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author:

Shen, Deli (Shen, Deli.) [1] | Mao, Haijuan (Mao, Haijuan.) [2] | Li, Yafeng (Li, Yafeng.) [3] | Abate, Antonio (Abate, Antonio.) [4] | Wei, Mingdeng (Wei, Mingdeng.) [5]

Indexed by:

EI

Abstract:

Effective control of the perovskite crystallinity, homogeneity and surface morphology is very important for state-of-the-art perovskite solar cells to retard the charge recombination at the grain boundaries. In this work, we develop a facile approach to promote the growth of high quality perovskite films that features a conductive glass-assisted annealing route. Such a novel annealing route not only confines the evaporation of the residual solvent effectively to gain high-crystallinity and micrometer-sized grains of CH3NH3PbI3 films, but also decreases the number of non-radiative recombination sites and facilitates charge transportation in the microstructural perovskite films dramatically compared with those obtained through the conventional annealing route, resulting in a remarkably improved power conversion efficiency along with an inconspicuous hysteresis. The best performing cell exhibits a PCE boosted to 18.08% compared with 16.18% achieved in the control one. And the optimized 1 cm2 device based on the reported method shows a satisfactory efficiency of 15.77%. © 2018 The Royal Society of Chemistry.

Keyword:

Annealing Conductive films Conversion efficiency Crystallinity Efficiency Glass Grain boundaries Grain growth Morphology Perovskite Perovskite solar cells Surface morphology Transportation routes

Community:

  • [ 1 ] [Shen, Deli]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 2 ] [Shen, Deli]Institute of Advanced Energy Materials, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 3 ] [Mao, Haijuan]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 4 ] [Mao, Haijuan]Institute of Advanced Energy Materials, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 5 ] [Li, Yafeng]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 6 ] [Li, Yafeng]Institute of Advanced Energy Materials, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 7 ] [Abate, Antonio]Institute of Advanced Energy Materials, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 8 ] [Abate, Antonio]Helmholtz-Zentrum Berlin für Materialien und Energie, Kekuléstrasse 5, Berlin; 12489, Germany
  • [ 9 ] [Wei, Mingdeng]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, Fujian; 350002, China
  • [ 10 ] [Wei, Mingdeng]Institute of Advanced Energy Materials, Fuzhou University, Fuzhou, Fujian; 350002, China

Reprint 's Address:

  • [li, yafeng]institute of advanced energy materials, fuzhou university, fuzhou, fujian; 350002, china;;[li, yafeng]state key laboratory of photocatalysis on energy and environment, fuzhou university, fuzhou, fujian; 350002, china

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Source :

Journal of Materials Chemistry A

ISSN: 2050-7488

Year: 2018

Issue: 41

Volume: 6

Page: 20289-20296

1 0 . 7 3 3

JCR@2018

1 0 . 8 0 0

JCR@2023

ESI HC Threshold:284

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 10

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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