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B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect SCIE
期刊论文 | 2025 , 36 (2) | CHINESE CHEMICAL LETTERS
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Abstract :

Birefringent crystals play an irreplaceable role in optical systems by adjusting the polarization state of light in optical devices. This work successfully synthesized a new thiophosphate phase of B-Pb3 P2 S8 through the high-temperature solid-state spontaneous crystallization method. Different from the cubic a-Pb3 P2 S8 , the B-Pb3 P2 S8 crystallizes in the orthorhombic Pbcn space group. Notably, B-Pb3 P2 S8 shows a large band gap of 2.37 eV in lead-based chalcogenides, wide infrared transparent window (2.5-15 mu m), and excellent thermal stability. Importantly, the experimental birefringence shows the largest value of 0.26@550 nm in chalcogenides, even larger than the commercialized oxide materials. The Barder charge analysis result indicates that the exceptional birefringence effect is mainly from the Pb2 + and S2- in the [PbSn ] polyhedrons. Meanwhile, the parallelly arranged polyhedral layers could improve the structural anisotropic. Therefore, this work supports a new method for designing chalcogenides with exceptional birefringence effect in the infrared region. (c) 2024 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.

Keyword :

Birefringent crystals Birefringent crystals Chalcogenides Chalcogenides Optical properties Optical properties Structural ansotropic Structural ansotropic

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GB/T 7714 Guo, Weiping , Zhu, Ying , Cui, Hong-Hua et al. B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect [J]. | CHINESE CHEMICAL LETTERS , 2025 , 36 (2) .
MLA Guo, Weiping et al. "B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect" . | CHINESE CHEMICAL LETTERS 36 . 2 (2025) .
APA Guo, Weiping , Zhu, Ying , Cui, Hong-Hua , Li, Lingyun , Yu, Yan , Luo, Zhong-Zhen et al. B-Pb 3 P 2 S 8: A new optical crystal with exceptional birefringence effect . | CHINESE CHEMICAL LETTERS , 2025 , 36 (2) .
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β-Pb3P2S8: A new optical crystal with exceptional birefringence effect Scopus
期刊论文 | 2025 , 36 (2) | Chinese Chemical Letters
Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts SCIE
期刊论文 | 2025 , 13 (7) , 4718-4745 | JOURNAL OF MATERIALS CHEMISTRY A
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Abstract :

Heterojunction photocatalysts, which consist of two or more semiconductors, have garnered significant attention owing to their extensive benefits, including a broad-spectrum response, efficient carrier separation and migration, as well as robust redox capabilities. Among the myriad of semiconductors, graphitic carbon nitride (g-C3N4) and zinc indium sulfide (ZnIn2S4) have been extensively researched due to their low toxicity, straightforward and scalable synthesis processes, controllable microstructures, and exceptional chemical stability. Recently, there has been a trend towards integrating these two semiconductors to complement each other's strengths. Consequently, a systematic summary and outlook on g-C3N4/ZnIn2S4 heterojunction photocatalysts is both urgent and valuable. This review summarizes the advancements in the g-C3N4/ZnIn2S4 heterojunctions in the last 10 years. We first analyzed the charge-transfer mechanisms in the type-I, type-II, Z-scheme and S-scheme heterojunctions. Then the typical synthesis methods employed for creating g-C3N4/ZnIn2S4 heterojunctions are introduced. Subsequently, we delve into the regulation strategies for g-C3N4/ZnIn2S4 heterojunctions, including morphology optimization, heteroatom doping, defect engineering, and the construction of multinary composites. The design concept and superiorities of these strategies are thoroughly discussed. Following this, we systematically showcase the photocatalytic applications of g-C3N4/ZnIn2S4 heterojunctions, encompassing CO2 reduction, H2 evolution, pollutant degradation, H2O2 production, biomass conversion, photoelectrochemical sensors, and so forth. Last, we propose the challenges that lie ahead in future research endeavors. This comprehensive review is expected to provide an instructive guideline for rational design and applications of g-C3N4/ZnIn2S4 heterojunctions.

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GB/T 7714 Lu, Yongjun , Zhuang, Zanyong , Li, Lingyun et al. Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts [J]. | JOURNAL OF MATERIALS CHEMISTRY A , 2025 , 13 (7) : 4718-4745 .
MLA Lu, Yongjun et al. "Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts" . | JOURNAL OF MATERIALS CHEMISTRY A 13 . 7 (2025) : 4718-4745 .
APA Lu, Yongjun , Zhuang, Zanyong , Li, Lingyun , Chen, Fei-Fei , Wei, Peishu , Yu, Yan . Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts . | JOURNAL OF MATERIALS CHEMISTRY A , 2025 , 13 (7) , 4718-4745 .
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Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts Scopus
期刊论文 | 2025 , 13 (7) , 4718-4745 | Journal of Materials Chemistry A
Advancements and challenges in g-C3N4/ZnIn2S4 heterojunction photocatalysts EI
期刊论文 | 2025 , 13 (7) , 4718-4745 | Journal of Materials Chemistry A
Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic-inorganic hybrid metal halide crystals SCIE
期刊论文 | 2025 , 68 (4) , 1004-1011 | SCIENCE CHINA-MATERIALS
Abstract&Keyword Cite Version(3)

Abstract :

The influence of hydrogen bonding on spectroscopic properties is one of the fundamental issues in the field of luminescent organic-inorganic hybrid metal halides (OIMHs). We design and prepare three OIMHs, namely, crystals 1, 2 and 3, using 2,2 '-bipyridine and ZnCl2 as starting materials. From crystals 1 to 3, the hydrogen bonding environment surrounding the 2,2 '-bipyridinium cations gradually weakens, with both the dihedral angle and the number of hydrogen bonds around them decreasing progressively. Correspondingly, the blue emission belonging to the S1 -> S0 transition of the three crystals gradually increases, with crystal 3 exhibiting the strongest blue light emission and a photo-luminescence quantum yield reaching 34.10%. In crystal 1, the dense hydrogen bonding environment of the 2,2 '-bipyridinium cation results in an obvious energy transfer from S1 to T1. This reduces the population of the S1 state, thereby leading to weaker blue light emission. In crystals 2 and 3, the weaker hydrogen bonding environment and smaller spatial distortion of organic cations weaken or even prevent energy transfer between S1 and T1, thereby enhancing blue light emission. These findings provide new insights for exploring novel luminescent OIMHs and developing more effective means of regulating their luminescence performance. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)-(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) (sic)(OIMHs)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)2,2 '-(sic)(sic)(sic)(sic)ZnCl2(sic)(sic)(sic), (sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)OIMH, (sic)(sic)(sic)1,2(sic)3. (sic)(sic)(sic)1(sic)(sic)(sic)3, 2,2 '-(sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) (sic). (sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)S1 -> S0(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)3 (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)34.10%. (sic)(sic)(sic)1(sic), 2,2 '-(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)S1(sic)T1(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic) (sic)(sic)S1(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)2(sic)3(sic), (sic)(sic)(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)S1(sic)T1(sic)(sic)(sic) (sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic). (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)OIMHs(sic) (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

Keyword :

blue emission blue emission hydrogen bonding hydrogen bonding optical materials optical materials organic-inorganic hybrid metal halides organic-inorganic hybrid metal halides photoluminescence photoluminescence

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GB/T 7714 Zhang, Qi , Huang, Tianwen , Liu, Zheyuan et al. Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic-inorganic hybrid metal halide crystals [J]. | SCIENCE CHINA-MATERIALS , 2025 , 68 (4) : 1004-1011 .
MLA Zhang, Qi et al. "Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic-inorganic hybrid metal halide crystals" . | SCIENCE CHINA-MATERIALS 68 . 4 (2025) : 1004-1011 .
APA Zhang, Qi , Huang, Tianwen , Liu, Zheyuan , Feng, Ya-Nan , Yu, Yan , Li, Lingyun . Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic-inorganic hybrid metal halide crystals . | SCIENCE CHINA-MATERIALS , 2025 , 68 (4) , 1004-1011 .
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Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic–inorganic hybrid metal halide crystals EI
期刊论文 | 2025 , 68 (4) , 1004-1011 | Science China Materials
Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic–inorganic hybrid metal halide crystals; [一系列锌基有机-无机杂化金属卤化物晶体中的氢键 演变和高效蓝光发射] Scopus
期刊论文 | 2025 , 68 (4) , 1004-1011 | Science China Materials
Hydrogen bonding evolution and efficient blue light emission in a series of Zn-based organic–inorganic hybrid metal halide crystals; [一系列锌基有机-无机杂化金属卤化物晶体中的氢键 演变和高效蓝光发射] Scopus
期刊论文 | 2025 | Science China Materials
Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications Scopus
期刊论文 | 2024 , 36 (39) | Advanced Materials
SCOPUS Cited Count: 9
Abstract&Keyword Cite

Abstract :

Organic-inorganic hybrid manganese(II) halides (OIMnHs) have garnered tremendous interest across a wide array of research fields owing to their outstanding optical properties, abundant structural diversity, low-cost solution processibility, and low toxicity, which make them extremely suitable for use as a new class of luminescent materials for various optoelectronic applications. Over the past years, a plethora of OIMnHs with different structural dimensionalities and multifunctionalities such as efficient photoluminescence (PL), radioluminescence, circularly polarized luminescence, and mechanoluminescence have been newly created by judicious screening of the organic cations and inorganic Mn(II) polyhedra. Specifically, through precise molecular and structural engineering, a series of OIMnHs with near-unity PL quantum yields, high anti-thermal quenching properties, and excellent stability in harsh conditions have been devised and explored for applications in light-emitting diodes (LEDs), X-ray scintillators, multimodal anti-counterfeiting, and fluorescent sensing. In this review, the latest advancements in the development of OIMnHs as efficient light-emitting materials are summarized, which covers from their fundamental physicochemical properties to advanced optoelectronic applications, with an emphasis on the structural and functionality design especially for LEDs and X-ray detection and imaging. Current challenges and future efforts to unlock the potentials of these promising materials are also envisioned. © 2024 Wiley-VCH GmbH.

Keyword :

anti-counterfeiting anti-counterfeiting circularly polarized luminescence circularly polarized luminescence hybrid manganese halide hybrid manganese halide light-emitting diode light-emitting diode mechanoluminescence mechanoluminescence photoluminescence photoluminescence X-ray scintillator X-ray scintillator

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GB/T 7714 Zhang, W. , Zheng, W. , Li, L. et al. Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications [J]. | Advanced Materials , 2024 , 36 (39) .
MLA Zhang, W. et al. "Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications" . | Advanced Materials 36 . 39 (2024) .
APA Zhang, W. , Zheng, W. , Li, L. , Huang, P. , Xu, J. , Shao, Z. et al. Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications . | Advanced Materials , 2024 , 36 (39) .
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Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes EI
期刊论文 | 2024 , 9 (10) , 5215-5224 | ACS Energy Letters
Abstract&Keyword Cite

Abstract :

Studying lithium growth on diverse substrates with unique crystal structures is crucial for linking atomic and macroscopic views, which ensures a long cycle life and safety in lithium metal batteries. This work provides explanations on (1) the stages of nucleation, which are influenced by the adsorption-relaxation mechanism, (2) acquiring evolved traits of dendritic morphology from the embryo, and (3) the integration of the atomic and macroscopic perspectives through a variety of techniques at different scales to validate dendrite evolution. The heteroepitaxial growth process of the embryos is divided into two principal stages: nucleation and growth. The adsorption-type substrates exhibit characteristics of relatively lower average interaction energy and specific stress energy during the nucleation stage. At the growth stage, the adsorption-type substrate tends to facilitate multilayer growth. This work provides potential to design and material selection for lithium metal batteries, contributing to the development of safer, more efficient, and longer-lasting energy storage systems. © 2024 American Chemical Society.

Keyword :

Crystal atomic structure Crystal atomic structure Epitaxial growth Epitaxial growth Indium phosphide Indium phosphide Lithium batteries Lithium batteries

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GB/T 7714 Li, Borong , Zhang, Weicheng , Yang, Kang et al. Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes [J]. | ACS Energy Letters , 2024 , 9 (10) : 5215-5224 .
MLA Li, Borong et al. "Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes" . | ACS Energy Letters 9 . 10 (2024) : 5215-5224 .
APA Li, Borong , Zhang, Weicheng , Yang, Kang , Li, Long , Luo, Jing , Lin, Qingqing et al. Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes . | ACS Energy Letters , 2024 , 9 (10) , 5215-5224 .
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Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications SCIE
期刊论文 | 2024 , 36 (39) | ADVANCED MATERIALS
WoS CC Cited Count: 2
Abstract&Keyword Cite Version(2)

Abstract :

Organic-inorganic hybrid manganese(II) halides (OIMnHs) have garnered tremendous interest across a wide array of research fields owing to their outstanding optical properties, abundant structural diversity, low-cost solution processibility, and low toxicity, which make them extremely suitable for use as a new class of luminescent materials for various optoelectronic applications. Over the past years, a plethora of OIMnHs with different structural dimensionalities and multifunctionalities such as efficient photoluminescence (PL), radioluminescence, circularly polarized luminescence, and mechanoluminescence have been newly created by judicious screening of the organic cations and inorganic Mn(II) polyhedra. Specifically, through precise molecular and structural engineering, a series of OIMnHs with near-unity PL quantum yields, high anti-thermal quenching properties, and excellent stability in harsh conditions have been devised and explored for applications in light-emitting diodes (LEDs), X-ray scintillators, multimodal anti-counterfeiting, and fluorescent sensing. In this review, the latest advancements in the development of OIMnHs as efficient light-emitting materials are summarized, which covers from their fundamental physicochemical properties to advanced optoelectronic applications, with an emphasis on the structural and functionality design especially for LEDs and X-ray detection and imaging. Current challenges and future efforts to unlock the potentials of these promising materials are also envisioned. This review focuses on the latest advancements in the development of organic-inorganic hybrid manganese(II) halides as efficient light-emitting materials, which covers from their fundamental physicochemical properties to advanced optoelectronic applications, with an emphasis on the structural and functionality design especially for light-emitting diodes and X-ray scintillators. Current challenges and future efforts toward this active research field are envisioned. image

Keyword :

anti-counterfeiting anti-counterfeiting circularly polarized luminescence circularly polarized luminescence hybrid manganese halide hybrid manganese halide light-emitting diode light-emitting diode mechanoluminescence mechanoluminescence photoluminescence photoluminescence X-ray scintillator X-ray scintillator

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GB/T 7714 Zhang, Wei , Zheng, Wei , Li, Lingyun et al. Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications [J]. | ADVANCED MATERIALS , 2024 , 36 (39) .
MLA Zhang, Wei et al. "Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications" . | ADVANCED MATERIALS 36 . 39 (2024) .
APA Zhang, Wei , Zheng, Wei , Li, Lingyun , Huang, Ping , Xu, Jin , Zhang, Wen et al. Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications . | ADVANCED MATERIALS , 2024 , 36 (39) .
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Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications Scopus
期刊论文 | 2024 , 36 (39) | Advanced Materials
Unlocking the Potential of Organic-Inorganic Hybrid Manganese Halides for Advanced Optoelectronic Applications EI
期刊论文 | 2024 , 36 (39) | Advanced Materials
Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries SCIE CSCD
期刊论文 | 2024 , 35 (6) | CHINESE CHEMICAL LETTERS
WoS CC Cited Count: 2
Abstract&Keyword Cite Version(1)

Abstract :

Side reactions and dendrite growth triggered by the unstable interface and inhomogeneous deposition have become the biggest obstacle to the commercialization for lithium metal batteries. In this study, a highly-chlorinated organic-inorganic hybrid interfacial protective layer is developed by rationally tuning the interfacial passivation and robustness to achieve the convenient and efficient Li metal anode. The polyvinyl chloride (PVC) can effectively resist water and oxygen, which is confirmed by density functional theory. The organic-dominant solid electrolyte interphases (SEI) with lithium chloride are investigated by the X-ray photoelectron spectroscopy (XPS) with little mineralization of oxide, such as Li2 O and Li2 CO3 . With such artificial SEI, a uniform and dense lithium deposition morphology are formed and an ultra-long stable cycle of over 500 h are achieved even at an ultra-high current density of 10 mA/cm2 . Moreover, the simple and convenient protected anode also exhibits excellent battery stability when paired with the LiNi0.8 Co0.1 Mn0.1 O2 (NCM811) and LiFePO4 (LFP) cathode, showing great potential for the commercial application of lithium metal batteries. (c) 2024 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.

Keyword :

Dendrite -free lithium metal batteries Dendrite -free lithium metal batteries Highly -chlorinated Highly -chlorinated High -rate High -rate Stable interphase Stable interphase Water/oxygen resistance Water/oxygen resistance

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GB/T 7714 Li, Long , Yang, Kang , Xi, Chenpeng et al. Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries [J]. | CHINESE CHEMICAL LETTERS , 2024 , 35 (6) .
MLA Li, Long et al. "Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries" . | CHINESE CHEMICAL LETTERS 35 . 6 (2024) .
APA Li, Long , Yang, Kang , Xi, Chenpeng , Li, Mengchao , Li, Borong , Xu, Gui et al. Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries . | CHINESE CHEMICAL LETTERS , 2024 , 35 (6) .
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Highly-chlorinated inert and robust interphase without mineralization of oxide enhancing high-rate Li metal batteries Scopus CSCD
期刊论文 | 2024 , 35 (6) | Chinese Chemical Letters
Tailoring the π-π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission SCIE
期刊论文 | 2024 , 12 (19) , 7053-7061 | JOURNAL OF MATERIALS CHEMISTRY C
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Abstract :

As an important interaction among organic cations containing aromatic rings, the pi-pi stacking interaction is a crucial factor determining the crystal structure of organic-inorganic hybrid metal halides (OIMHs). However, the relationship between pi-pi interaction and optical properties of luminescent OIMHs is yet to be studied. (C10H10N2)Cd1-xZnxCl4 (23-Cd1-xZnxCl4) crystals with 0D structures are synthesized by using optically active 2,3 '-bipyridine as the organic ligand. When x <= 0.2, there is no pi-pi interaction among 2,3 '-bipyridinium cations in 23-Cd1-xZnxCl4 crystals. When x > 0.2, pi-pi interaction among organic cations occurs and enhances as the Zn2+ content increases. The tailoring of the pi-pi interaction endows 23-Cd1-xZnxCl4 with tunable light emitting properties, resulting in a broad band emission involving blue and orange species. The blue emission dominates when there is no pi-pi interaction, while the orange emission enhances and finally becomes dominant as the strength of pi-pi interaction increases. The pi-pi interaction promotes the energy transfer from the higher energy valley to the lower one of the S-1 state of the organic cation, resulting in the enhancement of orange emission. Notably, the 23-ZnCl crystal exhibits a photo-luminescence quantum yield (PLQY) of 32%. This is the highest reported value to date among the Zn-based OIMHs, which have optical emission originating from the organic component. The mechanism of pi-pi stacking induced tunable light emission revealed in our work provides new guidance for the design of luminescent OIMHs.

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GB/T 7714 Zhang, Qi , Lin, Xinyi , Guo, Shanji et al. Tailoring the π-π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission [J]. | JOURNAL OF MATERIALS CHEMISTRY C , 2024 , 12 (19) : 7053-7061 .
MLA Zhang, Qi et al. "Tailoring the π-π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission" . | JOURNAL OF MATERIALS CHEMISTRY C 12 . 19 (2024) : 7053-7061 .
APA Zhang, Qi , Lin, Xinyi , Guo, Shanji , Zhang, Yaqing , Jiang, Yan , Zhang, Wei et al. Tailoring the π-π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission . | JOURNAL OF MATERIALS CHEMISTRY C , 2024 , 12 (19) , 7053-7061 .
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Tailoring the π-π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission EI
期刊论文 | 2024 , 12 (19) , 7053-7061 | Journal of Materials Chemistry C
Tailoring the π-π stacking interaction among organic cations in hybrid metal halide crystals towards tunable light emission Scopus
期刊论文 | 2024 , 12 (19) , 7053-7061 | Journal of Materials Chemistry C
Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes SCIE
期刊论文 | 2024 , 9 (10) , 5215-5224 | ACS ENERGY LETTERS
Abstract&Keyword Cite Version(2)

Abstract :

Studying lithium growth on diverse substrates with unique crystal structures is crucial for linking atomic and macroscopic views, which ensures a long cycle life and safety in lithium metal batteries. This work provides explanations on (1) the stages of nucleation, which are influenced by the adsorption-relaxation mechanism, (2) acquiring evolved traits of dendritic morphology from the embryo, and (3) the integration of the atomic and macroscopic perspectives through a variety of techniques at different scales to validate dendrite evolution. The heteroepitaxial growth process of the embryos is divided into two principal stages: nucleation and growth. The adsorption-type substrates exhibit characteristics of relatively lower average interaction energy and specific stress energy during the nucleation stage. At the growth stage, the adsorption-type substrate tends to facilitate multilayer growth. This work provides potential to design and material selection for lithium metal batteries, contributing to the development of safer, more efficient, and longer-lasting energy storage systems.

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GB/T 7714 Li, Borong , Zhang, Weicheng , Yang, Kang et al. Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes [J]. | ACS ENERGY LETTERS , 2024 , 9 (10) : 5215-5224 .
MLA Li, Borong et al. "Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes" . | ACS ENERGY LETTERS 9 . 10 (2024) : 5215-5224 .
APA Li, Borong , Zhang, Weicheng , Yang, Kang , Li, Long , Luo, Jing , Lin, Qingqing et al. Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes . | ACS ENERGY LETTERS , 2024 , 9 (10) , 5215-5224 .
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Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes Scopus
期刊论文 | 2024 , 9 (10) , 5215-5224 | ACS Energy Letters
Bridging Atomic and Macroscopic Perspectives on Heteroepitaxial Growth in Lithium Metal Anodes EI
期刊论文 | 2024 , 9 (10) , 5215-5224 | ACS Energy Letters
Lithium-Lanthanide Heterometallic Organic Frameworks with Near-Unity Photoluminescence Quantum Yields for Single-Composition White-Light Emission and Fluorescent Sensing on Nitrobenzene SCIE
期刊论文 | 2024 , 12 (21) | ADVANCED OPTICAL MATERIALS
WoS CC Cited Count: 2
Abstract&Keyword Cite Version(2)

Abstract :

Lanthanide ion contained metal-organic frameworks (MOFs) have garnered significant attention in the fields of solid-state lighting and chemical sensing due to their porous structure and distinctive optical properties. However, they also present challenges because of the limited photoluminescence (PL) intensity resulting from the parity-forbidden f-f transitions of lanthanide ions. Herein, the study reports a new heterometallic MOFs Ln3Li2L4 (Li-Ln-MOF, Ln = Y, Eu, Tb and Dy, L = deprotonated 1,3,5-tris(4-carboxyphenyl)benzene) with a Brunauer-Emmett-Teller (BET) surface area of 774.1 m2/g. The porous crystal structure of Li-Ln-MOF is characterized by three kinds of channels interpenetrating with each other. By employing ligand alternation and lanthanide ion alloying strategies, Li-Y1-xEux-MOF1 crystal isostructural with Li-Ln-MOF is synthesized by using 2,4,6-tris(4-carboxyphenyl)-1,3,5-triazine (H3TATB) as ligand. The Li-Y0.7Eu0.3-MOF1 crystal excels in the comprehensive performance with a BET surface area of 858.8 m2 g-1 and a near-unity PL quantum yield. The time density functional theory and natural transition orbitals calculations unravel that the outstanding optical properties Li-Y0.7Eu0.3-MOF1 originates from the charge transfer between TATB3- and Eu3+. Benefiting from the excellent comprehensive performance of Li-Y1-xEux-MOF1, the study reveals their potentials as single-composition white-light emission and fluorescent sensing probe for the detection of nitrobenzene. A strategy via ligand alteration is developed to achieve a near-unity photoluminescence quantum yield in lanthanide metal-organic frameworks (Ln-MOFs) with a porosity of up to 53.6%. Mechanistic investigation through theoretical calculation and time-resolved spectra unravel that Ln-MOF displayed outstanding optical properties ascribed to the charge transfer from the triple excited state of ligand to the Ln3+. image

Keyword :

fluorescent sensing fluorescent sensing lanthanide-organic frameworks lanthanide-organic frameworks ligand alteration ligand alteration photoluminescence photoluminescence white-light emission white-light emission

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GB/T 7714 Zhang, Wei , Wang, En-Ting , Li, Xinhao et al. Lithium-Lanthanide Heterometallic Organic Frameworks with Near-Unity Photoluminescence Quantum Yields for Single-Composition White-Light Emission and Fluorescent Sensing on Nitrobenzene [J]. | ADVANCED OPTICAL MATERIALS , 2024 , 12 (21) .
MLA Zhang, Wei et al. "Lithium-Lanthanide Heterometallic Organic Frameworks with Near-Unity Photoluminescence Quantum Yields for Single-Composition White-Light Emission and Fluorescent Sensing on Nitrobenzene" . | ADVANCED OPTICAL MATERIALS 12 . 21 (2024) .
APA Zhang, Wei , Wang, En-Ting , Li, Xinhao , Huang, Weixin , Sun, Yakun , Liu, Zheyuan et al. Lithium-Lanthanide Heterometallic Organic Frameworks with Near-Unity Photoluminescence Quantum Yields for Single-Composition White-Light Emission and Fluorescent Sensing on Nitrobenzene . | ADVANCED OPTICAL MATERIALS , 2024 , 12 (21) .
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Lithium-Lanthanide Heterometallic Organic Frameworks with Near-Unity Photoluminescence Quantum Yields for Single-Composition White-Light Emission and Fluorescent Sensing on Nitrobenzene EI
期刊论文 | 2024 , 12 (21) | Advanced Optical Materials
Lithium-Lanthanide Heterometallic Organic Frameworks with Near-Unity Photoluminescence Quantum Yields for Single-Composition White-Light Emission and Fluorescent Sensing on Nitrobenzene Scopus
期刊论文 | 2024 , 12 (21) | Advanced Optical Materials
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