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学者姓名：江莉龙
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Abstract ：
【目的】绿氨作为氢能的优质载体，生产工艺无碳化的优势使其成为实现碳中和目标的备选能源之一，因此绿氨终端站的布局与建设对促进氢能产业链的快速发展具有重要作用，有利于推动社会能源结构的绿色转型。【方法】概述了氨的性质：氨作为高效的储能与储氢介质，具有高能量密度、易储运、终端站无碳排放、安全性高等特点，能够显著降低储氢、运氢、用氢的成本，并可提高能源安全性。分析了氨用于储氢与储能介质具有的能量密度高、安全、长时储能等优势，调研了全球多国的氨氢项目发展与贸易情况，论述了全球快速增长的绿氨产能及需求，总结了目前氨能的贸易现状与终端站建设情况；对比目前成熟的LNG接收站相关工艺技术，详细介绍了绿氨终端站的关键工艺及技术，包括终端站绿氨存储工艺系统、液氨蒸发气处理工艺系统、终端站加注及卸载工艺系统。【结果】提出绿氨终端站的安全性问题，深入剖析了终端站液氨泄漏导致的毒性、燃烧爆炸性等危害，并给出了预防及防护措施。【结论】从化肥行业到能源领域，绿氨终端站技术的研究与发展对促进绿色能源氢能的利用具有重要意义，未来绿氨终端站的数量与规模将持续增加以适应新时代的需求，同时可以考虑改造LNG接收站等大宗能源及化工品储运设施以降低成本。（图5，表3，参59）
Keyword ：
储氢载体 储氢载体 接收工艺 接收工艺 接收终端 接收终端 液氨泄漏 液氨泄漏 碳中和 碳中和 绿氢 绿氢 绿氨 绿氨 绿色能源 绿色能源
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| GB/T 7714 | 滕霖 , 林崴 , 尹鹏博 et al. 碳中和目标下绿氨终端站储运技术发展现状及趋势 [J]. | 油气储运 , 2024 , 43 (01) : 1-11 . |
| MLA | 滕霖 et al. "碳中和目标下绿氨终端站储运技术发展现状及趋势" . | 油气储运 43 . 01 (2024) : 1-11 . |
| APA | 滕霖 , 林崴 , 尹鹏博 , 李卫东 , 黄鑫 , 李加庆 et al. 碳中和目标下绿氨终端站储运技术发展现状及趋势 . | 油气储运 , 2024 , 43 (01) , 1-11 . |
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【目的】在“双碳”背景下，氨作为无碳富氢的能源载体，体积能量密度高、易液化存储，具有广阔的发展前景。然而复杂的储运环境增加了液氨储罐和管道腐蚀的风险，因此，研究复杂输送环境下液氨腐蚀问题是“氨-氢”能源基础设施制造和安全服役的关键。【方法】通过综述液氨腐蚀的研究进展，探讨了不同环境、不同材料的氨腐蚀行为和应力腐蚀开裂机制。同时，总结了相关氨腐蚀检测方法和具体防护措施，并展望了未来氨腐蚀研究的发展方向。【结果】氧气、碳氧化合物、硫化物及氯化物的混入对氨腐蚀有促进作用，而水杂质对氨腐蚀的影响具有两面性；应力能够引起液氨应力腐蚀开裂，不同材料的应力腐蚀敏感性从大到小依次为铜及其合金、高强钢、碳钢。【结论】基于国内对液氨腐蚀行为机理尚不明确、氨腐蚀防护措施有待完善等问题，提出以下建议：(1)采用实验研究、仿真模拟等方法，探究多杂质关联作用下不同材质的液氨腐蚀行为和内在腐蚀机理；(2)需结合液氨管道实际输送环境及材料失效特征，开展管线钢及焊材-液氨临界失效边界检验与腐蚀风险评价；(3)从液氨储罐及管道的设计、选材、制造、使用等多个角度，结合多种腐蚀防腐措施，形成完善的液氨储运系统腐蚀控制、防护及评价标准体系。（图5，表2，参77）
Keyword ：
应力腐蚀 应力腐蚀 液氨储运 液氨储运 环境腐蚀 环境腐蚀 腐蚀检测 腐蚀检测 防护技术 防护技术
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| GB/T 7714 | 李加庆 , 冯智雨 , 梁辉龙 et al. 复杂输送环境下液氨腐蚀行为及防护技术研究进展 [J]. | 油气储运 , 2024 , 43 (02) : 121-133,162 . |
| MLA | 李加庆 et al. "复杂输送环境下液氨腐蚀行为及防护技术研究进展" . | 油气储运 43 . 02 (2024) : 121-133,162 . |
| APA | 李加庆 , 冯智雨 , 梁辉龙 , 尹鹏博 , 滕霖 , 陈崇启 et al. 复杂输送环境下液氨腐蚀行为及防护技术研究进展 . | 油气储运 , 2024 , 43 (02) , 121-133,162 . |
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Developing efficient anode catalysts for direct ammonia solid oxide fuel cells (NH3-SOFCs) under intermediate-temperatures is of great importance, in support of hydrogen economy via ammonia utilization. In the present work, the pyrochlore-type La2Zr2-xNixO7+delta (LZN(x), x = 0, 0.02, 0.05, 0.08, 0.10) oxides were synthesized as potential anode catalysts of NH3-SOFCs due to the abundant Frankel defect that contributes to the good conductivity and oxygen ion mobility capacity. The effects of different content of Ni2+ doping on the crystal structure, surface morphology, thermal matching with YSZ (Yttria-stabilized zirconia), conductivity, and electrochemical performance of pyrochlore oxides were examined using different characterization techniques. The findings indicate that the LZN(x) oxide behaves as an n-type semiconductor and exhibits an excellent high-temperature chemical compatibility and thermal matching with the YSZ electrolyte. Furthermore, LZN(0.05) exhibits the smallest conductive band potential and bandgap, making it have a higher power density as anode material for NH3-SOFCs compared to other anodes. As a result, the maximum power density of the LZN(0.05)-40YSZ composite anode reaches 100.86 mW/cm(2) at 800 degrees C, which is 1.8 times greater than that of NiO-based NH3-SOFCs (56.75 mW/cm(2)) under identical flow rate and temperature conditions. The extended durability indicates that the NH3-SOFCs utilizing the LZN(0.05)-40YSZ composite anode exhibits a negligible voltage degradation following uninterrupted operation at 800 degrees C for 100 h.
Keyword ：
ammonia oxidation ammonia oxidation anode catalyst anode catalyst NH3-SOFCs NH3-SOFCs Ni particles Ni particles
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| GB/T 7714 | Yang, Shiqing , Gao, Yijie , Wang, Xinmin et al. Pyrochlore La2Zr2-xNixO7 anodes for direct ammonia solid oxide fuel cells [J]. | FRONTIERS IN ENERGY , 2024 , 18 (5) : 699-711 . |
| MLA | Yang, Shiqing et al. "Pyrochlore La2Zr2-xNixO7 anodes for direct ammonia solid oxide fuel cells" . | FRONTIERS IN ENERGY 18 . 5 (2024) : 699-711 . |
| APA | Yang, Shiqing , Gao, Yijie , Wang, Xinmin , Zhong, Fulan , Fang, Huihuang , Luo, Yu et al. Pyrochlore La2Zr2-xNixO7 anodes for direct ammonia solid oxide fuel cells . | FRONTIERS IN ENERGY , 2024 , 18 (5) , 699-711 . |
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Ammonia decomposition for onsite hydrogen production has been regarded as an important reaction which links to efficient hydrogen storage, transport and utilization. However, it still remains challenging to develop efficient catalysts with robust stability for ammonia decomposition. Herein, an integrated strategy was employed to synthesize Ru/SiO2@N-CS via wrapping a thin layer of N-doped carbon onto the SiO2 sphere, following the anchor of Ru nanoparticles (NPs) onto the support. The obtained Ru/SiO2@N-CS (Ru loading: 1 wt%) shows a promising performance for ammonia decomposition, reaching 94.5 % at 550 °C with a gas hourly space velocity (GHSV) of 30 000 mL gcat-1h−1. The combination of the SiO2 as the core prevents the degradation of N-doped carbon layers and then enhance the durability of the catalysts, remaining stable after 50 h at evaluated temperatures. Adequate characterizations were used to illustrate the effect of microchemical environment on ammonia decomposition activity of Ru/SiO2@N-CS catalyst under different calcination atmosphere and the correlation between structure and performance. © 2024 Elsevier B.V.
Keyword ：
Ammonia decomposition Ammonia decomposition N-doped carbon N-doped carbon Ruthenium Ruthenium SiO2 SiO2 Stability Stability
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| GB/T 7714 | Huang, Y. , Ren, H. , Fang, H. et al. Ru nanoparticles embedded in Ru/SiO2@N-CS for boosting hydrogen production via ammonia decomposition with robust lifespan [J]. | Applied Surface Science , 2024 , 669 . |
| MLA | Huang, Y. et al. "Ru nanoparticles embedded in Ru/SiO2@N-CS for boosting hydrogen production via ammonia decomposition with robust lifespan" . | Applied Surface Science 669 (2024) . |
| APA | Huang, Y. , Ren, H. , Fang, H. , Ouyang, D. , Chen, C. , Luo, Y. et al. Ru nanoparticles embedded in Ru/SiO2@N-CS for boosting hydrogen production via ammonia decomposition with robust lifespan . | Applied Surface Science , 2024 , 669 . |
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The design of novel practical catalysts is critical for the blossoming of biodiesel green-energy, in which Mo-based catalysts are of particular interest. In this work, an in-situ synthesis method was proposed to obtain a combo Mo-based ionic liquid and SAPO-11 catalyst. The catalyst presents both highly dispersed MoS2 as hydrodeoxygenation active sites and acidic sites for isomerization. MoS2 with a few fine layers can be identified based on TEM images and the Bronsted acid sites are dominant based on Pyridine-IR analysis. A great performance of MoS2/C(8)min-15 %SA can be obtained under optimized reaction conditions with 100 % conversion of methyl palmitate, 75.0 mol% hydrodeoxygenation to n-C-15-C-16, and 20.5 mol % isomerization to i-C-15-C-16. The structure and activity of the catalyst can be retained at least for 4 cycles. Thin layers and high sulfurization, large amount of Br & oslash;nsted acid sites, and suitable reaction conditions are key points to achieve a significant performance and avoid over cracking and deactivation. On basis of detected intermediates and kinetic data simulations, a complex reaction pathway was proposed and the specific k values for each elementary reaction were provided for the hydrodeoxygenation and isomerization of methyl palmitate.
Keyword ：
Biodiesel Biodiesel Hydrodeoxygenation Hydrodeoxygenation Isomerization Isomerization Methyl palmitate Methyl palmitate MoS2 MoS2 SAPO-11 SAPO-11
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| GB/T 7714 | Ding, Yongxin , Lin, Jun , Yu, Panjie et al. An in-situ combo Mo-based ionic liquid and SAPO-11 catalyst for efficient biolipids hydrodeoxygenation and isomerization [J]. | FUEL , 2024 , 362 . |
| MLA | Ding, Yongxin et al. "An in-situ combo Mo-based ionic liquid and SAPO-11 catalyst for efficient biolipids hydrodeoxygenation and isomerization" . | FUEL 362 (2024) . |
| APA | Ding, Yongxin , Lin, Jun , Yu, Panjie , Zhang, Hongwei , Ma, Yongde , Cai, Zhenping et al. An in-situ combo Mo-based ionic liquid and SAPO-11 catalyst for efficient biolipids hydrodeoxygenation and isomerization . | FUEL , 2024 , 362 . |
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Ammonia (NH3) is closely related to the fields of food and energy that humans depend on. The exploitation of advanced catalysts for NH3 synthesis has been a research hotspot for more than one hundred years. Previous studies have shown that the Ru B5 sites (step sites on the Ru (0001) surface uniquely arranged with five Ru atoms) and Fe C7 sites (iron atoms with seven nearest neighbors) over nanoparticle catalysts are highly reactive for N2-to-NH3 conversion. In recent years, single-atom and cluster catalysts, where the B5 sites and C7 sites are absent, have emerged as promising catalysts for efficient NH3 synthesis. In this review, we focus on the recent advances in single-atom and cluster catalysts, including single-atom catalysts (SACs), single-cluster catalysts (SCCs), and bimetallic-cluster catalysts (BCCs), for thermocatalytic NH3 synthesis at mild conditions. In addition, we discussed and summarized the unique structural properties and reaction performance as well as reaction mechanisms over single-atom and cluster catalysts in comparison with traditional nanoparticle catalysts. Finally, the challenges and prospects in the rational design of efficient single-atom and cluster catalysts for NH3 synthesis were provided. Recent advances in single-atom and cluster catalysts, including single-atom catalysts (SACs), single-cluster catalysts (SCCs), and bimetallic-cluster catalysts (BCCs), for thermocatalytic NH3 synthesis at mild conditions.
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| GB/T 7714 | Peng, Xuanbei , Zhang, Mingyuan , Zhang, Tianhua et al. Single-atom and cluster catalysts for thermocatalytic ammonia synthesis at mild conditions [J]. | CHEMICAL SCIENCE , 2024 , 15 (16) : 5897-5915 . |
| MLA | Peng, Xuanbei et al. "Single-atom and cluster catalysts for thermocatalytic ammonia synthesis at mild conditions" . | CHEMICAL SCIENCE 15 . 16 (2024) : 5897-5915 . |
| APA | Peng, Xuanbei , Zhang, Mingyuan , Zhang, Tianhua , Zhou, Yanliang , Ni, Jun , Wang, Xiuyun et al. Single-atom and cluster catalysts for thermocatalytic ammonia synthesis at mild conditions . | CHEMICAL SCIENCE , 2024 , 15 (16) , 5897-5915 . |
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The capture the low-content NH3 from industrial streams, and recycle it as the feedstocks for industrial processes is very important. In this work, we reported the use of mesoporous polydivinylbenzene (PDVB) as the support of metal-based deep eutectic solvents (DESs) containing choline chloride (ChCl) and metal chlorides (SnCl2, FeCl3 or ZnCl2) for NH3 capture. The structure of composite materials was characterized in details, and the NH3 capture performance and mechanism of them were also examined in depth. Owing to the coordination interaction of metal ions with NH3, along with the hydrogen-bond interaction of - OH and Cl- with NH3, the DES@PDVB composites exhibit considerably high low-content NH3 capacities. The optimized sample ChCl + 2ZnCl2@PDVB1.5 can adsorb 7.43 mol/kg of NH3 at 25 degree celsius and 0.122 bar, which is advantageous over most other adsorbents fabricated in the literature. The mechanism of NH3 capture by DES@PDVB composites was also illustrated through spectroscopic characterizations.
Keyword ：
Deep eutectic solvent Deep eutectic solvent Low content Low content Mesoporous polymer Mesoporous polymer Multiple interaction Multiple interaction NH 3 capture NH 3 capture
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| GB/T 7714 | Zhang, Jiayin , Fang, Siqi , Zheng, Lu et al. Mesoporous polymer supported Metal-Based deep eutectic solvents for enhanced capture of Low-Content Ammonia [J]. | CHEMICAL ENGINEERING JOURNAL , 2024 , 493 . |
| MLA | Zhang, Jiayin et al. "Mesoporous polymer supported Metal-Based deep eutectic solvents for enhanced capture of Low-Content Ammonia" . | CHEMICAL ENGINEERING JOURNAL 493 (2024) . |
| APA | Zhang, Jiayin , Fang, Siqi , Zheng, Lu , Cao, Yanning , Zhang, Hongwei , Cai, Zhenping et al. Mesoporous polymer supported Metal-Based deep eutectic solvents for enhanced capture of Low-Content Ammonia . | CHEMICAL ENGINEERING JOURNAL , 2024 , 493 . |
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The use of bio-oil-based polymers in fertilizer coatings has drawn significant academic interest. However, the challenge remains to eliminate toxic chemicals while enhancing comprehensive properties. This study focused on synthesizing a degradable polymer from epoxidized soybean oil (ESO) without organic solvent at low temperature (120°C), accomplished through a modified curing agent (MCA). This MCA was made of an acidic eutectic mixture of phthalic anhydride (PA) and its glycerides, produced from inexpensive, low-toxic phthalic anhydride and glycerol. The process utilized a small quantity of zinc acetate (0.5 wt%) to facilitate the formation of phthalic triglyceride in the MCA and mitigate PA sublimation, resulting in the enhanced cross-link degree, superior mechanical properties and hydrophobicity of the ESO-based resin (ESOR). Under optimal preparation conditions, the solvent-free ESOR-coated fertilizer exhibited an extended longevity of 53 days, with an 80 % phosphorus release. This coating material can undergo hydrolytic degradation in soil and in-situ conversion into carboxylates. These findings hold significant potential for advancing the applications of ESOR in green and sustainable agriculture. © 2024 Elsevier B.V.
Keyword ：
Carboxylation Carboxylation Curing Curing Fertilizers Fertilizers Plastic coatings Plastic coatings Soybean oil Soybean oil Temperature Temperature Zinc compounds Zinc compounds
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| GB/T 7714 | Zhan, Yingying , Guo, Caiyan , Yang, Honglin et al. Moderate-temperature curing of epoxidized soybean oil for highly efficient coated fertilizer [J]. | Industrial Crops and Products , 2024 , 220 . |
| MLA | Zhan, Yingying et al. "Moderate-temperature curing of epoxidized soybean oil for highly efficient coated fertilizer" . | Industrial Crops and Products 220 (2024) . |
| APA | Zhan, Yingying , Guo, Caiyan , Yang, Honglin , Li, Xiang , Wang, Shiping , Zheng, Xiaohai et al. Moderate-temperature curing of epoxidized soybean oil for highly efficient coated fertilizer . | Industrial Crops and Products , 2024 , 220 . |
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gamma-ray radiation-induced grafting strategy was first employed to immobilize 4-aminobenzo-15-crown-5 onto a covalent organic framework (COF). This endeavor culminated in the successful synthesis of a class of two-dimensional crown ether-modified COFs (named [15C5]n%-(TzDa-G-x%)), marking the maiden utilization of COFs in the realm of 6Li/7Li isotope separation. These COFs exhibited swifter adsorption kinetics than alternative adsorbents. Among them, [15C5]57%-(TzDa-G-50%) with its excellent crystallinity, porosity, and stability exhibited the best performance in Li+ adsorption and 6Li/7Li isotope separation. The Li+ adsorption in acetonitrile achieved a capacity of 3.6 mg center dot g-1 within 30 min and a saturation capacity of 7.3 mg center dot g-1. The single -stage separation factor of 6Li/7Li isotopes was 1.014 +/- 0.001. The results of dynamic adsorption column experiments showed that the packed column made of [15C5]57%-(TzDa-G-50%) maintained stable performance during four cycles of Li+ adsorptionelution, with over 99% Li+ removal rate in acetonitrile. This crown ether-modified COF has potential application in 6Li/7Li isotope separation, and this radiation-assisted synthesis strategy is expected to become universal in the modification of COFs for diverse applications.
Keyword ：
6Li/7Li isotope separation 6Li/7Li isotope separation adsorption column adsorption column covalent organic framework covalent organic framework crown ether crown ether gamma ra- diation modification gamma ra- diation modification
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| GB/T 7714 | Zhong, Shouchao , Wang, Yue , Lan, Jianhui et al. Radiation-Assisted Synthesis of Crown Ether-Modified Covalent Organic Frameworks for Lithium Isotope Separation [J]. | CCS CHEMISTRY , 2024 , 6 (10) : 2594-2606 . |
| MLA | Zhong, Shouchao et al. "Radiation-Assisted Synthesis of Crown Ether-Modified Covalent Organic Frameworks for Lithium Isotope Separation" . | CCS CHEMISTRY 6 . 10 (2024) : 2594-2606 . |
| APA | Zhong, Shouchao , Wang, Yue , Lan, Jianhui , Xie, Mingshu , Wu, Yiqian , Li, Jiuqiang et al. Radiation-Assisted Synthesis of Crown Ether-Modified Covalent Organic Frameworks for Lithium Isotope Separation . | CCS CHEMISTRY , 2024 , 6 (10) , 2594-2606 . |
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A series of mesoporous polymers functionalized with different kinds and contents of Br & oslash; nsted acidic sites were designed and synthesized for NH 3 capture. The textural properties, morphologies and chemical structures of synthesized mesoporous polymers were characterized in details, and the NH 3 capture performance was evaluated systematically. It is found that the mesoporous polymers functionalized with phosphoric sites exhibit much better NH 3 capture performance at low pressures than those with carboxylic and sulfonic sites. Specifically, the NH 3 adsorption capacities of P(DVB-VPA)-4.0 can reach 4.82 mmol/g at 298.2 K and 0.033 bar. The excellent ability of P(DVB-VPA)-4.0 for selectively adsorbing low -content NH 3 from NH 3 /N 2 /H 2 and NH 3 /N 2 /CO 2 mixed gases was demonstrated by breakthrough experiments, and the adsorption of NH 3 by P(DVB-VPA)-4.0 is found to be mostly reversible. The thermodynamic properties and mechanism of NH 3 adsorption were also examined in depth, disclosing the important role of Br & oslash; nsted acidic sites in enhanced capture of low -content NH 3 by P(DVBVPA)-4.0.
Keyword ：
Acid -base interaction Acid -base interaction Br & oslash;nsted acidic site Br & oslash;nsted acidic site Low content Low content Mesoporous polymer Mesoporous polymer NH 3 capture NH 3 capture
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| GB/T 7714 | Zheng, Lu , Shi, Leilian , Li, Qiuke et al. Designing Brønsted acidic sites on mesoporous polymers for enhanced capture of low-content ammonia [J]. | CHEMICAL ENGINEERING SCIENCE , 2024 , 292 . |
| MLA | Zheng, Lu et al. "Designing Brønsted acidic sites on mesoporous polymers for enhanced capture of low-content ammonia" . | CHEMICAL ENGINEERING SCIENCE 292 (2024) . |
| APA | Zheng, Lu , Shi, Leilian , Li, Qiuke , Zhang, Hongwei , Cai, Zhenping , Huang, Kuan et al. Designing Brønsted acidic sites on mesoporous polymers for enhanced capture of low-content ammonia . | CHEMICAL ENGINEERING SCIENCE , 2024 , 292 . |
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