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author:

Li, Hui (Li, Hui.) [1] | Hou, Ruipeng (Hou, Ruipeng.) [2] | Sun, Yanhui (Sun, Yanhui.) [3] | Diao, Mengjuan (Diao, Mengjuan.) [4] | Liang, Ying (Liang, Ying.) [5] | Chen, Xin (Chen, Xin.) [6] | Huang, Zhipeng (Huang, Zhipeng.) [7] | Wang, Jun (Wang, Jun.) [8] | Humphrey, Mark G. (Humphrey, Mark G..) [9] | Yu, Zhiyang (Yu, Zhiyang.) [10] (Scholars:喻志阳) | Zhang, Chi (Zhang, Chi.) [11]

Indexed by:

EI SCIE

Abstract:

This work shows the electrical switching of the nonparametric optical nonlinearity of tungsten oxide (WO3-x). The sign and magnitude of the effective nonlinear absorption coefficient (beta(eff)) can be modulated via application of an external bias. With laser excitation at 1030 nm, WO3-x shows a relatively large saturable absorption (SA) under an applied voltage (V-A) of -2.5 V, with beta(eff) being as large as -632 cm GW(-1), while reverse saturable absorption (RSA) is found for V-A larger than -1.5 V. The electrical switching of the nonlinear optical (NLO) response is reproducible and durable. Both electrostatic and electrochemical dopings of WO3-x occur during V-A variation, with SA resulting mainly from the electrochemical doping (the intercalation of H+ into the lattice of WO3-x). The wavelength-dependent NLO performance of pristine WO3-x is attributed to competition between one-photon absorption and two-photon absorption, while the V-A-derived NLO response is correlated with variation in the band structure and its population. These results suggest a promising approach for the postsynthesis modulation of the NLO response and a potential device configuration for further optoelectric applications.

Keyword:

electrical tuning electrochemical doping intercalation nonlinear absorption order nonlinear optics third&#8208 tungsten oxide

Community:

  • [ 1 ] [Li, Hui]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 2 ] [Hou, Ruipeng]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 3 ] [Sun, Yanhui]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 4 ] [Diao, Mengjuan]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 5 ] [Liang, Ying]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 6 ] [Huang, Zhipeng]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 7 ] [Zhang, Chi]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China
  • [ 8 ] [Chen, Xin]Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China
  • [ 9 ] [Wang, Jun]Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Key Lab Mat High Power Laser, Shanghai 201800, Peoples R China
  • [ 10 ] [Humphrey, Mark G.]Australian Natl Univ, Res Sch Chem, Canberra, ACT 2601, Australia
  • [ 11 ] [Yu, Zhiyang]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Huang, Zhipeng]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China;;[Zhang, Chi]Tongji Univ, Sch Chem Sci & Engn, Shanghai 200092, Peoples R China

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Source :

ADVANCED OPTICAL MATERIALS

ISSN: 2195-1071

Year: 2021

Issue: 12

Volume: 9

1 0 . 0 5

JCR@2021

8 . 0 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:142

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 6

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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