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author:

Zeng, Lingxing (Zeng, Lingxing.) [1] | Liu, Renpin (Liu, Renpin.) [2] | Han, Lei (Han, Lei.) [3] | Luo, Fenqiang (Luo, Fenqiang.) [4] | Chen, Xi (Chen, Xi.) [5] | Wang, Jianbiao (Wang, Jianbiao.) [6] | Qian, Qingrong (Qian, Qingrong.) [7] | Chen, Qinghua (Chen, Qinghua.) [8] | Wei, Mingdeng (Wei, Mingdeng.) [9] (Scholars:魏明灯)

Indexed by:

EI Scopus SCIE

Abstract:

In this work, an Si/SiO2-ordered-mesoporous carbon (Si/SiO2-OMC) nanocomposite was initially fabricated through a magnesiothermic reduction strategy by using a two-dimensional bicontinuous mesochannel of SiO2-OMC as a precursor, combined with an NaOH etching process, in which crystal Si/amorphous SiO2 nanoparticles were encapsulated into the OMC matrix. Not only can such unique porous crystal Si/amorphous SiO2 nanoparticles uniformly dispersed in the OMC matrix mitigate the volume change of active materials during the cycling process, but they can also improve electrical conductivity of Si/SiO2 and facilitate the Li+/Na+ diffusion. When applied as an anode for lithium-ion batteries (LIBs), the Si/SiO2-OMC composite displayed superior reversible capacity (958 mAhg(-1) at 0.2 Ag-1 after 100 cycles) and good cycling life (retaining a capacity of 459 mAhg(-1) at 2 Ag-1 after 1000 cycles). For sodium-ion batteries (SIBs), the composite maintained a high capacity of 423 mAhg(-1) after 100 cycles at 0.05 Ag-1 and an extremely stable reversible capacity of 190 mAhg(-1) was retained even after 500 cycles at 1 Ag-1. This performance is one of the best long-term cycling properties of Si-based SIB anode materials. The Si/SiO2-OMC composites exhibited great potential as an alternative material for both lithium- and sodium-ion battery anodes.

Keyword:

electrochemical performance lithium-ion batteries mesoporous carbon silicon sodium-ion batteries

Community:

  • [ 1 ] [Zeng, Lingxing]Fujian Normal Univ, Chem Postdoctoral Stn, Fuzhou 35007, Fujian, Peoples R China
  • [ 2 ] [Qian, Qingrong]Fujian Normal Univ, Chem Postdoctoral Stn, Fuzhou 35007, Fujian, Peoples R China
  • [ 3 ] [Chen, Qinghua]Fujian Normal Univ, Chem Postdoctoral Stn, Fuzhou 35007, Fujian, Peoples R China
  • [ 4 ] [Wang, Jianbiao]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Wei, Mingdeng]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Han, Lei]Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, 700 Changcheng Rd, Qingdao, Peoples R China
  • [ 7 ] [Zeng, Lingxing]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 8 ] [Liu, Renpin]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 9 ] [Luo, Fenqiang]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 10 ] [Chen, Xi]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 11 ] [Qian, Qingrong]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 12 ] [Chen, Qinghua]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China
  • [ 13 ] [Chen, Qinghua]Fuqing Branch Fujian Normal Univ, Fuqing 350300, Fujian, Peoples R China

Reprint 's Address:

  • 魏明灯

    [Chen, Qinghua]Fujian Normal Univ, Chem Postdoctoral Stn, Fuzhou 35007, Fujian, Peoples R China;;[Wei, Mingdeng]Fuzhou Univ, Inst Adv Energy Mat, Fuzhou 350002, Fujian, Peoples R China;;[Chen, Qinghua]Fujian Key Lab Pollut Control & Resource Reuse, Fuzhou 350007, Fujian, Peoples R China;;[Chen, Qinghua]Fuqing Branch Fujian Normal Univ, Fuqing 350300, Fujian, Peoples R China

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Source :

CHEMISTRY-A EUROPEAN JOURNAL

ISSN: 0947-6539

Year: 2018

Issue: 19

Volume: 24

Page: 4841-4848

5 . 1 6

JCR@2018

3 . 9 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 66

SCOPUS Cited Count: 70

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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