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author:

Gan, Yanmei (Gan, Yanmei.) [1] | Zhu, Jiajie (Zhu, Jiajie.) [2] | Zhang, Qixin (Zhang, Qixin.) [3] | Wang, Chaoying (Wang, Chaoying.) [4] | Guan, Lunhui (Guan, Lunhui.) [5] | Zhao, Yi (Zhao, Yi.) [6]

Indexed by:

SCIE CSCD

Abstract:

Metal sulfides have been regarded as promising anodes for potassium-ion batteries (PIBs) due to their high theoretical capacities, while the performance is limited by their intrinsic poor conductivity and large volume fluctuation during the insertion/extraction of large potassium ion. Herein, the battery performance of iron sulfide anode is significantly enhanced through yolk-shell (Y-S) structure design and nickel doping, aiming to realize good structure stability and superior electron/ion transportation. For potassium storage, as-prepared Y-S Ni-FeS2@C shows excellent cyclic performance and sustains high capacities of 328 mA h g(-1) after 100 cycles at 0.2 A g(-1) and 226 mA h g(-1) after 1000 cycles at 1 A g(-1). Especially, it displays a superior rate capacity of 200 mA h g(-1) at 20 A g(-1), higher than that of Y-S FeS2@C and most as-reported metal sulfide anodes for PIBs. The experimental analysis and theoretical calculation illuminate the effect of Ni-doping on decreasing the particle size of iron sulfide and enhancing the ion/electron transport ability, thus accounting for the exceptional rate capability of Y-S Ni-FeS2@C composite.

Keyword:

anode FeS2 Ni-doping potassium-ion batteries yolk-shell structure

Community:

  • [ 1 ] [Gan, Yanmei]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Gan, Yanmei]Fujian Normal Univ, Straits Inst Flexible Elect, Future Technol, SIFE, Fuzhou 350117, Peoples R China
  • [ 3 ] [Zhang, Qixin]Fujian Normal Univ, Straits Inst Flexible Elect, Future Technol, SIFE, Fuzhou 350117, Peoples R China
  • [ 4 ] [Wang, Chaoying]Fujian Normal Univ, Straits Inst Flexible Elect, Future Technol, SIFE, Fuzhou 350117, Peoples R China
  • [ 5 ] [Zhao, Yi]Fujian Normal Univ, Straits Inst Flexible Elect, Future Technol, SIFE, Fuzhou 350117, Peoples R China
  • [ 6 ] [Gan, Yanmei]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Key Lab Nanomat, Fuzhou 350108, Peoples R China
  • [ 7 ] [Zhang, Qixin]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Key Lab Nanomat, Fuzhou 350108, Peoples R China
  • [ 8 ] [Guan, Lunhui]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fujian Key Lab Nanomat, Fuzhou 350108, Peoples R China
  • [ 9 ] [Zhu, Jiajie]Tongji Univ, Sch Phys Sci & Engn, Shanghai 200092, Peoples R China

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Source :

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2022

Issue: 5

Volume: 41

Page: 2205030-,

2 . 2

JCR@2022

5 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:74

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 10

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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