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Abstract:
Potassium-ion batteries (PIBs) are of academic and economic significance, but still limited by the lack of highly active electrode materials for de-/intercalation of large-radius K ions. Herein, an interconnected nitrogen/sulfur co-doped carbon nanosheep bundle (N/S-CSB) was proposed as the potassium ions storage material. The rich co-doping of nitrogen/sulfur of N/S-CNB with three-dimensional hierarchical bundled array structure yields distensible interlayer spaces to buffer the volume expansion during K+ insertion/extraction, offers more electrochemical active sites to obtain a high specific capacity, and provides efficient channels for fast ion/electron transports. Therefore, the N/S-CSB anode achieved high reversible specific capacity of 365 mAh/g obtained at 50 mA/g after 200 cycles with a coulombic efficiency (CE) close to 100%, high rate performance and long cycle stability. Moreover, the in-situ Raman spectra indicated outstanding reaction kinetics of as-prepared N/S-CSB anode.
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NANO RESEARCH
ISSN: 1998-0124
Year: 2021
Issue: 3
Volume: 15
Page: 2040-2046
1 0 . 2 6 9
JCR@2021
9 . 6 0 0
JCR@2023
ESI Discipline: PHYSICS;
ESI HC Threshold:87
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 30
SCOPUS Cited Count: 31
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 4
Affiliated Colleges: