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author:

Chen, Fei-Fei (Chen, Fei-Fei.) [1] (Scholars:陈飞飞) | Chen, Junbin (Chen, Junbin.) [2] | Li, Lingyun (Li, Lingyun.) [3] (Scholars:李凌云) | Peng, Feng (Peng, Feng.) [4] | Yu, Yan (Yu, Yan.) [5] (Scholars:于岩)

Indexed by:

EI SCIE

Abstract:

Carbon nitrides (g-C3N4) have emerged as the promising photocatalysts for CO2 conversion. However, they suffer from inefficient charge transfer and a lack of metal sites. Herein, the p-type CoNiO2 nanosheets are anchored on the n-type g-C3N4 microtubes to construct p-n heterojunction photocatalysts. The CoNiO2 nanosheets provide metal sites to bind and activate CO2 molecules, and the configuration of p-n heterojunction impels electron-hole separation. The CoNiO2 nanosheets that are vertically aligned on the surfaces of g-C3N4 microtubes build a hierarchical hollow structure and an intimate contact interface, which also contributes to the CO2 adsorption and rapid migration of charged carriers. As a result, the g-C3N4@CoNiO2 p-n heterojunction photocatalysts exhibit outstanding yields (3645 mu mol h-1 g-1 of CO and 943 mu mol h-1 g-1 of H2) from CO2 reduction under visible light irradiation, much higher than that of pure CoNiO2 nanosheets and g-C3N4 microtubes. In situ DRIFT spectra are performed to monitor the intermediates of CO2 reduction on the surfaces of g-C3N4@CoNiO2, the results of which confirm the adsorption and activation of CO2 molecules. It is expected that this work would provide a feasible strategy for designing high-efficiency g-C3N4-based heterojunction photocatalysts.

Keyword:

CoNiO( 2 )nanosheets g-C3N4&nbsp Hierarchical structure microtubes Photocatalytic CO2 reduction p-n heterojunction

Community:

  • [ 1 ] [Chen, Fei-Fei]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 2 ] [Chen, Junbin]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 3 ] [Li, Lingyun]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 4 ] [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China
  • [ 5 ] [Peng, Feng]Guangdong Acad Med Sci, Guangdong Prov Peoples Hosp, Dept Orthoped, Guangzhou 510080, Peoples R China

Reprint 's Address:

  • 陈飞飞 于岩

    [Chen, Fei-Fei]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China;;[Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Fuzhou 350108, Peoples R China;;[Peng, Feng]Guangdong Acad Med Sci, Guangdong Prov Peoples Hosp, Dept Orthoped, Guangzhou 510080, Peoples R China

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Source :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

Year: 2021

Volume: 579

7 . 3 9 2

JCR@2021

6 . 3 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 24

SCOPUS Cited Count: 25

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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