, Yihong , Liu, Fujian et al. Highly selective capture of SO2 with supported micro-mesoporous silica sphere from CO2-rich environment . | JOURNAL OF CLEANER PRODUCTION , 2024 , 436 . |
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The amine -based materials pose high potential for the adsorption of sulfur dioxide (SO 2 ). This work is aimed at modulating the morphologies of SBA -15 adsorbents by controlling the precursor self -assembly processes, for the sake of optimizing the utilization efficiency of amine species in the polytertiary amine (PTA)-functionalized SBA15. It results that worm -like SBA -15 (WLS) material shows a better particle aspect ratio and well-defined pore structure, which helps to optimize the adsorption sites invoked by the preferable dispersion and exposure of PTA, thus amplifying the chemisorption of SO 2 on the adsorbent. Consequently, the functionalized WLS-PTA adsorbent exhibits remarkable SO 2 adsorption performance (15.43 mmol/g), exceptionally high selectivities of SO 2 /N 2 (27522) and SO 2 /CO 2 (652). Surprisingly, the desulfurization capacity can be further enhanced by the positive effect of the water vapor co -fed. It is unveiled that the whole SO 2 adsorption process mainly follows the dual site Langmuir-Freundlich isotherm model and Bangham model. This work sheds light on the design of polymer -solid composite adsorbents for selective capture of SO 2 .
Keyword ：
Mesoporous SBA-15 Mesoporous SBA-15 Polytertiary amine Polytertiary amine Selective desulfurization Selective desulfurization SO2 adsorption SO2 adsorption Solid amine adsorbent Solid amine adsorbent
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| GB/T 7714 | Zhang, Qiongdan , Lei, Yuanyi , Ye, Ming et al. Facilely tuning the morphologies of tertiary amine-functionalized SBA-15 for optimizing selective SO 2 capture [J]. | CHEMICAL ENGINEERING JOURNAL , 2024 , 487 . |
| MLA | Zhang, Qiongdan et al. "Facilely tuning the morphologies of tertiary amine-functionalized SBA-15 for optimizing selective SO 2 capture" . | CHEMICAL ENGINEERING JOURNAL 487 (2024) . |
| APA | Zhang, Qiongdan , Lei, Yuanyi , Ye, Ming , Wang, Heng , Zheng, Yong , Xiao, Yihong et al. Facilely tuning the morphologies of tertiary amine-functionalized SBA-15 for optimizing selective SO 2 capture . | CHEMICAL ENGINEERING JOURNAL , 2024 , 487 . |
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Abstract ：
针对传统两级式LED驱动电源中存在着半导体功率器件数目多,控制电路复杂,效率低,成本高,可靠性差等问题,提出一种单级无桥Sepic谐振LED驱动电路,通过将单开关无桥Sepic电路主开关管与半桥LLC电路下开关管复用集成单级LED驱动电路,减少了半导体功率器件数目,简化控制电路,提高了电路效率和工作可靠性.详细分析了所提出电路的工作原理和工作过程,深入开展了电路输入输出电压变比、网侧特性、软开关特性等稳态特性推导和电路关键参数设计,并针对所提出单级电路由于输入电压变化引起直流母线电压变动范围大等问题,分析设计了一种APWM-PFM混合控制策略.最后进行计算机仿真分析,并设计一台交流输入185～265 Vrms、额定输出2A/96W的实验样机,样机效率最高可达91.5%,PF最大值为0.995,THD最小为5.5%,不同交流电压下直流母线电压总体变化范围在60V以内,实现直流母线电压限压.计算机仿真结果和实验结果验证所提出电路和混合控制策略的理论预期和有效性.
Keyword ：
LED照明 LED照明 功率因数校正 功率因数校正 单级无桥Sepic/LLC电路 单级无桥Sepic/LLC电路 直流母线电压APWM-PFM混合控制 直流母线电压APWM-PFM混合控制 软开关 软开关
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| GB/T 7714 | 林中寅 , 林维明 , 黄舒晨 et al. 单级无桥Sepic谐振LED驱动电路及其APWM-PFM混合控制 [J]. | 电机与控制学报 , 2024 , 28 (9) : 106-124 . |
| MLA | 林中寅 et al. "单级无桥Sepic谐振LED驱动电路及其APWM-PFM混合控制" . | 电机与控制学报 28 . 9 (2024) : 106-124 . |
| APA | 林中寅 , 林维明 , 黄舒晨 , 郑勇 . 单级无桥Sepic谐振LED驱动电路及其APWM-PFM混合控制 . | 电机与控制学报 , 2024 , 28 (9) , 106-124 . |
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Catalytic combustion shows promise in mitigating methane emissions from natural gas utilization, while the presence of sulfur species in natural gas can cause significant catalyst deactivation. Herein, a dual-modification strategy is proposed to construct active and sulfur-resistant nickel oxide (NiO)-based catalysts. Through regulating the hydrolysis of the silicon (Si) precursor and the precipitation of zirconium (Zr) and nickel (Ni) precursors, both the Si and Zr component could enter NiO lattice to generate strong interactions, leading to a decrease in crystallite size, an increase in active Ni2+ and surface adsorbed oxygen species for the efficient methane combustion. The incorporation of Si prominently enhanced the surface acidity of catalysts to inhibit the sulfating of NiO; the introduced Zr component also contributed to the generation of surface acid sites, and had a preferential interaction with sulfur dioxide (SO2) to protect Ni2+ sites. Consequently, the small NiO crystallites, active Ni2+ and oxygen species could be maintained in dual-modified catalysts under sulfur-containing reaction conditions, leading to the superior catalytic performance compared to NiO or catalysts modified by Zr or Si. This work introduces a practical and efficient approach for developing catalysts to remove gaseous pollutants.
Keyword ：
Catalytic combustion of methane Catalytic combustion of methane Modified NiO Modified NiO Si and Zr-incorporation Si and Zr-incorporation Sulfur-resistance Sulfur-resistance Surface acidity Surface acidity
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| GB/T 7714 | Tian, Chengchen , Lin, Jia , Lin, Li et al. A silicon-zirconium dual-modified nickel oxide with high activity and sulfur-resistance for catalytic combustion removal of methane [J]. | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2024 , 13 (1) . |
| MLA | Tian, Chengchen et al. "A silicon-zirconium dual-modified nickel oxide with high activity and sulfur-resistance for catalytic combustion removal of methane" . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 13 . 1 (2024) . |
| APA | Tian, Chengchen , Lin, Jia , Lin, Li , Zheng, Yong , Xiao, Yihong , Zheng, Ying . A silicon-zirconium dual-modified nickel oxide with high activity and sulfur-resistance for catalytic combustion removal of methane . | JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING , 2024 , 13 (1) . |
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It is essential to develop catalysts that demonstrate outstanding catalytic activity and N2 selectivity to effectively purify NH3-containing waste gas through selective oxidation of NH3. Herein, we present a facile strategy to construct high-performance CuO-based catalysts through the incorporation of niobium (Nb) component. The Nb species with molar ratios of 0.05-0.2 could enter the CuO lattice and generate Cu-O-Nb bonds, resulting in lattice distortion and weakened Cu-O bond, which enhanced the redox properties as well as surface acidity of CuO. The catalytic activity was improved by the increased Cu+, surface chemisorbed oxygen species, and weak acid sites, while N2 selectivity was promoted mainly due to the generation of moderate and strong acid sites. The catalyst with a relatively low content of Nb (molar ratio of 0.1) exhibited optimal redox properties and surface acidity, which facilitated the reaction to proceed through both imide and i-SCR mechanisms, resulting in significantly enhanced catalytic activity, stability, and N2 selectivity compared to CuO. This investigation underscores the importance of dual modification of redox properties and surface acidity of catalysts for improving catalytic performance.
Keyword ：
CuO-based catalysts CuO-based catalysts Nb-incorporation Nb-incorporation NH 3-SCO reaction NH 3-SCO reaction Redox property Redox property Surface acidity Surface acidity
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| GB/T 7714 | Pang, Lei , Gao, Mengjie , Lin, Jia et al. Redox-acidity dual modification of CuO by niobium-incorporation for enhanced selective catalytic oxidation of NH3 [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2024 , 354 . |
| MLA | Pang, Lei et al. "Redox-acidity dual modification of CuO by niobium-incorporation for enhanced selective catalytic oxidation of NH3" . | SEPARATION AND PURIFICATION TECHNOLOGY 354 (2024) . |
| APA | Pang, Lei , Gao, Mengjie , Lin, Jia , Zheng, Yong , Xiao, Yihong , Zheng, Ying et al. Redox-acidity dual modification of CuO by niobium-incorporation for enhanced selective catalytic oxidation of NH3 . | SEPARATION AND PURIFICATION TECHNOLOGY , 2024 , 354 . |
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The efficient adsorption of sulfur dioxide (SO2) is crucial for purifying exhaust gases, and zeolites are promising adsorbents due to their low cost and excellent stability. However, developing FAU-type zeolites with high adsorption capacities and selectivities remains challenging due to their narrow pores and limited adsorption sites. Herein, an additive-free synthesis strategy is proposed to facilely obtain NaX zeolites (X-HCL) with the house-of-card-like morphology. The hierarchical structure of X-HCL not only benefits the removal of SO2 through favorable spatial diffusion, but also promotes the loading of basic adsorption sites- [caprolactam] [tetrabutylammonium bromide] (CT) ionic liquid. The obtained CT/X-HCL adsorbent demonstrates remarkable SO2 adsorption capacity (10.58 mmol/g) and cyclic stability, as well as great selectivity of SO2/N-2 (1673) and SO2/ CO2 (219) due to the strong affinity of CT towards SO2. Moreover, co-feeding with water vapor benefits the adsorption of SO2 on CT/X-HCL owing to the enhanced chemisorption of hydrated CT for SO2. This research provides new insights into the construction of hierarchical zeolite for efficient adsorption and separation of SO2.
Keyword ：
Hierarchical Hierarchical House-of-card-like morphology House-of-card-like morphology Ionic liquid Ionic liquid NaX zeolite NaX zeolite Sulfur dioxide adsorption Sulfur dioxide adsorption
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| GB/T 7714 | Zhang, Qiongdan , Ye, Ming , Lei, Yuanyi et al. Additive-free synthesis of house-of-card NaX zeolite for supporting amine: An efficient adsorbent for SO2 removal [J]. | SEPARATION AND PURIFICATION TECHNOLOGY , 2024 , 354 . |
| MLA | Zhang, Qiongdan et al. "Additive-free synthesis of house-of-card NaX zeolite for supporting amine: An efficient adsorbent for SO2 removal" . | SEPARATION AND PURIFICATION TECHNOLOGY 354 (2024) . |
| APA | Zhang, Qiongdan , Ye, Ming , Lei, Yuanyi , Wang, Heng , Zheng, Yong , Xiao, Yihong et al. Additive-free synthesis of house-of-card NaX zeolite for supporting amine: An efficient adsorbent for SO2 removal . | SEPARATION AND PURIFICATION TECHNOLOGY , 2024 , 354 . |
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Ordered mesoporous carbon@silica hybrid frameworks with high nitrogen content and good stabilities show great significance to improve their functionalities. Herein, we report novel nitrogen-doped (3.51 - 4.62 wt%) and ordered mesoporous carbon@silica frameworks (N-OMC@SiO2) with reinforced nitrogen stability. The NOMC@SiO2 were designed from tricomponent direct co-assembly between block copolymer template and mixed precursors containing urea and tetramethoxysilane without using additional solvent. The N-OMC@SiO2 have large BET surface areas (444.3 - 674.9 m2/g), uniform mesoporous channels (5.8 - 10.9 nm) with well-defined hexagonal symmetry, and stable carbon@silica "reinforced concrete" framework that can be transformed into carbon@silicon by controllable reduction. The nitrogen sites were firmly embedded into their frameworks via the formation of Si-N bonding. Thus, the resulted N-OMC@SiO2 exhibit multi-functionalities and enhanced recyclability in acid waste gas capture and gaseous sulfides catalytic utilization, better than many reported porous adsorbents and catalysts. This study may help develop stable and efficient N-OMCs nanocomposites for acidic gas selective removal.
Keyword ：
Acid gas selective capture Acid gas selective capture Carbon@silica composites Carbon@silica composites Gaseous sulfides elimination Gaseous sulfides elimination Nitrogen -doping Nitrogen -doping Ordered mesoporosity Ordered mesoporosity Solvent -free synthesis Solvent -free synthesis
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| GB/T 7714 | Kan, Xun , Liu, Zihao , Sun, Yafei et al. Tricomponent direct co-assembly to nitrogen-doped, ordered mesoporous carbon@silica frameworks with enhanced nitrogen stability and multi-functionalities [J]. | CHEMICAL ENGINEERING SCIENCE , 2024 , 292 . |
| MLA | Kan, Xun et al. "Tricomponent direct co-assembly to nitrogen-doped, ordered mesoporous carbon@silica frameworks with enhanced nitrogen stability and multi-functionalities" . | CHEMICAL ENGINEERING SCIENCE 292 (2024) . |
| APA | Kan, Xun , Liu, Zihao , Sun, Yafei , Zhong, Shouchao , Zheng, Yong , Liang, Shijing et al. Tricomponent direct co-assembly to nitrogen-doped, ordered mesoporous carbon@silica frameworks with enhanced nitrogen stability and multi-functionalities . | CHEMICAL ENGINEERING SCIENCE , 2024 , 292 . |
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天然气、油田伴生气、高炉煤气等化工生产过程中伴生COS气体，不仅会腐蚀管道和毒害催化剂，还会严重污染环境并危害人类健康。COS催化水解反应可在温和条件下高效的将COS脱除，是最具应用前景的COS脱除技术之一。碱金属元素因其具有独特的电子供体性质、表面碱性和静电吸附等特性，常被用作助催化剂以提高Al_2O_3的COS催化水解性能。近年来，以钾为助剂改性的Al_2O_3催化剂(K_2CO_3/Al_2O_3)在COS催化水解反应中得到广泛的应用，但由于负载在Al_2O_3上的K物种的组成复杂，目前研究者对K_2CO_3/Al_2O_3催化剂上COS水解机理的理解仍存在一定的困惑和争议。本论文通过湿法浸渍法合成出一系列钾盐和钠盐改性的Al_2O_3催化剂，并利用各类先进的表征技术对这些催化剂进行分析。活性测试表明，以K_2CO_3、K_2C_2O_4、NaHCO_3、Na_2CO_3和NaC_2O_4改性Al_2O_3催化剂均有助于COS的水解。其中K_2CO_3/Al_2O_3拥有最佳的COS水解性能，连续运行20 h后其COS转化率仍高于～93%，远远优于未改性的Al_2O_3 (～58%)。我们利用原位红外光谱和X射线光电子能谱探明了反应过程中催化剂的化学结构特征，阐明了H_2O分子在K_2CO_3/Al_2O_3上的水解作用机制。原位红外表明COS在K_2CO_3/Al_2O_3上的水解过程中形成了硫代碳酸氢盐中间产物。X射线光电子能谱表征证明催化剂的失活主要是因为催化剂表面积累了硫酸盐和单质硫。此外，我们还研究了水蒸气含量对COS水解性能的影响，研究发现，由于H_2O和COS分子在催化剂表面存在竞争吸附，过量的H_2O会引起催化活性的下降。上述研究表明，K_2CO_3/Al_2O_3催化剂上COS水解性能的提高主要是形成了HO-Al-O-K界面活性位。更为重要的是，所制备的催化剂都是在模拟工业工况条件下进行的，这为后续的工业应用提供了宝贵理论指导。本工作为理解助剂钾在Al_2O_3催化剂上COS水解活性的增强提供了新的见解，这为未来设计稳定高效的COS水解催化剂打开了新的发展方向。
Keyword ：
HO-Al-O-K界面活性位点 HO-Al-O-K界面活性位点 催化水解 催化水解 失活机理 失活机理 工业工况条件 工业工况条件 羰基硫 羰基硫
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| GB/T 7714 | 雷淦昌 , 郑勇 , 曹彦宁 et al. 钾改性氧化铝基羰基硫水解催化剂及其失活机理（英文） [J]. | 物理化学学报 , 2023 , 39 (09) : 115-124 . |
| MLA | 雷淦昌 et al. "钾改性氧化铝基羰基硫水解催化剂及其失活机理（英文）" . | 物理化学学报 39 . 09 (2023) : 115-124 . |
| APA | 雷淦昌 , 郑勇 , 曹彦宁 , 沈丽娟 , 王世萍 , 梁诗景 et al. 钾改性氧化铝基羰基硫水解催化剂及其失活机理（英文） . | 物理化学学报 , 2023 , 39 (09) , 115-124 . |
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In this work, metal oxides with different phase structures (stannic oxide, zirconia and tin-zirconium binary oxide) were designed to construct palladium-based catalysts. The factors affecting methane combustion over catalysts were revealed by exploring the reasons for the enhancement and depression of catalytic performance under various reaction conditions. The formation of SnxZr1_ xO2 solid solutions not only generated abundant oxygen vacancies to improve the reducibility of PdO and the redox of Pd <-> PdO, but also induced the formation of active PdOx, conjointly leading to the excellent catalytic activity and hydrothermal stability. Under SO2-containing atmosphere, the thermodynamically favorable formation of stable Zr(SO4)2 caused the significant diminish of oxygen vacancies and active Pd step sites in catalysts. Consequently, the sulfur-resistance and regeneration performance of Zr-containing catalysts were inferior to those of Pd/SnO2. The above contrast manifested that both oxygen vacancies and active palladium species were responsible for the efficient and stable methane combustion.
Keyword ：
Methane combustion Methane combustion Oxygen vacancies Oxygen vacancies Palladium catalysts Palladium catalysts Sn x Zr 1_x O 2 solid solutions Sn x Zr 1_x O 2 solid solutions Support effect Support effect
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| GB/T 7714 | Lin, Jia , Huang, Jiangli , Chen, Xiaohua et al. Key factors for methane combustion over palladium-based catalysts revealed by enhanced and depressed catalytic performance [J]. | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY , 2023 , 340 . |
| MLA | Lin, Jia et al. "Key factors for methane combustion over palladium-based catalysts revealed by enhanced and depressed catalytic performance" . | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY 340 (2023) . |
| APA | Lin, Jia , Huang, Jiangli , Chen, Xiaohua , Zheng, Yong , Xiao, Yihong , Zheng, Ying et al. Key factors for methane combustion over palladium-based catalysts revealed by enhanced and depressed catalytic performance . | APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY , 2023 , 340 . |
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Catalytic combustion holds great promise for eliminating unburned methane released by the natural gas industry, and the crucial factor is the development of cost-effective and efficient catalysts. Herein, the silicon component was introduced into nickel oxide by simultaneously regulating the precipitation of nickel precursors and the hydrolysis of silicon precursors. The generation of SiO4 groups in NiO inhibited the growth and sintering of NiO grains, meanwhile promoting the formation of active Ni2+ and adsorbed oxygen species for activation and oxidation of methane. With the increase of Si content, the existence of surface nickel silicate on NiO further improved the sinter resistance of NiO, but caused the diminish of Ni2+ and surface adsorbed oxygen species. The catalytic activity and stability were co-enhanced via facilely tuning the multiple Ni-Si interactions. The catalyst with abundant SiO4 groups and negligible nickel silicate exhibited considerably higher catalytic activity, sinter-resistance and water-resistance than NiO toward methane combustion.
Keyword ：
Catalytic activity Catalytic activity Methane combustion Methane combustion Multiple Ni-Si interaction Multiple Ni-Si interaction NiO-based catalysts NiO-based catalysts Thermal stability Thermal stability
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| GB/T 7714 | Wang, Zhixiong , Tang, Chenyao , Lin, Jia et al. Promoting methane combustion activity and stability by tuning multiple Ni-Si interactions in catalysts [J]. | FUEL , 2023 , 349 . |
| MLA | Wang, Zhixiong et al. "Promoting methane combustion activity and stability by tuning multiple Ni-Si interactions in catalysts" . | FUEL 349 (2023) . |
| APA | Wang, Zhixiong , Tang, Chenyao , Lin, Jia , Zheng, Yong , Xiao, Yihong , Zheng, Ying et al. Promoting methane combustion activity and stability by tuning multiple Ni-Si interactions in catalysts . | FUEL , 2023 , 349 . |
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