The　supplier　is　an　important　member　in　the　supply　chain.　The　work　of　supplier　evaluation　is　also　an　essential　effect　for　the　good　operation　of　the　manufacturing　supply　chain.　However,　supply　chain　has　some　characteristics.　They　are　dynamic　composition,　the　complicated　management　and　the　high　risk.　These　characteristics　determine　that　supplier　evaluation　is　complex　and　difficult.　Therefore,　in　this　paper,　we　study　the　supplier　evaluation　and　put　forward　the　assessment　framework　of　supply　chain　evaluation.　This　assessment　framework　with　new　hesitant　fuzzy　sets　can　better　express　the　decision　maker＇s　preference　more　accurately　and　can　be　applied　in　more　multiple　decision　making　problems.　Finally,　we　apply　this　method　to　evaluate　the　supplier　and　get　the　evaluated　results.　The　experiments　show　that　this　method　can　express　better　the　decision　maker’s　preference　more　accurately.　©　2016　SERSC.