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Abstract:
This work shows the electrical switching of the nonparametric optical nonlinearity of tungsten oxide (WO3-x). The sign and magnitude of the effective nonlinear absorption coefficient (beta(eff)) can be modulated via application of an external bias. With laser excitation at 1030 nm, WO3-x shows a relatively large saturable absorption (SA) under an applied voltage (V-A) of -2.5 V, with beta(eff) being as large as -632 cm GW(-1), while reverse saturable absorption (RSA) is found for V-A larger than -1.5 V. The electrical switching of the nonlinear optical (NLO) response is reproducible and durable. Both electrostatic and electrochemical dopings of WO3-x occur during V-A variation, with SA resulting mainly from the electrochemical doping (the intercalation of H+ into the lattice of WO3-x). The wavelength-dependent NLO performance of pristine WO3-x is attributed to competition between one-photon absorption and two-photon absorption, while the V-A-derived NLO response is correlated with variation in the band structure and its population. These results suggest a promising approach for the postsynthesis modulation of the NLO response and a potential device configuration for further optoelectric applications.
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ADVANCED OPTICAL MATERIALS
ISSN: 2195-1071
Year: 2021
Issue: 12
Volume: 9
1 0 . 0 5
JCR@2021
8 . 0 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:142
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 6
SCOPUS Cited Count: 6
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: