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author:

Suo, Yaohong (Suo, Yaohong.) [1] | Yang, Fuqian (Yang, Fuqian.) [2]

Indexed by:

EI

Abstract:

The chemical reactions taking place in lithium-ion batteries can trap lithium and alter the distribution of lithium and the deformation of the electrode during electrochemical charging and discharging. In this work, we incorporate the strain generated by chemical reactions in the transient analysis of diffusion-induced stress and numerically solve the one-dimensional problem under galvanostatic and potentiostatic operations, respectively. The numerical results show that both the diffusion and local chemical reaction contribute to the expansion of the electrode. Under the potentiostatic operation, lithiation introduces a stress spike at the fixed end at the onset of the lithiation. The chemical reactions play a significant role in controlling the temporal evolution of lithium and the deformation of electrode, which needs to be taken into account in the analysis of structural durability of lithium-ion batteries. © 2018, Springer-Verlag GmbH Austria, part of Springer Nature.

Keyword:

Chemical analysis Chemical operations Chemical reactions Deformation Diffusion Electrochemical electrodes Lithium-ion batteries Stresses Transient analysis

Community:

  • [ 1 ] [Suo, Yaohong]School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Suo, Yaohong]Department of Chemical and Materials Engineering, University of Kentucky, Lexington; KY; 40506-0046, United States
  • [ 3 ] [Suo, Yaohong]State Key Lab for Strength and Vibration of Mechanical Structures, School of Aerospace, Xi’an Jiaotong University, Xi’an; 710049, China
  • [ 4 ] [Yang, Fuqian]Department of Chemical and Materials Engineering, University of Kentucky, Lexington; KY; 40506-0046, United States

Reprint 's Address:

  • [suo, yaohong]state key lab for strength and vibration of mechanical structures, school of aerospace, xi’an jiaotong university, xi’an; 710049, china;;[suo, yaohong]school of mechanical engineering and automation, fuzhou university, fuzhou; 350108, china;;[suo, yaohong]department of chemical and materials engineering, university of kentucky, lexington; ky; 40506-0046, united states

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Source :

Acta Mechanica

ISSN: 0001-5970

Year: 2019

Issue: 3

Volume: 230

Page: 993-1002

2 . 1 0 2

JCR@2019

2 . 3 0 0

JCR@2023

ESI HC Threshold:150

JCR Journal Grade:3

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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