The　best　formation　process　of　black　colored　CuFeMnO4　spinel　powders,　which　were　synthesized　by　EDTA　complexing　Sol-Gel　method,　was　investigated.　Furthermore,　the　solar　absorptivity　of　CuFeMnO4　spinel　powders　was　examined　by　the　UV-Vis-NIR　spectrophotometer.　The　results　revealed　that　the　CuFeMnO4　spinel　powders　were　successfully　synthesized　without　the　CuO,　Fe2O3　and　the　MnO　extraneous　phase　under　circumstances　that　the　temperature　was　about　25C(ambient　temperature),　the　metal　ion　ratio　was　Mn2+:Cu2+:Fe3+=3:2:1　and　the　pH　value　of　the　solution　was　about　6.5.　After　annealed　at　800C,　the　powders　could　absorb　the　light　within　the　wavelength　range　of　200-2500　nm　efficiently　and　the　absorptivity　can　reach　up　to　95%.　It　showed　that　CuFeMnO4　spinel　powders　could　be　used　as　potential　material　for　solar　absorbers　in　solar　collector　systems.