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author:

李浩宏 (李浩宏.) [1] (Scholars:李浩宏) | 陈之荣 (陈之荣.) [2] (Scholars:陈之荣) | 黄长沧 (黄长沧.) [3] (Scholars:黄长沧) | 肖光参 (肖光参.) [4] (Scholars:肖光参) | 李俊篯 (李俊篯.) [5] | 张文选 (张文选.) [6]

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CQVIP PKU CSCD

Abstract:

A one dimensional coordination polymer, [(C7H18N)(Ag2I3)]n((C7H18N)+=Methyltriethylammonium) has been successfully synthesized and characterized by X-ray single-crystal diffraction method. Structure analysis shows that the compound consists of organic cations(Methyltriethylammonium) and inorganic anion chains (Ag2I3)n-.The inorganic moiety consists of AgI4 tetrahedron, which shares the same edges with adjacent AgI4 tetrahedrons to the crystal. Anion chains are surrounded by Methyltriethylammonium cations. Anion chains and cations are in combination with each other by static attracting forces in the crystal to form so-called organic-inorganic hybrid structure. According to the crystal structure data, quantum chemistry calculation with DFT on B3LYP level was used to reveal the electronic structure of title compound. CCDC: 254288.

Keyword:

有机/无机杂化 模板合成 碘化银 量子化学计算

Community:

  • [ 1 ] [李浩宏]福州大学
  • [ 2 ] [陈之荣]福州大学
  • [ 3 ] [黄长沧]福州大学
  • [ 4 ] [肖光参]福州大学
  • [ 5 ] [李俊篯]福州大学
  • [ 6 ] [张文选]福州大学

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Source :

无机化学学报

ISSN: 1001-4861

CN: 32-1185/O6

Year: 2005

Issue: 6

Volume: 21

Page: 933-937

0 . 6 9 7

JCR@2005

0 . 8 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

JCR Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 7

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