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Abstract:
Effective control of the perovskite crystallinity, homogeneity and surface morphology is very important for state-of-the-art perovskite solar cells to retard the charge recombination at the grain boundaries. In this work, we develop a facile approach to promote the growth of high quality perovskite films that features a conductive glass-assisted annealing route. Such a novel annealing route not only confines the evaporation of the residual solvent effectively to gain high-crystallinity and micrometer-sized grains of CH3NH3PbI3 films, but also decreases the number of non-radiative recombination sites and facilitates charge transportation in the microstructural perovskite films dramatically compared with those obtained through the conventional annealing route, resulting in a remarkably improved power conversion efficiency along with an inconspicuous hysteresis. The best performing cell exhibits a PCE boosted to 18.08% compared with 16.18% achieved in the control one. And the optimized 1 cm(2) device based on the reported method shows a satisfactory efficiency of 15.77%.
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JOURNAL OF MATERIALS CHEMISTRY A
ISSN: 2050-7488
Year: 2018
Issue: 41
Volume: 6
Page: 20289-20296
1 0 . 7 3 3
JCR@2018
1 0 . 8 0 0
JCR@2023
ESI Discipline: MATERIALS SCIENCE;
ESI HC Threshold:284
JCR Journal Grade:1
CAS Journal Grade:1
Cited Count:
WoS CC Cited Count: 9
SCOPUS Cited Count: 10
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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