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author:

Luo, Yu (Luo, Yu.) [1] | Liao, Shuting (Liao, Shuting.) [2] | Chen, Shuai (Chen, Shuai.) [3] | Fang, Huihuang (Fang, Huihuang.) [4] (Scholars:方辉煌) | Zhong, Fulan (Zhong, Fulan.) [5] (Scholars:钟富兰) | Lin, Li (Lin, Li.) [6] (Scholars:林立) | Zhou, Chen (Zhou, Chen.) [7] | Chen, Chongqi (Chen, Chongqi.) [8] (Scholars:陈崇启) | Cai, Guohui (Cai, Guohui.) [9] (Scholars:蔡国辉) | Au, Chak-Tong (Au, Chak-Tong.) [10] | Jiang, Lilong (Jiang, Lilong.) [11] (Scholars:江莉龙)

Indexed by:

EI SCIE

Abstract:

With high energy density both by weight and volume, ammonia (NH3) is a promising hydrogen carrier. Furthemore, NH3 has a mature industrial background, and in liquid form storage and transportation is not a problem. Adding the merit of zero CO2 emission, NH3-to-power by direct ammonia solid oxide fuel cells (DA-SOFCs) is an acceptable strategy to facilitate hydrogen usage. Nonetheless, to achieve efficacy, a high compatibility between operating temperature and catalytic materials for NH3 decomposition is needed. In this work, we developed a tubular DA-SOFC with an output power capability of > 3 W. By combining experimental measurements and multi-physics simulation, we comprehensively studies the related intrinsic processes. Based on experimental data, we developed a two-dimensional multi-scale electro-thermo model of tubular DA-SOFC. Separately we evaluated the effects of inlet fuel gas composition, inlet flow velocity, operating temperature, and operating voltage on the rate of NH3 catalytic decomposition and H-2 electrochemical oxidation, as well as on NH3 conversion, H atom utilization, and electrical efficiency of the tubular DA-SOFC. The results suggest that high H atom utilization could be realized by matching the rate of NH3 decomposition with that of H-2 electrochemical oxidation. It was observed that with the decrease of temperature, the rate of H-2 oxidation decreases more rapidly than that of NH3 decomposition, suggesting that the flow velocity of NH3 should be appropriately lowered to optimize H atom utilization. Finally, we established a correlation between H atom utilization, operating voltage, and electrical efficiency for synergistic optimization of operating conditions. At 0.7 V and 800 celcius, the tubular DA-SOFC fueled with NH3 of 27 mL.min(-1) is capable of offering 3.2 W, displaying an efficiency of 60%. Compared to that of a tubular H-2-SOFC (only 51% efficiency), the efficiency is significantly higher on the basis of equal voltage and fuel utilization ratio. The outcome of the present study demonstrates the potential of tubular DA-SOFC as a device for high-efficiency power generation.

Keyword:

Ammonia decomposition Direct ammonia fuel cell Efficiency improvement Multi-physics model Solid oxide fuel cell (SOFC) Tubular

Community:

  • [ 1 ] [Luo, Yu]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 2 ] [Liao, Shuting]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 3 ] [Chen, Shuai]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 4 ] [Fang, Huihuang]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 5 ] [Zhong, Fulan]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 6 ] [Lin, Li]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 7 ] [Zhou, Chen]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 8 ] [Chen, Chongqi]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 9 ] [Cai, Guohui]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 10 ] [Au, Chak-Tong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China
  • [ 11 ] [Jiang, Lilong]Fuzhou Univ, Natl Engn Res Ctr Chem Fertilizer Catalyst NERC C, Sch Chem Engn, Fuzhou 350002, Peoples R China

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Source :

APPLIED ENERGY

ISSN: 0306-2619

Year: 2022

Volume: 307

1 1 . 2

JCR@2022

1 0 . 1 0 0

JCR@2023

ESI Discipline: ENGINEERING;

ESI HC Threshold:66

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 27

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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