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author:

Cheng, Shuying (Cheng, Shuying.) [1] | Chen, Yanqing (Chen, Yanqing.) [2] | Huang, Cichang (Huang, Cichang.) [3] | Chen, Guonan (Chen, Guonan.) [4]

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EI

Abstract:

In this paper, SnS films were cathodically electrodeposited on ITO glass substrates from aqueous solution containing 5mM SnSO4 and 25mM Na2S2O3 with pH of 2-3. When the deposition potential (E) was varied from -0.60 to -1.1V vs SCE, the corresponding SnS films were characterized with X-ray diffractograms, microstructure and composition analysis. It was found that, the composition ratio Sn/S of the film varied with E, the ratio Sn/S significantly increased and exceeded 1 at E more cathodic than -0.75V vs SCE, and the ratio Sn/S significantly decreased and was less than 1 at E larger than -0.7V vs SCE. The stoichiometric SnS film was synthesized at-0.72-0.75V vs SCE . The structural and optical properties of the film have been studied. The X-ray diffraction pattern of the film showed that it was polycrystalline and of orthorhombic structure. The estimated optical bandgap energy was 1.31eV.

Keyword:

Composition Electric conductivity Electric potential Electrodeposition Metallic films Microstructure Polycrystalline materials Stoichiometry Synthesis (chemical) Tin compounds X ray diffraction

Community:

  • [ 1 ] [Cheng, Shuying]Chemistry Department, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Cheng, Shuying]Department of Electronic Science and Applied Physics, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Chen, Yanqing]Department of Electronic Science and Applied Physics, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Huang, Cichang]Department of Electronic Science and Applied Physics, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Chen, Guonan]Chemistry Department, Fuzhou University, Fuzhou 350002, China

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Source :

ISSN: 0277-786X

Year: 2005

Volume: 5633

Page: 308-314

Language: English

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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