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author:

Yu, Pengfei (Yu, Pengfei.) [1] (Scholars:吁鹏飞) | Xiao, Junwen (Xiao, Junwen.) [2] | Hu, Hai (Hu, Hai.) [3] | Lin, Mingju (Lin, Mingju.) [4] | Suo, Yaohong (Suo, Yaohong.) [5] (Scholars:锁要红)

Indexed by:

SCIE

Abstract:

Experiments have shown that stress has a significant effect on the hysteresis loop of the electrode potential while charging or discharging Li-ion batteries. In this work, considering the influence of stress on lithium-ion diffusion and electrode potential, a fully coupled electro-chemo-mechanical model is developed in a spherical electrode particle under galvanostatic operation. Then, some simulations are carried out to investigate the distribution of lithium-ion concentration, diffusion-induced stresses and electric potential. Meanwhile, the influences of C-rate and electrode particle radius are also discussed. Numerical results show that the smaller C-rate and electrode particle radius are beneficial in reducing the diffusion-induced stresses and improving the effective capacity of Li-ion batteries. Finally, some comparisons of lithium-ions concentration and the hysteresis of electrode potential between the present model and Jin's model (without the effect of deformation on diffusion) are performed. The work can provide some tips for designing electrodes in Li-ion batteries with a high capacity and durability.

Keyword:

Diffusion-induced stress Electro-chemo-mechanical model Lithium-ion batteries Voltage hysteresis

Community:

  • [ 1 ] [Yu, Pengfei]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 2 ] [Xiao, Junwen]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 3 ] [Hu, Hai]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 4 ] [Lin, Mingju]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 5 ] [Suo, Yaohong]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China
  • [ 6 ] [Yu, Pengfei]Xi An Jiao Tong Univ, Sch Aerosp, State Key Lab Strength & Vibrat Mech Struct, Xian 710049, Peoples R China

Reprint 's Address:

  • 锁要红

    [Suo, Yaohong]Fuzhou Univ, Sch Mech Engn & Automat, Fuzhou 350108, Peoples R China

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Source :

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE

ISSN: 1452-3981

Year: 2021

Issue: 10

Volume: 16

1 . 5 4 1

JCR@2021

1 . 3 0 0

JCR@2023

ESI Discipline: CHEMISTRY;

ESI HC Threshold:117

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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