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author:

Zhang, Bo (Zhang, Bo.) [1] | Wu, Kewen (Wu, Kewen.) [2] | Peng, Kaiping (Peng, Kaiping.) [3]

Indexed by:

EI

Abstract:

Nd2-xInxCe2O7 (x = 0, 0.05, 0.10, 0.15 and 0.20) powders are successfully synthesized by citric acid-nitrate sol-gel combustion method. The influence of In doping on the phase structure, morphology, and electrical conduction behavior of neodymium cerium is characterized by X-ray diffraction, Raman spectroscopy, scanning electron microscopy and electrochemical impedance spectroscopy. All Nd2-xInxCe2O7 ceramics are found to possess a fluorite-type structure. Moreover, Nd1.85In0.15Ce2O7 pellets keep sufficiently excellent chemical stability under different atmospheres containing CO2, water and wet hydrogen. Highly dense ceramics with increasing grain size are obtained by sintering at reduced temperature resulting from indium incorporation promotes sinterability of Nd2-xInxCe2O7. The Nd1.85In0.15Ce2O7 pellet promises the highest total conductivities of 0.75 × 10−2 and 2.07 × 10−2 S cm-1 at 700 °C in dry air and wet 5% H2-Ar conditions, respectively. Furthermore, an anode-supported single cell with dense Nd1.85In0.15Ce2O7 electrolyte film is successfully assembled and evaluated. The maximum power density of the cell reaches 743 mW cm-2 at 700 °C. The results indicate that In-doped Nd2Ce2O7 is a promising candidate as a proton-conducting electrolyte for intermediate-temperature solid oxide fuel cells. © 2018 Elsevier B.V.

Keyword:

Cerium oxide Chemical stability Electric conductivity Electrochemical impedance spectroscopy Electrolytes Fluorspar Gas fuel purification Indium compounds Neodymium compounds Pelletizing Phase structure Scanning electron microscopy Semiconductor doping Sintering Sol-gels Solid electrolytes Solid oxide fuel cells (SOFC)

Community:

  • [ 1 ] [Zhang, Bo]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 2 ] [Wu, Kewen]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China
  • [ 3 ] [Peng, Kaiping]College of Materials Science and Engineering, Fuzhou University, Fuzhou; Fujian; 350116, China

Reprint 's Address:

  • [peng, kaiping]college of materials science and engineering, fuzhou university, fuzhou; fujian; 350116, china

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2018

Volume: 399

Page: 157-165

7 . 4 6 7

JCR@2018

8 . 1 0 0

JCR@2023

ESI HC Threshold:284

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 14

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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