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author:

Liu, Qian (Liu, Qian.) [1] | Hu, Xiang (Hu, Xiang.) [2] | Liu, Yangjie (Liu, Yangjie.) [3] | Wen, Zhenhai (Wen, Zhenhai.) [4]

Indexed by:

SCIE

Abstract:

Various strategies have been developed to mitigate the huge volume expansion of a silicon-based anode during the process of (de)lithiation and accelerate the transport rate of the ions/electrons for lithium-ion batteries (LIBs). Here, we report a one-step synthetic route through a low-temperature eutectic molten salt (LiCl-KCl, 352 degrees C) to fabricate two-dimensional (2D) silicon-carbon hybrids (Si@SiOx@MpC), in which the silicon nanoparticles (SiNPs) with an ultrathin SiOx layer are fully encapsulated by graphene-like carbon nanosheets derived from a low-cost mesophase pitch. The combination of an amorphous graphene-like carbon conductive matrix and a SiOx protective layer strongly promotes the electrical conductivity, structure stability, and reaction kinetics of the SiNPs. Consequently, the optimized SipSiO(x)@MpC-2 anode delivers large reversible capacity (1239 mAh g(-1) at 1.0 A g(-1)), superior rate performance (762 mAh g(-1) at 8 A g(-1)), and long cycle life over 600 cycles (degradation rate of only 0.063% every cycle). When coupled with a homemade nano- LiFePO4 cathode in a full cell, it exhibits a promising energy density of 193.5 Wh kg(-1) and decent cycling stability for 200 cycles at 1C. The methodology driven by salt melt synthesis paves a low-cost way toward simple fabrication and manipulation of silicon-carbon materials in liquid media.

Keyword:

lithium-ion batteries low-temperature molten salt pitch silicon nanoparticles two-dimensional

Community:

  • [ 1 ] [Liu, Qian]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350116, Fujian, Peoples R China
  • [ 2 ] [Hu, Xiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350116, Fujian, Peoples R China
  • [ 3 ] [Liu, Yangjie]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350116, Fujian, Peoples R China
  • [ 4 ] [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350116, Fujian, Peoples R China
  • [ 5 ] [Liu, Qian]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350116, Fujian, Peoples R China
  • [ 6 ] [Hu, Xiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350116, Fujian, Peoples R China
  • [ 7 ] [Liu, Yangjie]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350116, Fujian, Peoples R China
  • [ 8 ] [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350116, Fujian, Peoples R China
  • [ 9 ] [Liu, Qian]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 10 ] [Hu, Xiang]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
  • [ 11 ] [Liu, Yangjie]Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350116, Fujian, Peoples R China;;[Wen, Zhenhai]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, Fuzhou 350116, Fujian, Peoples R China

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2020

Issue: 50

Volume: 12

Page: 55844-55855

9 . 2 2 9

JCR@2020

8 . 5 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 37

SCOPUS Cited Count: 37

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

Online/Total:2003/9407929
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